Skip to main content
SpringerLink
Log in

Non-covalent O···O interactions among isopolyanions using a cis-{MoO2} moiety by the assistance of N-H···O hydrogen bonds

  • Published:
Journal of Chemical Sciences Aims and scope Submit manuscript

Abstract

An inorganic-organic hybrid material, [2-AmpH]4[Mo8O26] (1) has been isolated by the reaction of Na2MoO4·2H2O with 2-aminopyrimidine (2-Amp) from an acidic aqueous medium. In this low pH synthesis, the organic molecule (2-Amp) gets mono-protonated (2-AmpH+) and acts as the cation in stabilizing the octamolybdate anion in 1. Compound 1 crystallizes in the triclinic space group P-1 with a = 9·925(3), b = 10·020(3), c = 10·414(3) Å, α = 88·811(4), β = 64·907(4), γ = 89.506(4)°, Z = 1. An interesting three-dimensional supramolecular structure, having well-defined channels, is formed through N-H···O and C-H···O hydrogen bonds, in which the protonated organic cation plays a significant role. The crystal structure also reveals an unusual cluster-cluster (non-covalent O···O) interaction using cis-(MoO2} moieties of the isopolyanion. N-H···O hydrogen bonds, originated from pyridimidinium cation and isopolyanion, are found to influence to attain such non-covalent O···O interactions among polyoxometalate anions. An interesting helical arrangement, formed from isopolyanion and organic cation, is observed.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Cheetham A M 1994 Science 264 794; Pope M T and Müller A 1991 Angew. Chem., Int. Ed. Engl. 30 34; Xu L, Qin C, Wang X L, Wei Y G and Wang E B 2003 Inorg. Chem. 42 7342; Müller A, Reuter H and Dillinger S 1995 Angew. Chem., Int. Ed. Engl. 34 2328; Yaghi O M 1999 Nature 402 276; Yaghi O M 1998 J. Am. Chem. Soc. 120 8571

    Article  CAS  Google Scholar 

  2. Yamase T 1993 Mol. Eng. 3 241; Uchida S, Hashimoto M and Mizuno N 2002 Angew. Chem., Int. Ed. 41 2814

    Article  CAS  Google Scholar 

  3. LaDuca R. L Jr, Desciak M, Laskoski M, Rarig R S Jr and Zubieta J 2000 J. Chem. Soc., Dalton Trans. 2255; Hagrman P J and Zubieta J 2000 Inorg. Chem. 39 5218; Zapf P J, Haushalter, R C and Zubieta J 1997 Chem. Commun. 321

  4. Hagman P J, Hagraman D and Zubieta J 1999 Angew. Chem., Int. Ed. 38 2638; Peng Z, Lu M, Xu B, Xu L, Wei Y, Xie B and Katabathini N R 2003 Polym. Prepr. 44 671; Wu C D, Lu C Z, Zhuang H H and Huang J S 2002 Inorg. Chem. 41 563; Yang W, Lu C, and Zhuang H 2002 Dalton Trans. 14 2879; Rarig R S and Zubieta J 2000 Inorg. Chim. Acta. 312 188; Wu C D, Lu C Z, Zhuang H H and Huang J S 2002 Inorg. Chem. 41 5636

    Article  Google Scholar 

  5. Soghomonian V, Chen Q, Haushalter R C, Zubieta J, O’Connor C J and Young-Sook Lee 1993 Chem. Mater. 5 1690; Soghomonian V, Haushalter R C, Chen Q, Zubieta Z and O’Connor C J 1993 Angew. Chem., Int. Ed. Engl. 32 610; Kroenke Jr J W, John P F and Anthony M M 1983 Inorg. Chem. 22 2412; Wilson A J, Mckee V, Penfold B R and Wilkins C J 1984 Acta Crystallogr. Sec. C. 40 2027

    Article  CAS  Google Scholar 

  6. McCarron E M, Whitney J F and Chase D B 1984 Inorg. Chem. 23 3275; Pan C-L, Xu J-Q, Wang K-X, Cui X-B, Ye L, Lu Z-L, Chu D-Q and Wang T-G 2003 Inorg. Chem. Commun. 6 370; Niu J-Y, Wei M-L, Wang J-P and Dang D-B 2003 J. Mol. Struct. 655 171; Pan C-L, Song J-F, Xu J-Q, Li G-H, Ye L and Wang T-G 2003 Inorg. Chem. Commun. 6 535

    Article  CAS  Google Scholar 

  7. Wozniak K, He H, Klinowski J, Jones W and Grech E 1994 J. Phys. Chem. 98 13755; Ni B, Lee K H and Sinnott S B 2004 J. Phys. Condens. Matter 16 7261; Breza M, Biskupic S and Manova A 2003 Polyhedron 22 2863; Jenkins S and Morrison I 2000 Chem. Phys. Lett. 317 97; Lemos M C, Luque J J and Jimenez-Morales F 1998 J. Chem. Phys. 109 8069; Blake N P, Weakliem P C and Metiu H 1998 J. Phys. Chem. 102 67; Igarashi K, Tajiri K, Tanemura S, Nanbu R and Fukunaga T 1997 Z. Phys. D: At., Mol. Clusters 40 562; Dang L X 1992 J. Chem. Phys. 97 2659

  8. Raghavaiah P, Supriya S and Das S K 2006 Chem. Commun. 2762

  9. According to our Cambridge Structural Database (CSD) search, no O···O interactions among polyoxometalate anions were explored prior to this work. We could observe the O···O interactions among polyoxometalate anions in few structures; however the relevant references did not talk about such interactions. Some of these references are: Do J, Wang X, and Jacobson A J 1999 J. Solid State Chem. 143 77; Shu-Meichen, Lu C-Z, Yu Y-Q, Zhang Q-Z and He X 2004 Acta Crystallogr., Sect. E; Struct. Rep. Online 60 m723; Deng Z-P, Gao S, Huo L-H and Zhao H 2005 Acta Crystallogr. Sect. E: Struct. Rep. Online 61 2553; Chakrabarti S and Natarajan S 2002 Cryst. Growth Design. 2 333; Gili P, Nunez P, Martin-Zarza P and Lorenzo-Luis P A Acta Crystallogr., Sect. C: Cryst. Struct. Commun. 56 2000 e441; Cindric M, Strukan N and Kamenar B 1999 Polyhedron 18 2781; Upreti S and Ramanan A 2006 Cryst. Growth. Design 6 2066; Kortz U, Savelieff M G, Ghali F Y A, Khalil L M, Maalouf S A and Sinno D I 2002 Angew. Chem., Int. Ed. 41 4070; Liu H, Wang H, Shi D and Lu Z 2006 J. Coord. Chem. 59 1703; Aranzabe A, Wery A S J, Martin S, Gutierrez-Zorrila J M, Luque A, Martinez-Ripoll M and Roman P 1997 Inorg. Chim. Acta 255 35

    Article  CAS  Google Scholar 

  10. Software for the CCD Detector System 1998 Bruker analytical X-ray systems Inc., Madison, WI

  11. Sheldrick G M 1996 SADABS, A program for absorption correction with the Siemens SMART area-detector system, University of Göttingen, Germany

    Google Scholar 

  12. Sheldrick G M 1997 SHELXS-97 A program for solution of crystal structures, University of Göttingen, Germany

    Google Scholar 

  13. Sheldrick G M 1997 SHELXL-97, A program for solution of crystal structures, University of Göttingen, Germany

    Google Scholar 

  14. Carlucci L, Ciani G, Gudenberg D W V and Proserpio D M 1997 Inorg. Chem. 36 3812; Amendola V, Fabbrizzi L, Mangano C, Pallavivini P, Roboli E and Zema M 2000 Inorg. Chem. 39 5803; Lu C-Z, Wu C-D, Lu S-F, Liu J-C, Wu Q-J, Zhuang H-H and Huang J-S 2002 Chem. Commun. 152; Hirsch K A, Wilson S R and Moore J S 1998 Chem. Commun. 13; Garrett T M 1990 J. Chem. Soc., Chem. Commun. 557; Lehn J-M and Riganlt A 1988 Angew. Chem., Int. Ed. Engl. 27 1095; Shi Z, Feng S H, Gao S, Zhang L, Yang G and Hua J 2000 Angew. Chem., Int. Ed. 39 2325; Liang J, Wang Y, Yu J H, Li Y and Xu R R 2003 Chem. Commun. 882; Kniep R, Will H G, Boy I and Röhr C 1997 Angew. Chem. Int. Ed. Engl. 36 1013; Neeraj S, Natarajan S and Rao C N R 1999 Chem. Commun. 165

    Article  CAS  Google Scholar 

  15. Hemamalini M, Muthiah P T, Butcher R J and Lynch D E 2006 Inorg. Chem. Commun. 9 1155; Brown D J, and Mason S F 1962 The pyrimidines (New York: Interscience Publishers John Wiley & Sons); Brouillette C B, Chang C T and Mertes M P 1979 J. Med. Chem. 22 1541; Dlercq E D, Descamps J, Huang G and Torrence P 1978 Mol. Pharmacol. 14 422; Danenberg P V 1977 Biochim. Biophys. Acta 497 73; Silva A D D, Machado A S, Tempete C and Robert-Gero M 1994 Eur. J. Med. Chem. Chim. Ther. 29 1149; Sondhi S M, Johar M, Rajvanshi S, Dastidar S G, Shukla R, Raghubir R and Lown J W 2001 Aust. J. Chem. 54 169; Kidwai M, Saxena S, Rastogi S and Venkataramanan R 2004 Curr. Med. Chem. Ant-Infective Agents 2 269

    Article  CAS  Google Scholar 

  16. Huang S, Li R, Connolly P J, Xu G, Gaul M D, Emanuel S L, LaMontagne K R and Greenberger L M 2006 Bioorg. Med. Chem. Lett. 16 6063

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. School of Chemistry, University of Hyderabad, Hyderabad, 500 046, India

    T. Arumuganathan, A. Srinivasa Rao & Samar K. Das

Authors
  1. T. Arumuganathan
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. A. Srinivasa Rao
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Samar K. Das
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Samar K. Das.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Arumuganathan, T., Srinivasa Rao, A. & Das, S.K. Non-covalent O···O interactions among isopolyanions using a cis-{MoO2} moiety by the assistance of N-H···O hydrogen bonds. J Chem Sci 120, 297–304 (2008). https://doi.org/10.1007/s12039-008-0051-y

Download citation

  • Received:

  • Revised:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s12039-008-0051-y

Keywords

Search

Navigation