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Testing of starch-based carbohydrate polymer coatings for enhanced urea performance

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Abstract

In this study, starch–urea–borate adhesives were developed for coating the slow release urea. The physical properties of the developed adhesives were studied as a function of temperature, heating time, stirring rate, and pH. It was found that for certain specific adhesive composition, pH and stirring rate, the complete gelatinization time and corresponding adhesive viscosity do not remain constant with temperature. The suspension heated at 75°C reached its maximum viscosity after 21 min of heating, thereafter, remained constant over time. In contrast, the suspension heated at 80°C reached its peak viscosity after 12 min of heating. Further heating after 12 min caused a steady decrease in viscosity from its peak value of 450–339 cP. Once the adhesive physical properties were completely understood, a dripping solution technique was used to coat the urea granules with coating thickness ranging from 0.15 to 0.7 mm. It was noticed that the overall nutrients release time of the coated urea was three times higher than the uncoated urea. It was also concluded that the mechanical strength of coated urea strongly depends on the adhesive composition and coating thickness.

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References

  1. Suherman, I, Anggoro, DD, “Producing Slow Release Rate Urea by Coating with Starch/Acrylic Acid in Fluid Bed Spraying.” Int. J. Eng. Technol. IJET-IJENS, 11(6) 77–80 (2011)

  2. Naz, MY, Sulaiman, SA, Ariwahjoedi, B, Ku, Z, Ku, S, “Characterization of Modified Tapioca Starch Solutions and Their Sprays for High Temperature Coating Applications.” Sci. World J., 2014:Article ID 375206 (2014)

    Google Scholar 

  3. Suri, IK, “Coating of Prilled Urea with Neem.” Fertil. News, 45 71–72 (2000)

    Google Scholar 

  4. Saleh, DS, Hemati, M, “Experimental Study and Modeling of Fluidized Bed Coating and Agglomeration.” Powder Technol., 130 116–123 (2003)

    Article  Google Scholar 

  5. Kantheti, S, Narayan, R, Raju, KVSN, “Development of Moisture Cure Polyurethane–Urea Coatings Using 1,2,3-Triazole Core Hyperbranched Polyesters.” J. Coat. Technol. Res., 10 (5) 609–619 (2013)

    Article  Google Scholar 

  6. Chiellini, E, Solaro, R, “Biodegradable Polymeric Materials.” Adv. Mater., 4 305–313 (1996)

    Article  Google Scholar 

  7. Noordover, BAJ, Heise, A, Malanowksi, P, et al., “Biobased Step-Growth Polymers in Powder Coating Applications.” Prog. Org. Coat., 65 (2) 187–196 (2009)

    Article  Google Scholar 

  8. Herman, J, Remon, JP, DeVilder, J, “Modified Starches as Hydrophilic Matrices for Controlled Oral Delivery I: Production and Characterization of Thermally Modified Starches.” Int. J. Pharm. Nanotechnol., 56 51–66 (1989)

    Article  Google Scholar 

  9. Kottke, MK, Chueh, HR, Rhodes, CT, “Comparison of Disintegrant and Binder Activity of Three Corn Starch Products.” Drug Dev. Ind. Pharm., 18 2207–2223 (1992)

    Article  Google Scholar 

  10. Mulder, WJ, Gosselink, RJA, Vingerhoeds, MH, Harmsen, PFH, Eastham, D, “Publications Lignin Based Controlled Release Coatings.” Ind. Crops Prod., 34 915–920 (2011)

    Article  Google Scholar 

  11. Fernández-Pérez, M, González-Pradas, E, Villafranca-Sánchez, M, Flores-Céspedes, F, “Mobility of Isoproturon from an Alginate–Bentonite Controlled Release Formulation in Layered Soil.” Chemosphere, 41 (9) 1495–1501 (2000)

    Article  Google Scholar 

  12. Pratap, KG, Chowdary, KPR, Yasoda, KK, “Evaluation of Starch Acetate as Microencapsulating Agent for Controlled Release of Carbamazepine in Comparison to Other Known Polymers.” Int. J. Pharma. Sci., 2 (4) 67–69 (2012)

    Google Scholar 

  13. Jin, S, Wang, Y, He, J, Yang, Y, Yu, X, Yue, G, “Preparation and Properties of a Degradable Interpenetrating Polymer Networks Based on Starch with Water Retention, Amelioration of Soil, and Slow Release of Nitrogen and Phosphorus Fertilizer.” J. Appl. Polym. Sci., 128 (1) 407–415 (2012)

    Article  Google Scholar 

  14. Jiang, L, Chen, Y, Hu, C, “Polyurethaneurea Aqueous Dispersions Prepared with Diethyltoluenediamine as Chain Extender.” J. Coat. Technol. Res., 4 (1) 59–66 (2007)

    Article  Google Scholar 

  15. Blouin, GM, Rindt, DW, Moore, OE, “Sulphur-Coated Fertilizers for Controlled Release. Pilot Plant Production.” J. Agric. Food Chem., 19 (5) 801–808 (1971)

    Article  Google Scholar 

  16. Tang, ES, Liew, CV, Er, DZ, Liu, X, Wigmore, AJ, Heng, PW, “Study of Coat Quality of Tablets Coated by an On-Line Supercell Coater.” AAPS PharmSciTech., 8 E92–E98 (2007)

    Article  Google Scholar 

  17. Naz, MY, Sulaiman, SA, Ariwahjoedi, B, Ku, Z, “Visual Study of Hollow Cone Water Spray Jet Breakup Process at Elevated Temperatures and Pressures.” Appl. Mech. Mater., 465–466 485–489 (2014)

    Google Scholar 

  18. Liu, Y-q, Li, X-y, Zhang, F-x, Sun, Y-y, Zhao, G-z, “Design and Characteristic Analysis of a New Nozzle for Preparing Microencapsulated Particles by RESS.” J. Coat. Technol. Res., 6 (3) 377–382 (2009)

    Article  Google Scholar 

  19. Chowdary, KPR, Krishna, M, “Synthesis and Evaluation of Starch–Urea–Borate as Rate Controlling Matrix for Controlled Release.” Int. J. Pharm. Nanotechnol., 1 (2) 167–170 (2008)

    Google Scholar 

  20. Meinke, LJ, Mayo, Z, Weissling, TJ, “Pheromone Delivery System: Western Corn Rootworm (Coleoptera: Chrysomelidae) Pheromone Encapsulation in a Starch Borate Matrix.” J. Econ. Entomol., 82 1830–1835 (1989)

    Google Scholar 

  21. Widiarto, S, “Effect of Borax on Mechanical Properties and Biodegradability of Sago Starch—Poly(vinylalcohol) Blend Films.” Jurnal Sains and Teknologi, 2 151–157 (2005)

    Google Scholar 

  22. Gunaratne, A, Hoover, R, “Effect of Heat-Moisture Treatment on the Structure and Physicochemical Properties of Tuber and Root Starches.” Carbohydr. Polym., 49 425–437 (2002)

    Article  Google Scholar 

  23. Overbeek, A, “Polymer Heterogeneity in Waterborne Coatings.” J. Coat. Technol. Res., 7 (1) 1–21 (2010)

    Article  Google Scholar 

  24. Deka, A, Dey, N, “Rheological Studies of Two Component High Build Epoxy and Polyurethane Based High Performance Coatings.” J. Coat. Technol. Res., 10 (3) 305–315 (2013)

    Article  Google Scholar 

  25. Yin, W, Zeng, X, Li, H, Lin, X, Ren, B, Tong, Z, “Steady Rheological Behaviors of UV-Curable Waterborne Hyperbranched Polyurethane Acrylate Dispersions.” J. Coat. Technol. Res., 10 (1) 57–64 (2013)

    Article  Google Scholar 

  26. Jin, Y, Cheng, X, Zheng, Z, “Preparation and Characterization of Phenol–Formaldehyde Adhesives Modified with Enzymatic Hydrolysis Lignin.” Bioresour. Technol., 101 (96) 2046–2048 (2010)

    Article  Google Scholar 

  27. Guo, M, Liu, M, Zhan, F, Wu, L, “Preparation and Properties of a Slow-Release Membrane-Encapsulated Urea Fertilizer with Superabsorbent and Moisture Preservation.” Ind. Eng. Chem. Res., 44 4206–4211 (2005)

    Article  Google Scholar 

  28. Trenkel, ME, Improving Fertilizer Use Efficiency. Controlled-Release and Stabilized Fertilizers in Agriculture. The International Fertilizer Industry Association, Paris, 1997

    Google Scholar 

  29. Ţolescu, C, Iovu, H, “Polymer Conditioned Fertilizers.” U.P.B. Sci. Bull. B, 72 (2) 3–14 (2010)

    Google Scholar 

  30. Controlled, SA, Fertilizers, R, IFA International Workshop on Enhanced-Efficiency Fertilizers, Frankfurt. International Fertilizer Industry Association, Paris, 2005

    Google Scholar 

  31. Engelsjord, ME, Fostad, O, Singh, BR, “Effects of Temperature on Nutrient Release from Slow-Release Fertilizers.” Nutr. Cycl. Agroecosyst., 46 (3) 179–187 (1996)

    Article  Google Scholar 

  32. Simonne, EH, Hutchinson, CM, “Controlled-Release Fertilizers for Vegetable Production in the Era of Best Management Practices: Teaching New Tricks to an Old Dog.” HortTechnology., 15 36–46 (2005)

    Google Scholar 

  33. Engelsjord, M, Fostad, O, Singh, B, “Effects of Temperature on Nutrient Release from Slow-Release Fertilizers.” Nutr. Cycl. Agroecosyst., 46 179 (1996)

    Article  Google Scholar 

  34. Lu, DR, Xiao, CM, Xu, SJ, “Starch-Based Completely Biodegradable Polymer Materials.” eXPRESS Polym. Lett., 6 (3) 366–375 (2009)

    Article  Google Scholar 

  35. Samyn, P, Schoukens, G, Abbeele, H, Vonck, L, Stanssens, D, “Application of Polymer Nanoparticle Coating for Tuning the Hydrophobicity of Cellulosic Substrates.” J. Coat. Technol. Res., 8 (3) 363–373 (2011)

    Article  Google Scholar 

  36. Choi, M, Meisen, A, “Hydrodynamics of Shallow, Conical Spouted Beds.” Can. J. Chem. Eng., 70 916–924 (1992)

    Article  Google Scholar 

  37. Choi, MMS, Meisen, A, “Sulfur Coating of Urea in Shallow Spouted Beds.” Chem. Eng. Sci., 52 (7) 1073–1086 (1997)

    Article  Google Scholar 

  38. Shi, R, Bi, J, Zhang, Z, et al., “The Effect of Citric Acid on the Structural Properties and Cytotoxicity of the Polyvinyl Alcohol/Starch Films When Molding at High Temperature.” Carbohydr. Polym., 74 (4) 763–770 (2008)

    Article  Google Scholar 

  39. Dash, S, Murthy, PN, Nath, L, Chowdhury, P, “Kinetic Modeling on Drug Release from Controlled Drug Delivery Systems.” Acta Pol. Pharm., 67 (3) 217–223 (2010)

    Google Scholar 

  40. Bourne, DW, “Pharmacokinetics.” In: Banker, GS, Rhodes, CT (eds.) Modern Pharmaceutics4th, pp. 67–92. Marcel Dekker Inc., New York, 2002

    Google Scholar 

  41. Mikhailova, A, Tamboura, M, Jia, M, “Synthesis, Characterization, and Analyses of Mechanical, Adhesion, and Thermal Properties of Polysiloxane Resin Modified with Segmented Polyurethane.” J. Coat. Technol. Res., 10 (1) 97–108 (2013)

    Article  Google Scholar 

  42. Tudorachi, N, Cascaval, CN, Rusu, M, “Testing of Polyvinyl Alcohol and Starch Mixtures as Biodegradable Polymeric Materials.” Polym. Test., 19 (7) 785–799 (2000)

    Article  Google Scholar 

  43. Chiellini, E, Corti, A, Solaro, R, “Biodegradation of Poly(vinyl alcohol) Based Blown Films Under Different Environmental Conditions.” Polym. Degrad. Stab., 62 (2) 305–312 (2009)

    Google Scholar 

Download references

Acknowledgments

This research work was partially funded by the Long Term Research Grant Scheme (LRGS) of the Ministry of Higher Education Malaysia No. 15-8200-137-4-3.

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Naz, M.Y., Sulaiman, S.A. Testing of starch-based carbohydrate polymer coatings for enhanced urea performance. J Coat Technol Res 11, 747–756 (2014). https://doi.org/10.1007/s11998-014-9590-y

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