Skip to main content
SpringerLink
Log in

Carbon dioxide reforming of methane to synthesis gas over LaNi1−x Cr x O3 perovskite catalysts

  • Catalysis, Reaction Engineering
  • Published:
Korean Journal of Chemical Engineering Aims and scope Submit manuscript

Abstract

Carbon dioxide reforming of methane was investigated over LaNi1−x Cr x O3 perovskite catalysts which were prepared by the malic acid method. The respective perovskite catalysts were a single phase of perovskite oxide without impurity phases. Their reduction behavior was characterized by temperature programmed reduction. In the LaNi1−x Cr x O3 perovskite catalysts, the catalytic activities were closely related to the reduction behavior of the catalysts, and the partial substitution of Cr to the B-site of perovskite catalysts promoted stability against reduction. When the x values were lower than 0.4, the LaNi1−x Cr x O3 perovskite catalysts were decomposed to La2O3 and Ni and the decomposition of perovskite structure led to large coke deposition. When the x values were higher than 0.4, the LaNi1−x Cr x O3 perovskite catalysts showed reduced catalytic activity but became stable to reduction and coke formation in the reforming reaction.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Y. H. Hu and E. Ruckenstein, Adv. Catal., 48, 297 (2004).

    Article  CAS  Google Scholar 

  2. M. S. Fan, A. Z. Abdullah and S. Bhatia, ChemCatChem, 1, 192 (2009).

    Article  CAS  Google Scholar 

  3. A. T. Ashcroft, A. K. Cheetham, M. L.H. Green and P. D. F. Vernon, Nature, 452, 225 (1991).

    Article  Google Scholar 

  4. J. M. Fox, Catal. Rev. Sci. Eng., 35, 169 (1993).

    Article  CAS  Google Scholar 

  5. J.R. Rostrup-Nielsen and J. H.B. Hansen, J. Catal., 144, 38 (1993).

    Article  CAS  Google Scholar 

  6. Z. Zhang and X. E. Verykios, J. Chem. Soc., Chem. Commun., 71 (1995).

  7. Y. H. Hu and E. Ruckenstein, J. Catal., 163, 306 (1996).

    Article  CAS  Google Scholar 

  8. R. N. Bhat and W.M. H. Sachtler, Appl. Catal. A: Gen., 150, 279 (1997).

    Article  CAS  Google Scholar 

  9. H.Y. Wang and C. T. Au, Appl. Catal. A: Gen., 155, 239 (1997).

    Article  CAS  Google Scholar 

  10. S. M. Stagg, E. Romeo, C. Padro and D. E. Resasco, J. Catal., 178, 137 (1998).

    Article  CAS  Google Scholar 

  11. M. C. J. Bradford and M.A. Vannice, J. Catal., 183, 69 (1999).

    Article  CAS  Google Scholar 

  12. M.C. J. Bradford and M. A. Vannice, Catal. Rev. Sci. Eng., 41, 1 (1999).

    Article  CAS  Google Scholar 

  13. G. C. de Araujo, S.M. de Lima, J. M. Assaf, M. A. Pena, J. L.G. Fierro and M. C. Rangel, Catal. Today, 133–135, 129 (2008).

    Article  Google Scholar 

  14. Y. G. Chen and J. Ren, Catal. Lett., 29, 39 (1994).

    Article  CAS  Google Scholar 

  15. V. R. Choudhary, B. S. Uphade and A. S. Mamman, Catal. Lett., 32, 387 (1995).

    Article  CAS  Google Scholar 

  16. V. R. Choudhary, B. S. Uphade and A. A. Belhekar, J. Catal., 163, 312 (1996).

    Article  CAS  Google Scholar 

  17. Z. L. Zhang, X. E. Verykios, S. M. MacDonald and S. J. Affrossman, J. Phys. Chem., 100, 744 (1996).

    Article  CAS  Google Scholar 

  18. Z. L. Zhang and X. E. Verykios, Appl. Catal. A: Gen., 138, 109 (1996).

    Article  CAS  Google Scholar 

  19. Z. Cheng, Q. Wu, J. Li and Q. Zhu, Catal. Today, 30, 147 (1996).

    Article  CAS  Google Scholar 

  20. V. R. Choudhary and A.M. Rajput, Ind. Eng. Chem. Res., 35, 3934 (1996).

    Article  CAS  Google Scholar 

  21. H. Kim, S. J. Lee and K. S. Song, Korean J. Chem. Eng., 24, 477 (2007).

    Article  Google Scholar 

  22. F. Solymosi, G. Kutsan and A. Erdohelyi, Catal. Lett., 11, 149 (1991).

    Article  CAS  Google Scholar 

  23. A. Erdohelyi, E. Cserényi and F. Solymosi, J. Catal., 141, 287 (1993).

    Article  CAS  Google Scholar 

  24. D. Qin and J. Lapszewicz, Catal. Today, 21, 551 (1994).

    Article  CAS  Google Scholar 

  25. M. F. Mark and W. F. Maier, J. Catal., 164, 122 (1996).

    Article  CAS  Google Scholar 

  26. K. Nagaoka, K. Takanabe and K. Aika, Appl. Catal. A: Gen., 268, 151 (2004).

    Article  CAS  Google Scholar 

  27. Z.Y. Hou, P. Chen, H. L. Fang, X.M. Zheng and T. Yashima, Int. J. Hydrog. Energy, 31, 555 (2006).

    Article  CAS  Google Scholar 

  28. A. Sauvet, J. Guindet and J. Fouletier, IONICS, 5, 150 (1999).

    Article  CAS  Google Scholar 

  29. M. E. Rivas, J. L. G. Fierro, M. R. Goldwasser, E. Pietri, M. J. Pérez-Zurita, A. Griboval-Constant and G. Leclercq, Appl. Catal. A: Gen., 344, 10 (2008).

    Article  CAS  Google Scholar 

  30. M. Stojanovic, R.G. Haverkamp, C. A. Mims, H. Moudallal and A. J. Jacobson, J. Catal., 166, 315 (1997).

    Article  CAS  Google Scholar 

  31. Y. Wu, O. Kawaguchi and T. Matsuda, Bull. Chem. Soc. Jpn., 71, 563 (1998).

    Article  CAS  Google Scholar 

  32. G. Valderrama, A. Kiennemann and M.R. Goldwasser, Catal. Today, 133–135, 142 (2008).

    Article  Google Scholar 

  33. T. Nakamura, G. Petzow and L. J. Gauckler, Mater. Res. Bull., 14, 649 (1979).

    Article  CAS  Google Scholar 

  34. J.W. Erning, T. Hauber, U. Stimming and K. Wippermann, J. Power Sources, 61, 205 (1996).

    Article  CAS  Google Scholar 

  35. J. L. G. Fierro and L. G. Tejuca, Appl. Surf. Sci., 27, 453 (1987).

    Article  CAS  Google Scholar 

  36. L.G. Tejuca and J. L.G. Fierro, Thermochim. Acta, 147, 361 (1989).

    Article  CAS  Google Scholar 

  37. H. Provendier, C. Petit, C. Estournes, S. Libs and A. Kiennemann, Appl. Catal. A: Gen., 180, 163 (1999).

    Article  CAS  Google Scholar 

  38. D. L. Trimm, Catal. Rev. Sci. Eng., 16, 155 (1977).

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Department of Chemical and Biological Engineering, Korea University, Anam-dong, Seongbuk-gu, Seoul, 136-713, Korea

    Joonho Kim, Taeyoon Kim, Ki Bong Lee & Suk-In Hong

  2. Eco-Composite Materials Center, Korea Institute of Ceramic Engineering and Technology, Gasan-dong, Guemcheon-gu, Seoul, 153-801, Korea

    Jung Whan Yoo

Authors
  1. Joonho Kim
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Taeyoon Kim
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Jung Whan Yoo
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Ki Bong Lee
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. Suk-In Hong
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Ki Bong Lee.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Kim, J., Kim, T., Yoo, J.W. et al. Carbon dioxide reforming of methane to synthesis gas over LaNi1−x Cr x O3 perovskite catalysts. Korean J. Chem. Eng. 29, 1329–1335 (2012). https://doi.org/10.1007/s11814-012-0057-5

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11814-012-0057-5

Key words

Search

Navigation