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Effects of sodium dodecyl benzenesulfonic acid (SDBS) on the morphology and the crystal phase of CaCO3

  • Materials (Organic, Inorganic, Electronic, thin Films)
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Abstract

The effects of anionic surfactant on the morphology and crystallization of calcium carbonate precipitated from CaCl2 and Na2CO3 were investigated. Although reaction temperature did not have an effect on the morphology of calcium carbonate, it did have an effect on the cluster size. The cluster size became bigger with high reaction temperature. With the addition of sodium dodecyl benzenesulfonic acid (SDBS), the morphology of precipitated calcium carbonate changed from cubic to porous spheres with over 98% of the crystal phase transformed from calcite to vaterite. The analysis of precipitates formed by the reaction of CaCl2 solution (from limestone (CaO 50% content)) and Na2CO3 found that the morphology of precipitated calcium carbonate changed from cubic to spherical, and the crystal phase changed from calcite to over 94% vaterite with the addition of sodium dodecyl benzenesulfonic acid. These vaterite structures were solid spheres rather than hollow ones.

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Authors and Affiliations

  1. Korea Institute of Limestone and Advanced Materials, 63, Wooduk-ri, Maepo-up, Danyang-gun, Chungbuk, 395-903, Korea

    Dae Ju Hwang, Kye Hong Cho, Moon Kwan Choi, Young Hwan Yu & Seung Kwan Lee

  2. Mineral Processing Department, Mineral Resources Research Division, Korea Institute of Geoscience and Mineral Resources, 92-Science-ro, Yuseong-gu, Daejeon, 305-350, Korea

    Ji Whwan Ahn

  3. Department of Chemical Engineering, Kwangwoon University, 447-1 Wolgye-dong, Nowon-gu, Seoul, 139-701, Korea

    Gwang Il Lim & Choon Han

  4. Department of Chemical Engineering, Chungbuk National University, 410 Sungong-ro, Heungduk-gu, Chung-ju, Chungbuk, 361-763, Korea

    Dae Ju Hwang & Jong Dae Lee

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  1. Dae Ju Hwang
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  2. Kye Hong Cho
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  3. Moon Kwan Choi
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  4. Young Hwan Yu
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  5. Seung Kwan Lee
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  6. Ji Whwan Ahn
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  7. Gwang Il Lim
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  8. Choon Han
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  9. Jong Dae Lee
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Correspondence to Choon Han.

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Hwang, D.J., Cho, K.H., Choi, M.K. et al. Effects of sodium dodecyl benzenesulfonic acid (SDBS) on the morphology and the crystal phase of CaCO3 . Korean J. Chem. Eng. 28, 1927–1935 (2011). https://doi.org/10.1007/s11814-011-0044-2

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  • DOI: https://doi.org/10.1007/s11814-011-0044-2

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