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Leaching toxicity characteristics of municipal solid waste incineration bottom ash

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Abstract

The continuously increasing production of municipal solid waste incineration bottom ash (MSWIBA) has promoted its utilization as construction material and raised environmental concern. The physico-chemical properties and leaching behavior of MSWIBA were studied, and ecotoxicological testing using a luminescent bacterium bioassay was performed to assess the ecological pollution risks associated with its leached constituents. The MSWIBA was leached by two types of leachants, H2SO4/HNO3 and HAc solution, at different liquid to solid ratios and contact times. The concentrations of heavy metals and anions in the leachates were analyzed. Multivariate statistical analyses, including principle component analysis, Pearson’s correlation analysis and hierarchical cluster analysis, were used to evaluate the contributions of the constituents to the toxicity (EC 50) of the MSWIBA leachate. The statistical analyses of the ecotoxicological results showed that the Ba, Cr, Cu, Pb, F−and total organic carbon (TOC) concentrations were closely correlated with the EC 50 value, and these substances were the main contributors to the ecotoxicity of the MSWIBA leachate. In addition, the cluster of these variables indicated similar leaching behaviors. Overall, the research demonstrated that the ecotoxicological risks resulting from MSWIBA leaching could be assessed before its utilization, which provides crucial information for the adaptation of MSWIBA as alternative materials.

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Authors and Affiliations

  1. State Key Laboratory of Pollution Control & Resource Reuse, Tongji University, Shanghai, 200092, China

    Khamphe Phoungthong, Yi Xia & Hua Zhang

  2. Institute of Waste Treatment and Reclamation, Tongji University, Shanghai, 200092, China

    Liming Shao & Pinjing He

  3. Centre for the Technology Research and Training on Household Waste in Small Towns & Rural Area, Ministry of Housing and Urban–Rural Development of PR China (MOHURD), Shanghai, 200092, China

    Liming Shao & Pinjing He

Authors
  1. Khamphe Phoungthong
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  2. Yi Xia
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  3. Hua Zhang
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  4. Liming Shao
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  5. Pinjing He
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Correspondence to Hua Zhang.

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Phoungthong, K., Xia, Y., Zhang, H. et al. Leaching toxicity characteristics of municipal solid waste incineration bottom ash. Front. Environ. Sci. Eng. 10, 399–411 (2016). https://doi.org/10.1007/s11783-015-0819-5

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  • DOI: https://doi.org/10.1007/s11783-015-0819-5

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