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Experimental measurements of water content in crude oil emulsions by terahertz time-domain spectroscopy

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Abstract

We measured the water content (0.01%–0.25% w/w) in crude oil emulsions using terahertz time-domain spectroscopy (THz-TDS). To improve the precision and range of the measurements, we used 1 and 10 mm thick quartz cells. The experiments were performed at 20 °C and the THz wave was transmitted vertically to the samples and detected on the other side. The experimental results suggest linear relation for the THz absorption coefficient and the water content of the crude oil emulsions in the observed range. The linear dependence facilitates high-precision measurements of the water content of crude oil. This suggests the potential of THz-TDS in determining the water concentration in crude oil and borehole fluid identification.

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References

  • Banerjee, D., Spiegel, W. von, Thomson, M. D., Schabel, S., and Roskos, H. G., 2008, Diagnosing water content in paper by terahertz radiation: Opt. Express, 16, 9060–9066.

    Article  Google Scholar 

  • George, P. A., Hui, W., Rana, F., Hawkins, B. G., Simth, A. E., and Kirby, B. J., 2008, Microfluidic devices for terahertz spectroscopy of biomolecules: Opt. Express, 16, 1577–1582.

    Article  Google Scholar 

  • Gorenflo, S., Tauer, U., Hinkov, I., Lambrecht, A., Buchner, R., and Helm H., 2006, Dielectric properties of oil-water complexes using terahertz transmission spectroscopy: Chem. Phys. Lett., 421, 494–498.

    Article  Google Scholar 

  • Grischkowsky, D., Keiding, S., Van Exter, M., and Fattinger, C., 1990, Far-infrared time domain spectroscopy with terahertz beams of dielectrics and semiconductors: J. Opt. Soc. Am. B, 7, 2006–2015.

    Article  Google Scholar 

  • Hadjiloucas, S., Karatzas, L. S., and Bowen, J. W., 1999, Measurements of leaf water content using terahertz radiation: IEEE Transactions on Microwave Theory and Techniques, 47, 142–149.

    Article  Google Scholar 

  • Kristensen, T. T. L., Withayachumnankul, W., Jepsen, P. U., and Abbott, D., 2010, Modeling terahertz heating effects on water: Opt. Express, 18, 4727–4739.

    Article  Google Scholar 

  • Löffler, T., Hahn, T., Thomson, M., Jacob, F., and Roskos, H. G., 2005, Large-area electro-optic ZnTe terahertz emitters: Opt. Express, 13, 5353–5362.

    Article  Google Scholar 

  • Tonouchi, M., 2007, Cutting-edge terahertz technology; Nature Photonics, 1, 97–105.

    Article  Google Scholar 

  • Withayachumnankul, W., Fischer, B. M., and Abbott, D., 2008, Material thickness optimization for transmissionmode terahertz time-domain spectroscopy: Opt. Express, 16, 7382–7396.

    Article  Google Scholar 

  • Vij, J. K., Simpson, D. R. J., and Panarina, O. E., 2004, Far infrared spectroscopy of water at different temperatures: GHz to THz dielectric spectroscopy of water: Journal of Molecular Liquids, 112, 125–135

    Article  Google Scholar 

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Correspondence to Kun Zhao.

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This research is sponsored jointly by the National Key Basic Research Program of China (No. 2013CB328706), the Special-funded Program on National Key Scientific Instruments and Equipment Development (No. 2012YQ140005), the Beijing National Science Foundation (No. 4122064) and the Science Foundation of China University of Petroleum (Beijing) (No. QZDX-2010-01 and KYJJ2012-06-27).

Jin Wu-Jun is a PhD student in China University of Petroleum, Beijing. He graduated from Yangtze University and received Bachelor degree in 2008 and received his Master degree from China University of Petroleum (Beijing) in 2011. His main research focus is on oil-gas optics and down-hole fluid identification.

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Jin, WJ., Zhao, K., Yang, C. et al. Experimental measurements of water content in crude oil emulsions by terahertz time-domain spectroscopy. Appl. Geophys. 10, 506–509 (2013). https://doi.org/10.1007/s11770-013-0404-2

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  • DOI: https://doi.org/10.1007/s11770-013-0404-2

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