Abstract
The syngas composition characteristic was investigated in the real slurry-feed gasifier using a detailed gas phase reaction mechanism. The results show that the time for syngas to reach equilibrium is much shorter than the residence time for slurry feed entrained-flow gasifiers, indicating a gas phase species partial equilibrium state. Further calculation shows that the four major species, CO, CO2, H2, and H2O, are in equilibrium via the reaction CO + H2O ⇔ CO2+H2. Suggestions are provided for future modeling and model validation.
Similar content being viewed by others
References
Maustad O. An overview of coal based integrated gasification combined cycle (IGCC) technology. 2005, http://lfee.mit.edu/public/LFEE_2005-002_WP5.pdf
Ruggiero M, Manfrida G. An equilibrium model for biomass gasification processes. Renewable Energy, 1999, 16(1–4): 1106–1109
Chern S M, Wallawender W P, Fan L T. Equilibrium modeling of a downdraft gasifier. 1. overall gasifier. Chemical Engineering Communications, 1991, 108(1): 243–265
Li X, Grace J, Watkinson A, et al. Equilibrium modeling of gasification: a free energy minimization approach and its application to a circulating fluidized bed coal gasifier. Fuel, 2001, 80(2): 195–207
Li Z, Wang T, Han Z, et al. Study of mathematical model for Texaco gaifier (I)-Modeling. Power Engineering, 2001, 21(2): 1316–1319
Li Z, Wang T, Han Z, et al. Study of mathematical model for Texaco gaifier (II)-Calculation and analysis. Power Engineering, 2001, 21(4): 1161–1168
Ruprecht P, Schafer W, Wallace P. A computer model of entrained coal gasification. Fuel, 1988, 67(6): 739–742
Chen C, Horio M, Kojima T., Numerical simulation of entrained flow coal gasifiers. Part I: Modeling of coal gasification in an entrained flow gasifier. Chemical Engineering Science, 2000, 55(8): 3861–3874
Chen C, Horio M, Kojima T. Numerical simulation of entrained flow coal gasifiers. Part II: Effects of operating conditions on gasifier performance. Chemical Engineering Science, 2000, 55(8): 3875–3883
Chen C, Horio M, Kojima T. Use of numerical modeling in the design and scale-up of entrained flow coal gasifiers. Fuel, 2001, 80(10): 1513–1523
Choi Y, Li X, Park T, et al. Numerical study on the coal gasification characteristics in an entrained flow coal gasifier. Fuel, 2001, 80(15): 2193–2201
Cho H. A numerical study on parametric sensitivity of the flow characteristics on pulverized coal gasification. International Journal Energy Research, 2000, 24(6): 511–523
Vicente W, Ochoa S, Aguillon J, et al. An Eulerian model for the simulation of an entrained flow coal gasifier. Applied Thermal Engineering, 2003, 23(15): 1993–2008
Perkins G, Sahajwalla V. A mathematical model for the chemical reaction of a semi-infinite block of coal underground coal gasification. Energy & Fuels, 2005, 19(4): 1679–1692
Li J, Zhao Z, Kazakov A, et al. A comprehensive kinetic mechanism for CO, CH2O, and CH3OH combustion. International Journal of Chemical Kinetics, 2007, 39(3): 109–136
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Wang, Z., Yang, J., Li, Z. et al. Syngas composition study. Front. Energy Power Eng. China 3, 369–372 (2009). https://doi.org/10.1007/s11708-009-0044-7
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s11708-009-0044-7