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Activated carbon-hybridized and amine-modified polyacrylonitrile nanofibers toward ultrahigh and recyclable metal ion and dye adsorption from wastewater

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Abstract

Nanofibers with high specific surface area and chemical stability have broad prospects in the applications of adsorption. However, the adsorption capacity is limited by the scarcity of adsorption groups and storage space. Herein, the activated carbon-hybridized and amine-modified nanofibers are prepared by integrating activated carbon (AC) and polyacrylonitrile (PAN) via electrospinning method and the subsequent amination, which could provide additional storage space and adsorption groups for ultrahigh adsorption capability. Thus, the obtained aminerich porous PAN nanofibers (APAN/AC) readily realized the ultrahigh adsorption capacity for metal ions and dyes in wastewater. Specifically, the adsorption capacity of APAN/AC nanofibers were 284 mg·g−1 for Cr(VI) and 248 mg·g−1 for methyl orange, which were almost 2 and 4 times than that of amine-modified nanofibers (APAN) and carbon-hybridized nanofibers (PAN/AC), respectively. Moreover, the AC inhibited the chain mobility of polymer matrix and thereby endowing APAN/AC nanofibers with excellent recyclability. The adsorption capability retained 80% after nine adsorption-desorption cycles. The adsorption kinetics and corresponding mechanism were further explored. This strategy combines the advantages of polymer nanofibers and AC, opening a new avenue for developing next-generation absorbent materials.

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Acknowledgements

This work is supported by Natural Science Foundation of Henan Province (Grant No. 182300410276), the National Natural Science Foundation of China (Grant No. 51904274) and Program for Innovative Research Team (in Science and Technology) in University of Henan Province (Grant No. 19IRTSTHN028).

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Authors and Affiliations

  1. School of Chemical Engineering, Zhengzhou University, Zhengzhou, 450001, China

    Fengli Li, Chuang Chen, Yuda Wang, Wenpeng Li, Guoli Zhou, Haoqin Zhang, Jie Zhang & Jingtao Wang

  2. Henan Institute of Advanced Technology, Zhengzhou University, Zhengzhou, 450003, China

    Jingtao Wang

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  1. Fengli Li
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  2. Chuang Chen
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  3. Yuda Wang
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  4. Wenpeng Li
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  5. Guoli Zhou
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  6. Haoqin Zhang
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  7. Jie Zhang
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Correspondence to Guoli Zhou or Jie Zhang.

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11705_2020_2000_MOESM1_ESM.pdf

Activated carbon-hybridized and amine-modified polyacrylonitrile nanofibers toward ultrahigh and recyclable metal ion and dye adsorption from wastewater

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Li, F., Chen, C., Wang, Y. et al. Activated carbon-hybridized and amine-modified polyacrylonitrile nanofibers toward ultrahigh and recyclable metal ion and dye adsorption from wastewater. Front. Chem. Sci. Eng. 15, 984–997 (2021). https://doi.org/10.1007/s11705-020-2000-3

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  • DOI: https://doi.org/10.1007/s11705-020-2000-3

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