Skip to main content
SpringerLink
Log in

Preparation of starch esters with crosslinking structures derived from dianhydride

  • Research Article
  • Published:
Frontiers of Chemical Science and Engineering Aims and scope Submit manuscript

Abstract

Starch is a kind of natural polymer used in many industrial fields because of its low cost, availability and biodegradation. Potato starch was modified by esterification with pyromellitic dianhydride, and the products were obtained with crosslinking structures. Orthogonal experiments showed that reactive temperature was the primary influencing factor. The product prepared at 40°C for 3 h with the mass ratio of starch and dianhydride of 16:1 and pH value of 7.5 exhibited a degree of substitution of 11%. FTIR and UV analysis verified the formation of starch esters.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Zhou J, Zhang J, Ma Y, Tong J. Surface photo-crosslinking of corn starch sheets. Carbohydrate Polymers, 2008, 74(3): 405–410

    Article  CAS  Google Scholar 

  2. Shi R, Bi J, Zhang Z, Zhu A, Chen D, Zhou X, Zhang L, Tian W. The effect of citric acid on the structural properties and cytotoxicity of the polyvinyl alcohol/starch films when molding at high temperature. Carbohydrate Polymers, 2008, 74(4): 763–770

    Article  CAS  Google Scholar 

  3. Simi C K, Emilia Abraham T. Hydrophobic grafted and cross-linked starch nanoparticles for drug delivery. Bioprocess and Biosystems Engineering, 2007, 30(3): 173–180

    Article  CAS  Google Scholar 

  4. Deetae P, Shobsngob S, Varanyanond W, Chinachoti P, Naivikul O, Varavinit S. Preparation, pasting properties and freeze-thaw stability of dual modified crosslink-phosphorylated rice starch. Carbohydrate Polymers, 2008, 73(2): 351–358

    Article  CAS  Google Scholar 

  5. Zhang J, Li A, Wang A. Zhang J, Li A, Wang A. Study on superabsorbent composite. VI. Preparation, characterization and swelling behaviors of starch phosphate-graft-acrylamide/attapulgite superabsorbent composite. Carbohydrate Polymers, 2006, 65(2): 150–158

    Article  CAS  Google Scholar 

  6. Delville J. Delville J, Joly C, Dole P, Bliard C. Influence of photocrosslinking on the retrogradation of wheat starch based films. Carbohydrate Polymers, 2003, 53(4): 373–381

    Article  CAS  Google Scholar 

  7. Delville J. Delville J, Joly C, Dole P, Bliard C. Solid state photocrosslinked starch based films: a new family of homogeneous modified starches. Carbohydrate Polymers, 2002, 49(1): 71–81

    Article  CAS  Google Scholar 

  8. Staroszczyk H. Microwave-assisted silication of potato starch. Carbohydrate Polymers, 2009, 77(3): 506–515

    Article  CAS  Google Scholar 

  9. El-Tahlawy K, Venditti R A, Pawlak J J. Aspects of the preparation of starch microcellular foam particles crosslinked with glutaraldehyde using a solvent exchange technique. Carbohydrate Polymers, 2007, 67(3): 319–331

    Article  CAS  Google Scholar 

  10. Juntanon K, Niamlang S, Rujiravanit R, Sirivat A. Electrically controlled release of sulfosalicylic acid from crosslinked poly(vinyl alcohol) hydrogel. International Journal of Pharmaceutics, 2008, 356(1–2): 1–11

    Article  CAS  Google Scholar 

  11. Dae H K, Seong K N, Jong S P, Kee J Y, Dae W I. Studies on the preparation of hydrolyzed starch-g-PAN (HSPAN)/PVA blend films-effect of the reaction with epichlorohydrin. European Polymer Journal, 2002, 38(6): 1199–1204

    Article  Google Scholar 

  12. Du Y L, Cao Y, Lu F, Li F, Cao Y, Wang X L, Wang Y Z. Biodegradation behaviors of thermoplastic starch (TPS) and thermoplastic dialdehyde starch (TPDAS) under controlled composting conditions. Polymer Testing, 2008, 27(8): 924–930

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. School of Chemistry and Chemical Engineering, Henan University of Technology, Zhengzhou, 450001, China

    Huijuan Chu, Hongliang Wei, Jing Zhu & Shouyin Hu

Authors
  1. Huijuan Chu
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Hongliang Wei
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Jing Zhu
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Shouyin Hu
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Huijuan Chu.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Chu, H., Wei, H., Zhu, J. et al. Preparation of starch esters with crosslinking structures derived from dianhydride. Front. Chem. Sci. Eng. 5, 51–54 (2011). https://doi.org/10.1007/s11705-010-0534-5

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11705-010-0534-5

Keywords

Search

Navigation