Abstract
The effects of aging treatment on corrosion properties of an extruded Mg-8.9Gd-2.8Y-1.8Zn-0.4Zr-0.2Ca (wt.%) alloy were investigated. The as-extruded alloy was consisted of un-dynamically recrystallized region containing lamellar long period stacking ordered (LPSO) phase and block-shaped LPSO phase, finely recrystallized grains and small amounts of Mg-RE phase. After aging treatment, part of lamellar LPSO phases was dissolved into the matrix and replaced by recrystallized grains. The size of recrystallized grain was increased from 1.8 μm for the as-extruded sample and to 3.5 μm for the peak-aged sample. Corrosion tests indicated that aging treatment effectively improved the corrosion resistance of the as-extruded Mg-8.9Gd-2.8Y-1.8Zn-0.4Zr-0.2Ca (wt.%) alloy. The lamellar LPSO phases with a low potential were preferentially corroded, and the homogeneous microstructure of the peak-aged sample effectively reduced the possibility of micro-galvanic corrosion. Hence, the peak-aged sample with a more homogeneous microstructure and small amount of lamellar LPSO phase showed a better corrosion resistance.
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K. Nie, X. Kang, K. Deng, Y. Guo, J. Han and Z. Zhu, Development of Mg-Zn-Y-Ca Alloys Containing Icosahedral Quasicrystal Phase Through Trace Addition of Y, J. Mater. Res., 2018, 33(18), p 2806–2816.
S.H. Huang, Microstructure and Mechanical Properties of a Ag Micro-Alloyed Mg-5Sn Alloy, J. Mater. Eng. Perform., 2018, 27(7), p 3199–3205.
H. Mirzadeh, High Strain Rate Superplasticity Via Friction Stir Processing (FSP): A Review, Mater. Sci. Eng. A, 2021, 819, p 141499.
A. Heinz, A. Haszler, C. Keidel, S. Moldenhauer, R. Benedictus and W.S. Miller, Recent Development in Aluminium Alloys for Aerospace Applications, Mater. Sci. Eng. A, 2000, 280(1), p 102–107.
H. Mirzadeh, Quantification of the Strengthening Effect of Rare Earth Elements During Hot Deformation of Mg-Gd-Y-Zr Magnesium Alloy, J. Mater. Res. Technol., 2016, 5(1), p 1–4.
Y.Z. Du, D.J. Liu and Y.F. Ge, Effects of Ce Addition on Mechanical and Corrosion Properties of the As-Extruded Mg-Zn-Ca Alloy, J. Mater. Eng. Perform., 2021, 30(1), p 488–496.
V.E. Bazhenov, S.S. Saidov, Y.V. Tselovalnik, O.O. Voropaeva, I.V. Plisetskaya, A.A. Tokar, A.I. Bazlov, V.A. Bautin, A.A. Komissarov, A.V. Koltygin and V.D. Belov, Comparison of Castability, Mechanical, and Corrosion Properties of Mg-Zn-Y-Zr Alloys Containing LPSO and W Phases, Trans. Nonferr. Metal. Soc., 2021, 31(5), p 1276–1290.
M. Lotfpour, M. Emamy and C. Dehghanian, Influence of Cu Addition on the Microstructure, Mechanical, and Corrosion Properties of Extruded Mg-2%Zn Alloy, J. Mate. Eng. Perform., 2020, 29(5), p 2991–3003.
L.B. Tong, J.H. Chu, W.T. Sun, C. Xu, D.N. Zou, K.S. Wang, S. Kamado and M.Y. Zheng, Achieving an Ultra-High Strength and Moderate Ductility in Mg-Gd-Y-Zn-Zr Alloy Via a Decreased-Temperature Multi-directional Forging, Mater. Charact., 2021, 171, p 110804.
K. Li, V.S.Y. Injeti, R.D.K. Misra, L.G. Meng and X.G. Zhang, The Contribution of Long-Period Stacking-Ordered Structure (LPSO) to High Strength-High Ductility Combination and Nanoscale Deformation Behavior of Magnesium-Rare Earth Alloy, Mater. Sci. Eng. A, 2018, 713, p 112–117.
C.Q. Li, D.K. Xu, Z.R. Zeng, B.J. Wang, L.Y. Sheng, X.B. Chen and E.H. Han, Effect of Volume Fraction of LPSO Phases on Corrosion and Mechanical Properties of Mg-Zn-Y Alloys, Mater. Des., 2017, 121, p 430–441.
J. Wang, T. Li, H.X. Li, Y.Z. Ma, K.N. Zhao, C.L. Yang, J.S. Zhang, Effect of Trace Ni Addition on Microstructure, Mechanical and Corrosion Properties of the Extruded Mg-Gd-Y-Zr-Ni Alloys for Dissoluble Fracturing Tools, J. Magnes. Alloy., 2020 (in press).
S. Yin, W. Duan, W. Liu, L. Wu and Z. Zhang, Influence of Specific Second Phases on Corrosion Behaviors of Mg-Zn-Gd-Zr Alloys, Corros. Sci., 2019, 166, p 108419.
M. Yamasaki, S. Izumi, Y. Kawamura and H. Habazaki, Corrosion and Passivation Behavior of Mg-Zn-Y-Al Alloys Prepared by Cooling Rate-Controlled Solidification, Appl. Surf. Sci., 2011, 257(19), p 8258–8267.
Y. Wang, Y. Zhang, P. Wang, D. Zhang and H. Jiang, Effect of LPSO Phases and Aged-Precipitations on Corrosion Behavior of as-Forged Mg-6Gd-2Y-1Zn-0.3Zr Alloy, J. Mater. Res. Technol., 2020, 9(4), p 7087–7099.
L. Wu and H. Li, Effect of Selective Oxidation on Corrosion Behavior of Mg-Gd-Y-Zn-Zr Alloy, Corros. Sci., 2018, 142, p 238–248.
J.F. Nie and B.C. Muddle, Precipitation Hardening of Mg-Ca(-Zn) Alloys, Scr. Mater., 1997, 37(37), p 1475–1481.
C. Xu, T. Nakata, X.G. Qiao, H.S. Jiang, W.T. Sun, Y.C. Chi, M.Y. Zheng and S. Kamado, Effect of Extrusion Parameters on Microstructure and Mechanical Properties of Mg-7.5Gd-2.5Y-3.5Zn-0.9Ca-0.4Zr (wt%) alloy, Mater. Sci. Eng. A, 2017, 685, p 159–167.
H. Jiang, X. Qiao, C. Xu, S. Kamado, K. Wu and M. Zheng, Influence of Size and Distribution of W Phase on Strength and Ductility of High Strength Mg-5.1Zn-3.2Y-0.4Zr-0.4Ca Alloy Processed by Indirect Extrusion, J. Mater. Sci. Technol., 2018, 34(2), p 277–283.
T. Chen, Z. Chen, J. Shao, R. Wang, L. Mao and C. Liu, Evolution of LPSO Phases in a Mg-Zn-Y-Gd-Zr Alloy During Semi-Continuous Casting, Homogenization and Hot Extrusion, Mater. Des., 2018, 152, p 1–9.
Y.M. Zhu, M. Weyland, A.J. Morton, K. Oh-Ishi, K. Hono and J.F. Nie, The Building Block of Long-Period Structures in Mg-RE-Zn Alloys—ScienceDirect, Scr. Mater., 2009, 60(11), p 980–983.
C. Xu, S.W. Xu, M.Y. Zheng, K. Wu, E.D. Wang, S. Kamado, G.J. Wang and X.Y. Lv, Microstructures and Mechanical Properties of High-Strength Mg-Gd-Y-Zn-Zr Alloy Sheets Processed by Severe Hot Rolling, J. Alloys Compd., 2012, 524, p 46–52.
H.X. Shao, Q.Z. Yang and L.X. Ma, Strengthening and Toughening Mechanisms in Mg-Zn-Y Alloy with a Long Period Stacking Ordered Structure, Acta Mater., 2010, 58(14), p 4760–4771.
J.D. Robson, D.T. Henry and B. Davis, Particle Effects on Recrystallization in Magnesium–Manganese Alloys: Particle-Stimulated Nucleation, Acta Mater., 2009, 57(9), p 2739–2747.
A. Jx, B. Zca, A. Js, C.A. Tao, L.A. Xia, A. Cl, Evolution of Long-Period Stacking Ordered Phases and Their Effect on Recrystallization in Extruded Mg-Gd-Y-Zn-Zr alloy During Annealing—ScienceDirect, Mater. Charact., 2020, 167. (in press).
Y.Z. Bao, Y. Adachi, Y. Toomine, P.G. Xu, T. Suzuki and Y. Tomota, Dynamic Recrystallization by Rapid Heating Followed by Compression for a 17Ni-0.2 C Martensite Steel, Scr. Mater., 2005, 53(12), p 1471–1476.
L. Liu, X. Zhou, S. Yu, J. Zhang and Z. Su, Effects of Heat Treatment on Mechanical Properties of an Extruded Mg-4.3Gd-3.2Y-1.2Zn-0.5Zr Alloy and Establishment of its Hall–Petch Relation, J. Magnes. Alloys, 2020 (in press).
C. Xu, M.Y. Zheng, K. Wu, E.D. Wang and Y.T. Liu, Effect of Final Rolling Reduction on the Microstructure and Mechanical Properties of Mg-Gd-Y-Zn-Zr Alloy Sheets, Mater. Sci. Eng. A, 2013, 559, p 232–240.
C. Xu, M.Y. Zheng, K. Wu, E.D. Wang, G.H. Fan, S.W. Xu, S. Kamado, X.D. Liu, G.J. Wang and X.Y. Lv, Effect of Ageing Treatment on the Precipitation Behaviour of Mg-Gd-Y-Zn-Zr Alloy, J. Alloys Compd., 2013, 550, p 50–56.
Y. Meng, J. Yu, K. Liu, H. Yu and H. Wang, The Evolution of Long-Period Stacking Ordered Phase and Its Effect on Dynamic Recrystallization in Mg-Gd-Y-Zn-Zr Alloy Processed by Repetitive Upsetting-Extrusion, J. Alloys Compd., 2020, 828, p 154454.
J. Zhang, J. Xu, W. Cheng, C. Chen and J. Kang, Corrosion Behavior of Mg-Zn-Y Alloy with Long-Period Stacking Ordered Structures, J. Mater. Sci. Technol., 2012, 28(12), p 1157–1162.
J. Liu, Y. Song, J. Chen, P. Chen, D. Shan and E.-H. Han, The Special Role of Anodic Second Phases in the Micro-galvanic Corrosion of EW75 Mg Alloy, Electrochim. Acta, 2016, 189, p 190–195.
F. Shi, C.-Q. Wang and Z.-M. Zhang, Microstructures, Corrosion and Mechanical Properties of As-Cast Mg-Zn-Y-(Gd) alloys, Trans. Nonferr. Metal. Soc., 2015, 25(7), p 2172–2180.
J. Liu, L. Yang, C. Zhang, B. Zhang and T. Zhang, Significantly Improved Corrosion Resistance of Mg-15Gd-2Zn-0.39Zr Alloys: Effect of Heat-Treatment, J. Mater. Sci. Technol., 2019, 35(8), p 1644–1654.
Y.S. Huang, X.T. Zeng, X.F. Hu and F.M. Liu, Corrosion Resistance Properties of Electroless Nickel Composite Coatings, Electrochim. Acta, 2004, 49(25), p 4313–4319.
Y. Wang, Y. Zhang, P. Wang, D. Zhang, B. Yu, Z. Xu and H. Jiang, Effect of LPSO Phases and Aged-Precipitations on Corrosion Behavior of as-Forged Mg-6Gd-2Y-1Zn-0.3Zr Alloy, J. Mater. Res. Technol., 2020, 9(4), p 7087–7099.
X. Zhang, Q. Wang, F. Chen, Y. Wu, Z. Wang and Q. Wang, Relation Between LPSO Structure and Biocorrosion Behavior of Biodegradable GZ51K Alloy, Mater. Lett., 2015, 138, p 212–215.
T. Zhang, Y. Shao, G. Meng, Z. Cui and F. Wang, Corrosion of Hot Extrusion AZ91 Magnesium Alloy: I-Relation Between the Microstructure and Corrosion Behavior, Corros. Sci., 2011, 53(5), p 1960–1968.
G.L. Song and Z. Xu, The Surface, Microstructure and Corrosion of Magnesium Alloy AZ31 Sheet, Electrochim. Acta, 2010, 55(13), p 4148–4161.
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This work was supported by China Postdoctoral Science Foundation funded project (Nos. 2019M653703 and 2020T130523) and Shannxi Provincial Natural Science Foundation (No. 2018JQ8017).
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Yuan, X., Du, Y., Dong, D. et al. Corrosion Resistance Improvement of an Extruded Mg-Gd-Y-Zn-Zr-Ca via Aging Treatment. J. of Materi Eng and Perform 31, 2909–2917 (2022). https://doi.org/10.1007/s11665-021-06455-z
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DOI: https://doi.org/10.1007/s11665-021-06455-z