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Preparation and Properties of a Novel Al-Si-Ge-Zn Filler Metal for Brazing Aluminum

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Abstract

The study is concerned with developing a filler metal with low melting temperature and good processability for brazing aluminum and its alloys. For this purpose, a novel Al-Si-Ge-Zn alloy was prepared according to Al-Si-Ge and Al-Si-Zn ternary phase diagrams. The melting characteristics, microstructures, wettability, and processing property of the alloy were investigated. The results showed that the melting temperature range of the novel filler metal was 505.2-545.1 °C, and the temperature interval between the solidus and the liquidus was 39.9 °C. Compared with a common Al-Si-Ge alloy, it had smaller and better dispersed β-GeSi solid solution precipitates, and the Zn-rich phases distributed on the boundary of the β-GeSi precipitates. The novel filler metal has good processability and good wettability with Al. There was one obvious transition layer with a thin α-Al solid solution between the filler metal and base metal, which is favorable to improve the strength of brazing joint.

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References

  1. Y. Sugiyama, Brazing of Aluminum Alloys, Weld. Int., 1989, 3, p 700–710

    Article  Google Scholar 

  2. W. Wang and Y. Tsai, Microstructural Characterization and Mechanical Property of Active Soldering Anodized 6061 Al Alloy Using Sn-3.5Ag−xTi Active Solders, Mater. Charact., 2012, 68, p 42–48

    Article  Google Scholar 

  3. W. Dai, S.B. Xue, J.Y. Lou, Y.B. Lou, and S.Q. Wang, Torch Brazing 3003 Aluminum Alloy with Zn-Al Filler Metal, Trans. Nonfer. Metal. Soc. China, 2012, 22, p 30–35

    Article  Google Scholar 

  4. T. Hattori, S. Sakai, A. Sakamoto, and C. Fujiwara, Brazeability of Aluminum in Vacuum-Nitrogen Partial-Pressure Atmosphere Brazing, Weld. J., 1994, 73, p 233–240

    Google Scholar 

  5. T. Hosch and R.E. Napolitano, The Effect of the Flake to Fiber Transition in Silicon Morphology on the Tensile Properties of Al-Si Eutectic Alloys, Mater. Sci. Eng. A, 2010, 528, p 226–232

    Article  Google Scholar 

  6. G. Humpston, S.P.S. Sangha, and D.M. Jacobson, New Filler Metals and Process for Fluxless Brazing of Aluminium Engineering Alloys, Mater. Sci. Technol. Lond., 1995, 11, p 1161–1168

    Article  Google Scholar 

  7. D.M. Jacobson, G. Humpston, and S.P.S. Sangha, A New Low-Melting-Point Aluminum Braze, Weld. J., 1996, 75, p 243–250

    Google Scholar 

  8. K. Suzuki, M. Kagayama, and Y. Takeuchi, Eutectic Phase Equilibrium of Al-Si-Zn System and its Applicability for Lower Temperature, J. Jpn. Inst. Light Met., 1993, 43, p 533–538

    Article  Google Scholar 

  9. S.B. Xue, J. Dong, X.C. Lv, and Y.Y. Qian, Brazing Technology of LY12 Aluminum Alloy at Middle Temperature, Trans. China Weld. Inst., 2003, 24, p 21–22,51

  10. R. Xu, H. Zhao, J. Li, R. Liu, and W.K. Wang, Microstructures of the Eutectic and Hypereutectic Al-Ge Alloys Solidified Under Different Pressures, Mater. Lett., 2006, 60, p 783–785

    Article  Google Scholar 

  11. Q.Y. Zhang, S.Q. Liu, and N.Z. Gao, The Solution Synthesis of Potassium Fluoaluminate Flux and its Brazing Mechanism, Trans. China Weld. Inst., 1982, 3, p 153–158

    Google Scholar 

  12. E. Hornbogen, A.K. Mukhopadhyay, and E.A. Starke, Precipitation Hardening of Al-(Si, Ge) Alloys, Scripta Mater., 1992, 27, p 733–738

    Article  Google Scholar 

  13. T. Kayamoto, J.H. Kim, S. Saito, and T. Onzawa, Brazing of Al-Mg Alloy and Al-Mg-Si Alloy with Al-Ge Based Filter Metals, Proc. Workshop. J. Weld. Soc., 1994, 12, p 495–501

    Google Scholar 

  14. Q.Y. Zhang, S.Q. Liu, and X.H. Fang, The Modification of Si Phase in Al-Si Eutectic Alloys-Effect of Element Addition on Microstructures of Al-Si and Al-Si-Ge Eutectic Alloys, Acta. Metall. Sin., 1982, 18, p 581–585

    Google Scholar 

  15. S.Q. Liu, G.P. Sun, and Q.Y. Zhang, The Phase Diagram of System Al-Si-Ge, Acta. Metall. Sin., 1982, 18, p 451–455

    Google Scholar 

  16. T.H. Chuang, L.C. Tsao, T.C. Tsai, M.S. Yeh, and C.S. Wu, Development of a Low-Melting-Point Filler Metal for Brazing Aluminum Alloys, Metall. Mater. Trans. A, 2000, 31, p 2239–2245

    Article  Google Scholar 

  17. G.A. Chadwick, Metallography of Phase Transformations, Butterworths First Publishing House, London, 1972, p 132–144

  18. B.S. Lao, S. Gao, and Q.Y. Zhang, Nonequilibrium Growth of Intermetallics at the Interface of Liquid-Solid Metal, Acta. Phys. Chim., 2001, 17, p 453–456

    Google Scholar 

  19. S. Zhang, S.B. Xue, J.L. Yang, J. Lou, and S.Q. Wang, Effect of P Element on Microstructure and Properties of Al-Si-Zn Filler Metal, Trans. China Weld. Inst., 2013, 34, p 103–107

    Google Scholar 

  20. Y.W. Shi, Y. Yu, Y.P. Li, Z.D. Xia, Y.P. Lei, X.Y. Li, and F. Guo, Study on the Microstructure and Wettability of an Al-Cu-Si Braze Containing Small Amounts of Rare Earth Erbium, J. Mater. Eng. Perform., 2009, 18, p 278–281

    Article  Google Scholar 

  21. M.H. El-Sayed, K.M. Hafez, and M. Naka, Interfacial Structure and Bond Strength of Ultrasonic Brazed Al-304 Stainless Steel Dissimilar Joints, Sci. Technol. Weld. Join., 2004, 9, p 560–564

    Article  Google Scholar 

  22. B. Bokstein, V. Ivanov, O. Oreshina, A. Peteline, and S. Peteline, Direct Experimental Observation of Accelerated Zn Diffusion Along Triple Junctions in Al, Mater. Sci. Eng. A, 2001, 302, p 151–153

    Article  Google Scholar 

  23. W. Dai, S.B. Xue, F. Ji, J. Lou, B. Sun, and S.Q. Wang, Brazing 6061 Aluminum Alloy with Al-Si-Zn Filler Metals Containing Sr, Int. J. Min. Met. Mater., 2013, 20, p 365–370

    Article  Google Scholar 

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Acknowledgment

This research was sponsored by the Guangdong provincial science and technology project, China (2010A080402014).

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Correspondence to Jihua Huang.

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Niu, Z., Huang, J., Yang, H. et al. Preparation and Properties of a Novel Al-Si-Ge-Zn Filler Metal for Brazing Aluminum. J. of Materi Eng and Perform 24, 2327–2334 (2015). https://doi.org/10.1007/s11665-015-1509-y

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  • DOI: https://doi.org/10.1007/s11665-015-1509-y

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