Abstract
Correlations between mechanical properties and microscopic features were investigated using unnotched specimens of rubber-PMMA composites in very low to medium range of cross head speeds. It is found that: (1) a trapezoid-shaped smooth region and fish scale-like texture with bands in rough region correlates with brittle failure in pure PMMA, while a quarter circle-shaped smooth region and hackle-like texture, and the presence of dimples and/or voids correlate with ductile failure in rubber-PMMA composites; (2) decrease in degree of roughness in rubber-PMMA composites can be correlated with decrease in Young’s modulus; (3) decrease in size of the smooth region with increasing speed can be correlated with decrease in modulus of toughness; (4) larger smooth region in rubber-PMMA composites containing more rubber correlates with higher modulus of toughness.
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References
C.B. Bucknall, Toughened Plastics, Applied Science Publishers Ltd, London, 1977
I.M. Ward, Mechanical Properties of Solid Polymers, 2nd ed., John Wiley & Sons Ltd, New York, 1990
S. Bandyopadhyay, Macroscopic Fracture Behaviour: Correlation with Macroscopic Aspects of Deformation in Toughened Epoxies, Toughened Plastics I: Science & Engineering, C. Keith Riew and Anthony J. Kinloch, Eds., Advances in Chemistry Series 233, American Chemical Society, 1993, p 211–258
O. Frank, J. Lehmann, Determination of Various Deformation Processes in Impact-Modified PMMA at Strain Rates up to 103 Per Minute; Colloid Polym. Sci. 1986, 264: 473-481
R.W. Truss, G.A. Chadwick, The Tensile Deformation Behaviour of a Transparent ABS Polymer, J. Mater. Sci. 1976, 11: 1385
R.K. Goldberg, G.D. Roberts, and A. Gilat, Incorporation of Mean Stress Effects into the Micromechanical Analysis of the High Strain Rate Response of Polymer Matrix Composites, Compos. Part B, 2003, 34, p 151–165
C. Grein, H.-H. Kausch, Ph. Be´guelin, Characterisation of Toughened Polymers by LEFM Using an Experimental Determination of the Plastic Zone Correction, Polymer Test. 2003, 22: 733-746
T. Vu-Khanh, Z. Yu, Mechanisms of Brittle-Ductile Transition in Toughened Thermoplastics, Theor. Appl. Fract. Mech. 1997, 26: 177-183
W. Jiang, D. Yu, B. Jiang, Brittle-Ductile Transition of Particle Toughened Polymers: Influence of the Matrix Properties, Polymer 2002, 45: 6427-6430
Christophe FOND and Robert SCHIRRER, Dynamic Fracture Surface Energy Values and Branching Instabilities During Rapid Crack Propagation in Rubber Toughened PMMA, in C. R. Acad. Sci. Paris, t. 329, Série II b, 2001, p 195–200
P.A. Tzika, M.C. Boyce, D.M. Parks, Micromechanics of Deformation in Particle-Toughened Polyamides, J. Mech. Phys. Solids, 2000, 48: 1893-1929
G.M. Kim, G.H. Michler, Micromechanical Deformation Processes in Toughened and Particle Filled Semicrystalline Polymers. Part 2: Model Representation for Micromechanical Deformation Processes, Polymer, 1998, 39(22): 5699-5703
S. Biwa, N. Ito, N. Ohno, Elastic Properties of Rubber Particles in Toughened PMMA: Ultrasonic and Micromechanical Evaluation, Mech. Mater. 2001, 33: 717-728
N. Murphy, A. Ivankovic, The Prediction of Dynamic Fracture Evolution in PMMA Using a Cohesive Zone Model, Eng. Fract. Mech. 2005, 72: 861-875
X.F. Yao, W. Xu, M.Q. Xu, K. Arakawa, T. Mada, K. Takahashi, Experimental Study of Dynamic Fracture Behavior of PMMA with Overlapping Offset-Parallel Cracks, Polymer Test. 2003, 22: 663-670
F. Zhou, J.-F. Molinari, T. Shioya, A Rate-Dependent Cohesive Model for Simulating Dynamic Crack Propagation in Brittle Materials, Eng. Fract. Mech. 2005, 72: 1383-1410
D. Taylor, M. Merlo, R. Pegleya, M.P. Cavatorta, The Effect of Stress Concentrations on the Fracture Strength of Olymethylmethacrylate, Mater. Sci. Eng. A 2004, 382: 288-294
W. Loyens, G. Groeninckx, Deformation Mechanisms in Rubber Toughened Semicrystalline Polyethylene Terephthalate, Polymer, 2003, 44: 4929-4941
C.B. Bucknall, I. Partridge, M.V. Ward, Rubber Toughening of Plastics, J. Mater. Sci. 1984, 19: 2064-2082
O. Julien, Ph. Begulin, I. Monnerie, and H.-H. Kausch, Loading-Rate Dependence of the Fracture Behaviour of Rubber-Modified Poly(Methyl Methacrylate), Toughened Plastics II: Novel Approaches in Science & Engineering, C. Keith Riew and Anthony J. Kinloch, Eds., Advances in Chemistry Series 252, American Chemical Society, 1996, p 233–252
A. Savadori, Methods of Measurements and Interpretation of results: In Rubber Toughened Engineering Plastics, A.A. Collyar Ed, Chapman & Hall, London, 1994, p 90-135
R.W. Truss, G.A. Chadwick, Tensile Behaviour of ABS Polymers, J. Mater. Sci. 1976, 11:111-117
David Broek, Elementary Engineering Fracture Mechanics, Martinus Nijhoff Publishers, Dordrecht, 1986
D.R. Askeland and P.P. Phulé, The Science and Engineering of Materials, 4th ed., Brooks Cole Publishing, a division of Thomson Learning, 2004
R.J. Young, P.A. Lovell, Introduction to Polymers, 2nd ed., CHAPMAN & HALL, London, 1991
J. Marin, Testing of Polymers, Vol.1, John V. Schmitz, Ed., John Willey & Sons, Inc., New York, 1965, p 87
C.R. Brooks, A. Choudhury, Failure Analysis of Engineering Materials, McGraw-Hill Companies, New York, 2002
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Gong, S., Bandyopadhyay, S. Mechanical Properties and Fracture Surface Morphologies in Unnotched Specimens of Rubber-PMMA Composites. J. of Materi Eng and Perform 16, 601–606 (2007). https://doi.org/10.1007/s11665-007-9042-2
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DOI: https://doi.org/10.1007/s11665-007-9042-2