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Improvements in the Sintering Behavior and Microwave Dielectric Properties of Geikielite-Type MgTiO3 Ceramics

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Abstract

Microwave dielectric ceramics based on geikielite-type MgTiO3 were prepared by an aqueous sol–gel process. The precursor powders and dielectric ceramics were characterized by x-ray diffraction, scanning electron microscopy (SEM), transmission electron microscopy (TEM), and microwave methods. Highly reactive nanosized magnesium titanate powders with particle sizes of 20 nm to 40 nm were successfully obtained at 500°C as precursors. Sintering characteristics and microwave dielectric properties of MgTiO3 ceramics were studied as a function of sintering temperature from 1100°C to 1300°C. With increasing sintering temperature, the density, ε r, and Qf values increased, saturating at 1200°C with excellent microwave properties of ε r = 17.5, Qf = 156,300 GHz, and τ f  = −44 ppm/°C. Correlations between the microstructure and dielectric properties of MgTiO3 ceramics were also investigated.

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References

  1. H. Ohsato, J. Ceram. Soc. Jpn. 113, 703 (2005).

    Article  CAS  Google Scholar 

  2. H. Ohsato, T. Tsunooka, Y. Ohishi, Y. Miyauchi, M. Ando, and K. Kakimoto, J. Korean Ceram. Soc. 40, 350 (2003).

    Article  CAS  Google Scholar 

  3. H. Ohsato, Mater. Res. Soc. Symp. Proc. 833, 55 (2005).

    CAS  Google Scholar 

  4. K.P. Surendran, P.V. Bijumon, and P. Mohanan, Appl. Phys. A 81, 823 (2005).

    Article  CAS  Google Scholar 

  5. K. Mor, H. Oqawa, and A. Kan, J. Eur. Ceram. Soc. 24, 1749 (2004).

    Article  Google Scholar 

  6. I.N. Jawahar, P. Mohanan, and M.T. Sebastain, Mater. Lett. 57, 4043 (2003).

    Article  CAS  Google Scholar 

  7. J. Bernard, D. Houivet, J. El Fallah, and J.M. Haussonne, J. Eur. Ceram. Soc. 24, 1877 (2004).

    Article  CAS  Google Scholar 

  8. F. Belnou, J. Bernard, D. Houivet, and J.M. Haussonne, J. Eur. Ceram. Soc. 25, 2785 (2005).

    Article  CAS  Google Scholar 

  9. X.H. Zhou, Y. Yuan, L.C. Xiang, and Y. Huang, J. Mater. Sci. 42, 6628 (2007).

    Article  CAS  Google Scholar 

  10. J. Bernard, F. Belnou, D. Houivet, and J.M. Haussonne, J. Mater. Process. Technol. 199, 150 (2008).

    Article  CAS  Google Scholar 

  11. K. Sreedhar and N.R. Pavaskar, Mater. Lett. 53, 452 (2002).

    Article  CAS  Google Scholar 

  12. B. Tang, S. Zhang, X.H. Zhou, C. Deng, and S.Q. Yu, J. Alloy. Compd. 492, 461 (2010).

    Article  CAS  Google Scholar 

  13. G. Pfaff, Ceram. Int. 20, 111 (1994).

    Article  CAS  Google Scholar 

  14. J.G. Baek, T. Isobe, and M. Senna, Solid State Ionics 90, 269 (1996).

    Article  CAS  Google Scholar 

  15. J.F. Liao and M. Senna, Mater. Res. Bull. 30, 385 (1995).

    Article  CAS  Google Scholar 

  16. N. Stubičar, A. Tonejc, and M. Stubičar, J. Alloy. Compd. 370, 296 (2004).

    Article  Google Scholar 

  17. K. Hamada, S. Yamamoto, and M. Senna, Adv. Powder Technol. 11, 361 (2000).

    Article  CAS  Google Scholar 

  18. M.K. Suresh, J.K. Thomas, H. Sreemoolanadhan, and C.N. George, Mater. Res. Bull. 45, 761 (2010).

    Article  CAS  Google Scholar 

  19. D.D. Li, L.Q. Wang, and D.F. Xue, J. Alloy. Compd. 492, 564 (2010).

    Article  CAS  Google Scholar 

  20. V.M. Ferreira and J.L. Baptista, Mater. Res. Bull. 29, 1017 (1994).

    Article  CAS  Google Scholar 

  21. A.B. Gaikwad, S.C. Navale, V. Samuel, A.V. Murugan, and V. Ravi, Mater. Res. Bull. 41, 347 (2006).

    Article  CAS  Google Scholar 

  22. M.J. Martínez-Lope, M.P. Baura-Peña, and M.E. García-Clavel, Thermochim. Acta 206, 113 (1992).

    Article  Google Scholar 

  23. Y.F. Deng, S.D. Tang, L.Q. Lao, and S.Z. Zhan, Inorg. Chim. Acta 363, 827 (2010).

    Article  CAS  Google Scholar 

  24. Y.M. Miao, Q.L. Zhang, H. Yang, and H.P. Wang, Mater. Sci. Eng. B 128, 103 (2006).

    Article  CAS  Google Scholar 

  25. I.R. Abothu, A.V.P. Rao, and S. Komarneni, Mater. Lett. 38, 186 (1999).

    Article  CAS  Google Scholar 

  26. M. Zhang, M. Guo, and Y. Zhou, Int. J. Appl. Ceram. Technol. 8, 591 (2011).

    Article  CAS  Google Scholar 

  27. A.E. Souza, G.T.A. Santos, R.A. Silva, M.L. Moreira, D.P. Volanti, E.C. Paris, S.R. Teixeira, and E. Longo, Int. J. Appl. Ceram. Technol. 9, 186 (2012).

    Article  CAS  Google Scholar 

  28. B.W. Hakki and P.D. Coleman, IEEE Trans. 8, 402 (1960).

    Google Scholar 

  29. W.E. Courtney, IEEE Trans. 18, 476 (1970).

    Google Scholar 

  30. A.L. Patterson, Phys. Rev. 56, 978 (1939).

    Article  CAS  Google Scholar 

  31. A. Thorvaldsen, Acta Mater. 45, 595 (1997).

    Article  CAS  Google Scholar 

  32. S. Brunauer, P.H. Emmett, and E. Teller, J. Am. Chem. Soc. 60, 309 (1938).

    Article  CAS  Google Scholar 

  33. J.H. Sohn, Y. Inaguma, S.O. Yoon, M. Itoh, T. Nakamura, S.J. Yoon, and H.J. Kim, Jpn. J. Appl. Phys. 33, 5466 (1994).

    Article  CAS  Google Scholar 

  34. R.D. Shannon and G.R. Rossman, Am. Miner. 77, 94 (1992).

    CAS  Google Scholar 

  35. R.D. Shannon, J. Appl. Phys. 73, 348 (1993).

    Article  CAS  Google Scholar 

  36. S.J. Penn, M.N. Alford, A. Templeton, X. Wang, M. Xu, M. Reece, and K. Schrapel, J. Am. Ceram. Soc. 80, 1885 (1997).

    Article  CAS  Google Scholar 

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Wu, H.T., Jiang, Y.S., Cui, Y.J. et al. Improvements in the Sintering Behavior and Microwave Dielectric Properties of Geikielite-Type MgTiO3 Ceramics. J. Electron. Mater. 42, 445–451 (2013). https://doi.org/10.1007/s11664-012-2349-2

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  • DOI: https://doi.org/10.1007/s11664-012-2349-2

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