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An Evaluation of Structural, Topographic, Optical, and Temperature-Dependent Electrical Features of Sol–Gel Spin-Coated p-NiO/n-Si Heterojunction

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Abstract

p-NiO/n-Si heterodiode was deposited with an easy and cheap sol–gel route using a spin coater. The XRD results revealed that NiO film had polycrystalline cubic bunsenite structure with (200) preferential direction. The AFM and SEM micrographs indicated that the film was composed of homogenously distributed nanoparticles on n-Si surface. The uniform scattering of Ni and O elements was also seen from EDX mapping pictures. The band gap value for NiO sample was found to be 3.74 eV. The current–voltage (IV) properties of Ag/p-NiO/n-Si heterojunction were inquired in the temperature range of 80 K to 300 K (−193 °C to 27 °C). The temperature coefficient of barrier height of the Ag/p-NiO/n-Si heterojunction was determined to be 2.6 meV/K. The I-V measurements showed that the barrier height of the heterojunction increased with an increment in the temperature.

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References

  1. B.A. Reguig, A. Khelil, L. Cattin, M. Morsli, J.C. Bernède: Appl. Surf. Sci., 2007, vol. 253 pp. 4330-4334.

    Article  Google Scholar 

  2. G. Turgut, E. Sonmez, S. Duman: Ceram. Inter., 2005, vol. 41, pp. 2976-2989.

    Article  Google Scholar 

  3. B.O. Jung, Y.H. Kwon, D.J. Seo, D.S. Lee, H.K. Cho: J. Crystal Growth, 2013, vol. 370, pp.314-318.

    Article  Google Scholar 

  4. P.S. Patil, L.D. Kadam: Appl. Surf. Sci., 2002, vol. 199, pp. 211-221.

    Article  Google Scholar 

  5. V. Gowthami, P. Perumal, R. Sivakumar, C. Sanjeeviraja: Physica B, 2014, vol. 452, pp. 1-6.

    Article  Google Scholar 

  6. U.S. Joshi, I. Matsumoto, K. Itaka, M. Sumiya, H. Koinuma: Appl. Surf. Sci., 2006, vol. 252, pp. 2524-2528.

    Article  Google Scholar 

  7. E.F. Keskenler, M. Tomakin, S. Doğan, G. Turgut, S. Aydın, S. Duman, B. Gürbulak: J. Alloy. Comp., 2013, vol. 550, pp. 129-132.

    Article  Google Scholar 

  8. Y.-M. Lee, W.-M. Nung, C.-H. Lai: Physica E, 2010, vol. 42, pp. 2289-2294.

    Article  Google Scholar 

  9. M.A. Abbasi, Z.H. Ibupoto, A. Khan, O. Nur, M. Willander: Mater. Lett., 2013, vol. 108, pp. 149-152.

    Article  Google Scholar 

  10. X.L. Zhang, K.S. Hui, K.N. Hui: Mater. Res. Bull., 2013, vol. 48, pp. 305-309.

    Article  Google Scholar 

  11. S.Y. Tsai, M.-H. Hon, Y.-M. Lu: Solid-State Elec., 2011, vol. 63, pp. 37-41.

    Article  Google Scholar 

  12. A. Echresh, M.A. Abbasi, M.Z. Shoushtari, M. Farbod, O. Nur and M. Willander: Semicond. Sci. Technol., 2014, vol. 29, pp. 115009 (6pp).

  13. R. Rajendran, Z. Yaakob, M.A.M. Teridi, M.S.A. Rahaman, K. Sopian: Mater. Lett., 2014, vol. 133, pp. 123-126.

    Article  Google Scholar 

  14. H. Wang, G. Fang, H. Long, S. Li, X. Mo, H. Huang, H. Zhou and X. Zhao: Semicond. Sci. Technol., 2011, vol. 26, pp. 125015 (4pp).

  15. S. Mitra, S. Chakraborty, K.S.R. Menon: Appl. Phys. A, 2014, vol. 115, pp. 1173-1179.

    Article  Google Scholar 

  16. M. Cavas, R.K. Gupta, A.A. Al-Ghamdi, Z. Serbetci, Z.H. Gafer, F. El-Tantawy, F. Yakuphanoglu: J. Electroceram., 2013, vol. 31, pp. 260-264.

    Article  Google Scholar 

  17. F.H. Hsu, N.F. Wang, Y.Z. Tsai, Y.S. Cheng, and M.P. Houng: J. Phys. D: Appl. Phys., 2013, vol. 46, pp. 275104 (9pp).

  18. J.-M. Choi, S. Im: Appl. Surf. Sci., 2005, vol. 244, pp. 435-438.

    Article  Google Scholar 

  19. G. Turgut, S. Duman: J. Alloys and Comp., 2016, vol. 664, pp. 547-552.

    Article  Google Scholar 

  20. G. Turgut, S. Duman, F.S. Özçelik, E.Sönmez, B. Gürbulak: J. Sol-Gel Sci. Technol., 2014, vol. 71, pp. 589-596.

    Article  Google Scholar 

  21. A.H. Berg, G.S. Sahasrabudhe, R.A. Kerner, B.P. Rand, J. Schwartz, and J.C. Sturm: Device Research Conference (DRC), 2016 74th Annual., 2016, 19–22 June.

  22. R. Islam, P. Ramesh, J.H. Nam, and K.C. Saraswat: Photovoltaic Specialist Conference (PVSC), 2015 IEEE 42nd, 2015, 14–19 June.

  23. M. Stamataki, D. Tsamakis, N. Brilis, I. Fasaki, A. Giannoudakos, M. Kompitsas: P hys. Stat. Sol. (a), 2008, vol. 205, pp. 2064-2068.

    Article  Google Scholar 

  24. M.D. Irwin, J.D. Servaites, D.B.Buchholz, B.J. Leever, J. Liu, J.D. Emery, M. Zhang, J.-H. Song, M.F. Durstock, A.J. Freeman, M.J. Bedzyk, M.C. Hersam, R.P.H. Chang, M.A. Ratner, T.J. Marks: Chem. Mater., 2011, vol. 23, pp. 2218-2226.

    Article  Google Scholar 

  25. D. Zhang, K. Uchida, S. Nozaki: MRS Proceedings, 2013, vol. 1494, pp. 305–309.

    Article  Google Scholar 

  26. F.C. Comanescu, M. Purica, E. Budianu: Proc. of SPIE, 2012, vol. 8411, pp. 84–86.

    Google Scholar 

  27. A.E. Gad, S. Mathur: Ceramic Engineering and Science Proceedings, 2014, vol. 34, pp. 133-137.

    Google Scholar 

  28. M. Guziewicz, W. Jung, J. Grochowski, M. Borysiewicz, K. Golaszewska, R. Kruszka, A. Baranska, A. Piotrowska, B.S. Witkowski, J.Z. Domagala, M. Gryzinski, K. Tyminsk, A. Stonert: Acta Physica Polonica A, 2011, vol. 120, pp. A69-A72.

    Article  Google Scholar 

  29. S.M. Attia, J. Wang, G. Wu, J. Shen, J. Ma: J. Mater. Sci. Tech., 2002, vol. 18, pp. 211-217.

    Google Scholar 

  30. I. Sta, M. Jlassi, M. Hajji, H. Ezzaouia: Thin Solid Films, 2014, vol. 555, pp. 131-137.

    Article  Google Scholar 

  31. E.F. Keskenler, G. Turgut, S.Aydın, S. Dogan: Optik, 2013, vol. 124, pp. 4827-4831.

    Article  Google Scholar 

  32. A.R. Bushroa, R.G. Rahbari, H.H. Masjuki, M.R. Muhamad: Vacuum, 2012, vol. 86, pp. 1107-1112.

    Article  Google Scholar 

  33. K.K. Purushothaman, S.J Antony, G. Muralidharan: Sol. Ener., 2011, vol. 85, pp. 978-984.

    Article  Google Scholar 

  34. R.K. Gupta, A.A. Hendi, M. Cavas, A.A. Al-Ghamdi, O.A. Al-Hartomy, R.H. Aloraini, F. El-Tantawy, F.Yakuphanoglu: Physica E, 2014, vol. 56, pp. 288-295.

    Article  Google Scholar 

  35. G. Turgut: Philosophical Magazine, 2015, vol. 95, pp.1607-1625.

    Article  Google Scholar 

  36. S.R. Nalage, M.A. Chougule, Shashwati Sen, P.B. Joshi, V.B. Patil: Thin Solid Films, 2012, vol. 520, pp.4835-4840.

    Article  Google Scholar 

  37. H. Aydin, Sh.A. Mansour, C. Aydin, A.A. Al-Ghamdi, O.A. Al-Hartomy, F. El-Tantawy, F. Yakuphanoglu: J. Sol-Gel Sci. Technol., 2012, vol. 64, pp. 728-733.

    Article  Google Scholar 

  38. E. H. Rhoderick, R. H. Williams: Metal-Semiconductor Contacts, 2nd ed. Clarendon, Oxford, 1988.

    Google Scholar 

  39. S. Duman, G. Turgut, F. S. Ozcelik, and B. Gurbulak: Philosophical Magazine, 2015, vol. 95, pp. 1646.

    Article  Google Scholar 

Download references

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Correspondence to Güven Turgut.

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Manuscript submitted June 27, 2016.

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Turgut, G., Duman, S. & Özcelik, F.Ş. An Evaluation of Structural, Topographic, Optical, and Temperature-Dependent Electrical Features of Sol–Gel Spin-Coated p-NiO/n-Si Heterojunction. Metall Mater Trans A 48, 3137–3142 (2017). https://doi.org/10.1007/s11661-017-4071-4

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