Skip to main content
SpringerLink
Log in

Interdiffusion behavior of Pt-modified γ-Ni + γ′-Ni3Al alloys coupled to Ni-Al-based alloys

  • Published:
Metallurgical and Materials Transactions A Aims and scope Submit manuscript

Abstract

The effect of platinum addition on the interdiffusion behavior of γ-Ni + γ′-Ni3Al alloys was studied by using diffusion couples comprised of a Ni-Al-Pt alloy mated to a Ni-Al, Ni-Al-Cr, or Ni-based commercial alloy. The commercial alloys studied were CMSX-4 and CMSX-10. Diffusion annealing was at 1150 °C for up to 100 hours. An Al-enriched γ′-layer often formed in the interdiffusion zone of a given couple during diffusion annealing due to the uphill diffusion of Al. This uphill diffusion was ascribed to Pt addition decreasing the chemical activity of aluminum in the γ + γ′ alloys. For a given diffusion couple end member, the thickening kinetics of the γ′ layer that formed increased with increasing Pt content in the Ni-Al-Pt γ + γ′ alloy. The γ′-layer thickening kinetics in diffusion couples with Cr showed less of a dependence on Pt concentration. Inference of a negative effect of Pt and positive effect of Cr on the Al diffusion in this system enabled explanation of the observed interdiffusion behaviors. There was no or minimal formation of detrimental topologically close-packed (TCP) phases in the interdiffusion zone of the couples with CMSX-4 or CMSX-10. An overlay Pt-modified γ + γ′ coating on CMSX-4 showed excellent oxidation resistance when exposed to air for 1000 hours at 1150 °C. Moreover, the Al content in the coating was maintained at a relatively high level due to Al replenishment from the CMSX-4 substrate.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. M. Peters, C. Leyens, U. Schulz, and W.A. Kaysser: Adv. Eng. Mater., 2001, vol. 3, pp. 193–204.

    Article  CAS  Google Scholar 

  2. D.R. Clarke and C.G. Levi: Annu. Rev. Mater. Res., 2003, vol. 33, pp. 383–417.

    Article  CAS  Google Scholar 

  3. V.K. Tolpygo, D.R. Clarke, and K.S. Murphy: Surf. Coating Technol., 2001, vols. 146–147, pp. 124–31.

    Article  Google Scholar 

  4. Y.H. Sohn, J.H. Kim, E.H. Jordan, and M. Gell: Surf. Coating Technol., 2001, vol. 146–147, pp. 70–78.

    Article  Google Scholar 

  5. A.G. Evans, M.Y. He, and J.W. Hutchinson: Progr. Mater. Sci., 2001, vol. 46, pp. 249–71.

    Article  CAS  Google Scholar 

  6. M. Gell, K. Vaidyanathan, B. Barber, J. Cheng, and E. Jordan: Metall. Mater. Trans. A, 1999, vol. 30A, pp. 427–35.

    CAS  Google Scholar 

  7. V.K. Tolpygo and D.R. Clarke: Acta Mater., 2000, vol. 48, pp. 3283–93.

    Article  CAS  Google Scholar 

  8. R. Panat, S. Zhang, and K.J. Hsia: Acta Mater., 2003, vol. 51, pp. 239–49.

    Article  CAS  Google Scholar 

  9. Y. Zhang, J.A. Haynes, B.A. Pint, I.G. Wright, and W.Y. Lee: Surf. Coating Technol., 2003, vols. 163–164, pp. 19–24.

    Article  Google Scholar 

  10. J.H. Chen and J.A. Little: Surf. Coating Technol., 1997, vol. 92, pp. 69–77.

    Article  CAS  Google Scholar 

  11. Y.H. Zhang, D.M. Knowles, and P.J. Withers: Surf. Coating Technol., 1998, vol. 107, pp. 76–83.

    Article  CAS  Google Scholar 

  12. J. R. Nicholls: MRS Bull., 2003, vol. 28, pp. 659–670.

    CAS  Google Scholar 

  13. B. Gleeson, W. Wang, S. Hayashi, and D. Sordelet: Iowa State University, Ames, IA, unpublished research, 2003.

  14. B. Gleeson, W. Wang, S. Hayashi, and D. Sordelet: Mater. Sci. Forum, 2004, vols. 461–464, pp. 213–22.

    Article  Google Scholar 

  15. A.G. Guy and C.B. Smith: Trans. ASM, 1962, vol. 55, pp. 1–9.

    CAS  Google Scholar 

  16. J.S. Kirkaldy and D.J. Young: Diffusion in the Condensed State, Institute of Metals, London, 1987, pp. 127–71.

    Google Scholar 

  17. J.S. Kirkaldy: in Advances in Materials Research, H. Herman, ed., Wiley, New York, NY, 1970, vol. 4, pp. 55–100.

    Google Scholar 

  18. E. Copland: NASA/CR-2005-213330, NASA, Cleveland, OH, 2005, pp. 1–28.

    Google Scholar 

  19. S. Hayashi, W. Wang, D. Sordelet, L.R. Walker, and B. Gleeson: Iowa State University, Ames, IA, unpublished research, 2003.

  20. N.C. Oforka and B.B. Argent: J. Less-Common Met., 1985, vol. 114, pp. 97–109.

    Article  CAS  Google Scholar 

  21. J.A. Nesbit and R.W. Heckel: Metall. Trans. A, 1987, vol. 18A, pp. 2075–86.

    Google Scholar 

Download references

Author information

Author notes

  1. Shigenari Hayashi & Wen Wang

    Present address: the Department of Materials Science and Engineering, Iowa State University, 50011, Arnes, IA

Authors and Affiliations

  1. the Research Group of Interface Control Engineering, Graduate School of Engineering, Hokkaido University, 060-8628, Sapporo, Japan

    Shigenari Hayashi

  2. the State Key Laboratory for Corrosion and Protection, Institute of Metal Research, Chinese Academy of Sciences, 110016, Shenyang, P.R. China

    Wen Wang

  3. the Department of Materials Science and Engineering, Iowa State University, 50011, Arnes, IA

    Daniel J. Sordelet & Brian Gleeson

Authors
  1. Shigenari Hayashi
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Wen Wang
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Daniel J. Sordelet
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Brian Gleeson
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Hayashi, S., Wang, W., Sordelet, D.J. et al. Interdiffusion behavior of Pt-modified γ-Ni + γ′-Ni3Al alloys coupled to Ni-Al-based alloys. Metall Mater Trans A 36, 1769–1775 (2005). https://doi.org/10.1007/s11661-005-0041-3

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11661-005-0041-3

Keywords

Search

Navigation