Skip to main content
Log in

Estimation of reservoir temperature using silica and cationic solutes geothermometers: a case study in the Tengchong geothermal area

  • Original Article
  • Published:
Chinese Journal of Geochemistry Aims and scope Submit manuscript

Abstract

Reservoir temperature estimation is vitally important for assessing the exploitation potential of a geothermal field. In this study, the concentrations of major chemical constituents in geothermal water sampled from boiling and hot springs in the Tengchong hydrothermal area were measured, and quartz and cationic solutes geothermometers were used to calculate subsurface temperatures. Log (Q/K) diagrams and Na–K–Mg triangular diagrams were applied to evaluating the equilibrium status of geothermal water samples with regard to reservoir minerals, and results were used to select suitable geothermometers. The results show that samples RH01, RH03, RH04, RH05, and LL16 were in or very close to full equilibrium with the selected minerals, and therefore a Na–K geothermometer is appropriate. A K/Mg geothermometer, however, is applicable to LP08 and PZH18 whose chemical compositions adjusted to the shallow reservoir temperatures during their re-equilibrium processes. In contrast, cationic solute geothermometers are unsuitable for SQ20 and RH07, which are categorized as immature water in the Na–K–Mg diagram; a quartz geothermometer was adopted to evaluate the corresponding subsurface temperatures of these samples. According to the reservoir temperature estimation made in this study, there is at least one high-temperature reservoir below Rehai with a possible temperature range of 210–270 °C.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6

Similar content being viewed by others

References

  • Ahmad M et al (2002) Assessment of reservoir temperatures of thermal springs of the northern areas of Pakistan by chemical and isotope geothermometry. Geothermics 31(5):613–631

    Article  Google Scholar 

  • Anzil PA, Guereschi AB, Martino RD (2012) Mineral chemistry and geothermometry using relict primary minerals in the La Cocha ultramafic body: a slice of the upper mantle in the Sierra Chica of Cordoba, Sierras Pampeanas, Argentina. J S Am Earth Sci 40:38–52

    Article  Google Scholar 

  • Asta MP et al (2012) Hydrochemistry and geothermometrical modeling of low-temperature Panticosa geothermal system (Spain). J Volcanol Geotherm Res 235:84–95

    Article  Google Scholar 

  • Crerar DA, Anderson GM (1971) Solubility and solvation reactions of quartz in dilute hydrothermal solutions. Chem Geol 8:107–122

    Article  Google Scholar 

  • Du JG et al (2005) Variations of geothermometry and chemical-isotopic compositions of hot spring fluids in the Rehai geothermal field, Southwestern China. J Volcanol Geotherm Res 142(3–4):243–261

    Article  Google Scholar 

  • Dulanya Z, Morales-Simfors N, Sivertun A (2010) Comparative study of the silica and cation geothermometry of the Malawi hot springs: potential alternative energy source. J Afr Earth Sci 57(4):321–327

    Article  Google Scholar 

  • Ellis AJ, Wilson SH (1960) The geochemistry of metal ions in the hydrothermal system. NZ J Geol Geophys 3(4):593–617

    Article  Google Scholar 

  • Fournier RO, Rowe JJ (1966) Estimation of underground temperatures from the silica content of water from hot springs and wet-steam wells. Am J Sci 264:685–697

    Article  Google Scholar 

  • Fournier RO, Truesdell AH (1973) An empirical Na–K–Ca Geothermometer for natural waters. Geochim Cosmochim Acta 37(5):1255–1275

    Article  Google Scholar 

  • Giggenbach WF (1988) Geothermal solute equilibria-derivation of Na–K–Mg–Ca geoindicators. Geochim Cosmochim Acta 52(12):2749–2765

    Article  Google Scholar 

  • Gokgoz A, Tarcan G (2006) Mineral equilibria and geothermometry of the Dalaman-Koycegiz thermal springs, southern Turkey. Appl Geochem 21(2):253–268

    Article  Google Scholar 

  • Guo QH, Wang YX (2012) Geochemistry of hot springs in the Tengchong hydrothermal areas, Southwestern China. J Volcanol Geotherm Res 215:61–73

    Article  Google Scholar 

  • Majumdar N, Mukherjee AL, Majumdar RK (2009) Mixing hydrology and chemical equilibria in Bakreswar geothermal area, Eastern India. J Volcanol Geotherm Res 183(3–4):201–212

    Article  Google Scholar 

  • Mimi AL et al (1998) Application of chemical geothermometrys to thermal springs. Geothermics 27(2):211–233

    Article  Google Scholar 

  • Mohammadi Z, Bagheri R, Jahanshahi R (2010) Hydrogeochemistry and geothermometry of Changal thermal springs, Zagros region, Iran. Geothermics 39(3):242–249

    Article  Google Scholar 

  • Mutlu H (1998) Chemical geothermometry and fluid-mineral equilibria for the Omer-Gecek thermal waters, Afyon area, Turkey. J Volcanol Geotherm Res 80(3–4):303–321

    Article  Google Scholar 

  • Mutlu H, Gulec N (1998) Hydrogeochemical outline of thermal waters and geothermometry applications in Anatolia (Turkey). J Volcanol Geotherm Res 85(1–4):495–515

    Article  Google Scholar 

  • Pang ZG (2001) Isotope and chemical geothermometry and its applications. Sci China Ser E-Technol Sci 44S:16–20

    Article  Google Scholar 

  • Pang ZH, Reed M (1998) Theoretical chemical thermometry on geothermal waters: problems and methods. Geochim Cosmochim Acta 62(6):1083–1091

    Article  Google Scholar 

  • Pang ZH, Wang JY, Fan ZC (1990) Calculation of reservior temperature using a SiO2 mixing model, Zhangzhou geothermal field, SE China. Chin Sci Bull 35(16):1360–1363

    Google Scholar 

  • Pasvanoglu S (2011) Hydrogeochemical and isotopic investigation of the Bursa-Oylat thermal waters, Turkey. Environ Earth Sci 64(4):1157–1167

    Article  Google Scholar 

  • Pirlo MC (2004) Hydrogeochemistry and geothermometry of thermal groundwaters from the Birdsville Track Ridge, Great Artesian Basin, South Australia. Geothermics 33(6):743–774

    Article  Google Scholar 

  • Reed M, Spycher N (1984) Calculation of Ph and mineral equilibria in hydrothermal waters with application to geothermometry and studies of boiling and dilution. Geochim Cosmochim Acta 48(7):1479–1492

    Article  Google Scholar 

  • Shangguan ZG (2000) Structure of geothermal reservoirs and the temperature of mantle-derived magma hot source in the Rehai area, Tengchong. Acta Petrol Sin 16(1):83–90

  • Shangguan ZG, Zhao CP, Li HZ, Gao QW, Sun ML (2005) Evolution of hydrothermal explosions at Rehai geothermal field, Tengchong volcanic region, China. Geothermics 34(4):518–526

    Article  Google Scholar 

  • Sun ZX, Wu HM (1999) Calculation of the fluid-rock equilibrium state and geothermal reservior temperatures in the geothermal system. Acta Geosci Sin 20:595–598

    Google Scholar 

  • Tong W, Zhang M (1989) Geothermics in Tengchong. Science press, Beijing. (in Chinese with English abstract)

  • Zheng XL, Liu HJ (1996) Study of the water-rock equilibrium state in the application of geothermometer. J Xi’an Coll Geol 18(1):74–79

  • Zhang GP et al (2008) Geochemistry of the Rehai and Ruidian geothermal waters, Yunnan Province, China. Geothermics 37:73–83

    Article  Google Scholar 

  • Zheng XL, Armannsson H, Li YL, Qiu HX (2002) Chemical equilibria of thermal waters for the application of geothermometers from the Guanzhong basin, China. J Volcanol Geotherm Res 113(1–2):119–127

    Google Scholar 

Download references

Acknowledgments

This study was financially supported by the National Natural Science Foundation of China (No. 41120124003), the Ministry of Education of China (111 Project, No. B08030), the Research fund of Bureau of Science and Technology of Qinghai Province (No. 2013-G-Q08A), and the Fundamental Research Fund for National Universities, China University of Geosciences (Wuhan) (Nos. CUG120505 and CUG120113). The helpful comments of two anonymous reviewers are gratefully acknowledged.

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Qinghai Guo.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Zhang, X., Guo, Q., Li, J. et al. Estimation of reservoir temperature using silica and cationic solutes geothermometers: a case study in the Tengchong geothermal area. Chin. J. Geochem. 34, 233–240 (2015). https://doi.org/10.1007/s11631-015-0037-7

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11631-015-0037-7

Keywords

Navigation