Abstract
In order to study the chemical modification mechanism and rheological properties of polyphosphoric acid (PPA) -modified asphalt, asphalt modified with different PPA contents were characterized by four-component test, atomic force microscopy (AFM) and Fourier transform infrared spectroscopy (FTIR). In the test, changes in asphalt chemical composition and colloidal structure were analyzed for different PPA contents, and infrared spectra were fitted with a Gaussian function. The reaction mechanism of PPA and matrix asphalt was also discussed. Based on dynamic shear rheometer (DSR) test and bending beam rheometer (BBR) test, rheological index G*/sinδ and S/m were used to evaluate the modification effect of PPA on asphalt. The results show that, with an increase in PPA content, both large and small honeycomb structures increased in the three-dimensional topography seen in the atomic force microscope (AFM). In a certain space range, some of the micelles in the asphalt are connected each other to form interlocking skeleton structures, and locally form dense spatial network structures. The added PPA does not chemically react with the functional groups in the functional-group area of the infrared spectra (3 100–2 750 cm−1, 1 800–1 330 cm−1), and the structure is very stable. However, there is an obvious new absorption peak below 1 330 cm−1 in the fingerprint area, that is, the chemical reaction between PPA and the matrix asphalt generates a new compound, inorganic phosphate. Infrared spectra of PPA-modified asphalt with different contents were fitted by a Gaussian function, which makes up for the limitation that the absorption intensity information of each superimposed functional group cannot be obtained directly from the original infrared spectra. Results of this qualitative analysis were further verified by quantitative analysis. The addition of PPA can effectively improve the high and low-temperature performance of asphalt, and the lower the temperature is in the negative temperature zone, the more obvious the improvement is. When PPA content is more than 1%, the improvement of asphalt low-temperature performance is not obvious.
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References
Orange Gilles, Martin Jean Valery, Menapace A, et al, Rutting and Moisture Resistance of Asphalt Mixtures Containing Polymer and Polyphosphoric Acid Modified Bitumen[J]. Road Materials and Pavement Design, 2004, 5(3): 323–354
Huang S-C, Miknis F P, Schuster W, et al. Rheological and Chemical Properties of Hydrated Lime and Polyphosphoric Acid-Modified Asphalts with Long-Term Aging[J]. Journal of Materials in Civil Engineering, 2011, 23(5): 628–637
Zahid Hossain, Md Shahriar Alam, Gaylon Baumgardner. Evaluation of Rheological Performance and Moisture Susceptibility of Polyphosphoric Acid Modified Asphalt Binders[J]. Road Materials and Pavement Design, 2020, 21(1): 237–252
Edwards Y, Tasdemir Y, Isacsson U. Rheological Effects of Commercial Waxes and Polyphosphoric Acid in Bitumen 160/220 — High and Medium Temperature Perfor Mance[J]. Construction & Building Materials, 2007, 21(10): 1 899–1 908
Mazumder M, Ahmed R, Wajahat Ali A, et al. SEM and ESEM Techniques Used for Analysis of Asphalt Binder and Mixture: A State of the Art Review[J]. Construction & Building Materials, 2018, 186: 313–329
Mokhtari A, David Lee H, Williams R C, et al. A Novel Approach to Evaluate Fracture Surfaces of Aged and Rejuvenator-Restored Asphalt Using Cryo-SEM and Image Analysis Techniques[J]. Construction & Building Materials, 2017, 133: 301–313
Zeng Q, Liu Y, Liu Q, et al. Preparation and Modification Mechanism Analysis of Graphene Oxide Modified Asphalts[J]. Construction & Building Materials, 2020, 238: 117 706
Luo S, Tian J, Liu Z, et al. Rapid Determination of Styrene-Butadiene-Styrene (SBS) Content in Modified Asphalt Based on Fourier Transform Infrared (FTIR) Spectrometer and Linear Regression Analysis[J]. Measurement, 2020, 151: 107 204
Amini N, Hayati P. Effects of CuO Nanoparticles as Phase Change Material on Chemical, Thermal and Mechanical Properties of Asphalt Binder and Mixture[J]. Construction & Building Materials, 2020, 251: 118 996
Sun L, Wang Y, Zhang Y. Aging Mechanism and Effective Recycling Ratio of SBS Modified Asphalt[J]. Construction & Building Materials, 2014, 70: 26–35
Liu B, Li J, Han M, et al. Properties of Polystyrene Grafted Activated Waste Rubber Powder (PS-ARP) Composite SBS Modified Asphalt[J]. Construction & Building Materials, 2020, 238: 117 737
Li J, Zhang F, Liu Y, et al. Preparation and Properties of Soybean Bio-asphalt/SBS Modified Petroleum Asphalt[J]. Construction & Building Materials, 2019, 201: 268–277
Liang M, Xin X, Fan W, et al. Phase Field Simulation and Microscopic Observation of Phase Separation and Thermal Stability of Polymer Modified Asphalt[J]. Construction & Building Materials, 2019, 204: 132–143
Cao Z, Chen M, Han X, et al. Influence of Characteristics of Recycling Agent on the Early and Long-term Performance of Regenerated SBS Modified Bitumen[J]. Construction & Building Materials, 2020, 237: 117 631
Li P, Ding Z, Zou P, et al. Analysis of Physico-Chemical Properties for Crumb Rubber in Process of Asphalt Modification[J]. Construction & Building Materials, 2017, 138: 418–426
Hou S, Chen C, Zhang J, et al. Thermal and Mechanical Evaluations of Asphalt Emulsions and Mixtures for Microsurfacing[J]. Construction & Building Materials, 2018, 191: 1 221–1 229
Masson J F, Gagné A. Reactions of Polyphosphoric Acid and Bitumen Model Compounds with Oxygenated Functional Groups: Where is the Phosphorylation[J]. Energy & Fuels, 2008, 22(6): 4 151–4 157
Pereira G D, Morales A R. Modification of Thermal and Rheological Behavior of Asphalt Binder by the Addition of an Ethylene-Methyl Acrylate-Glycidyl Methacrylate Terpolymer and Polyphosphoric Acid[J]. Polimeros-Ciencia E Tecnologia, 2017, 27(4): 298–308
Liu B Q, Zhen J T, Chen H X, et al. Pavement Performance and Mechanism Analysis of Polyphosphate Modified Asphalt[J]. Journal of Shenzhen University (Science and Engineering Edition), 2018, 35(03): 292–298
Zhang H L, Shi C J, Yu J Y, et al. Modification and Its Mechanism of Different Asphalts by Polyphosphoric Acid[J]. Journal of Building Materials, 2013, 16(02): 255–260
Dourado Er, Pizzorno Bs, Mottalmg, et al. Simao RA, Leite lfm. Analysis of Asphaltic Binders Modified with PPA by Surface Techniques[J]. Journal of Microscopy, 2014, 254(3): 122–128
Tan X, Zhang J, Guo D, et al. Preparation, Characterization and Repeated Repair Ability Evaluation of Asphalt-based Crack Sealant Containing Microencapsulated Epoxy Resin and Curing Agent[J]. Construction & Building Materials, 2020, 256: 119 433
Sarnowski M, Michal. Rheological Properties of Road Bitumen Binders Modified with SBS Polymer and Polyphosphoric Acid[J]. Roads Bridges-Drogii Mosty, 2015, 14(1): 47
Yadollahi G, Sabbagh Mollahosseini H. Improving the Performance of Crumb Rubber Bitumen by Means of Poly Phosphoric Acid (PPA) and Vestenamer Additives[J]. Construction & Building Materials, 2011, 25(7): 3 108–3 116
Alam S, Hossain Z. Changes in Fractional Compositions of PPA and SBS Modified Asphalt Binders[J]. Construction & Building Materials, 2017, 152: 386–393
Zhang F, Yu J. The Research for High-Performance SBR Compound Modified Asphalt[J]. Construction & Building Materials, 2010, 24(3): 410–418
Liu X, Zhang Z W, Yang X L, et al. The Present Situation and Prospect of the Research on the Modified Asphalt of Polyphosphoric Acid[J]. Materials Reports, 2017, 31(19): 104–111
Liu C, Li Z J, Liu S H, et al. Analysis and Prospect of Polyphosphate Modified Asphalt Technology[J]. Chinese Adhesive, 2020, 29(08): 63–67
Fu G Z, Zhao Y Q, Sun Q Q. Modification Mechanism of Polyphosphoric Acid and SBS Composite Modified Asphalt[J]. Journal of Composite Materials, 2017, 34(06): 1 374–1 380
Lesueur. The Colloidal Structure of Bitumen: Consequences on the Rheology and on the Mechanisms of Bitumen Modification[J]. Adv. Colloid Interf, 2009, 145: B42–82
Zhang M, Hao P, Dong S, et al. Asphalt Binder Micro-Characterization and Testing Approaches: A Review[J]. Measurement, 2020, 151: 107 255
Alexander Schmets, Niki Kringos, T Pauli, et al. On the Existence of Wax-Induced Phase Separation in Bitumen[J]. International Journal of Pavement Engineering, 2010, 11(06): 555–563
Kuang D, Liu Y, Niu C, et al. Study on Design and Optimization of Novelty Asphalt Rejuvenator Composition Based on Crystal Nucleus Dispersion Theory[J]. Construction & Building Materials, 2019, 222: 319–331
Liang M, Jiang F S, Fan W Y, et al. Effect of PE Molecular Structure on Viscoelastic Energy and Microstructure of Modified Asphalt[J]. Journal of China University of Petrolumn(Edition of Natural Science), 2016, 40(6): 170–177
Liu J, Yan K, You L, et al. Laboratory Performance of Warm Mix Asphalt Binder Containing Polyphosphoric Acid[J]. Construction & Building Materials, 2016, 106: 218–227
Li N, Liu Q S. The Combustion Reactivity of Coal with Different Metamorphic Degrees and the Structural Change of Its Pyrolysis Process Were Analyzed by FTIR[J]. Spectroscopy and Spectral Analysis, 2016, 36(9): 2 760–2 764
LU Qingqing. High Temperature Properties of Polyethylene Wax Modified Asphalts Based on Rheological Behavior[J]. Journal of Jilin University (Engineering and Technology Edition), 2020, 50(06): 2 141–2 146
Lin Peng, Yan Chuanqi, Huang Wei-dong, et al. Rheological, Chemical and Aging Characteristics of High Content Polymer Modified Asphalt[J]. Construction and Building Materials, 2019, 207: 616–62
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Funded by National Natural Science Foundation of China (No. 11962024), Inner Mongolia Transportation Technology Project (No. NJ-2014-9), and Research Fund for the Doctoral Program of Higher Education of China (RFDP)(No. BS2020042)
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Wang, L., Pei, K. & Li, C. Analysis of Chemical Modification Mechanism and Rheological Properties of Polyphosphoric Acid Modified Asphalt. J. Wuhan Univ. Technol.-Mat. Sci. Edit. 37, 876–884 (2022). https://doi.org/10.1007/s11595-022-2609-9
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DOI: https://doi.org/10.1007/s11595-022-2609-9