Abstract
Lead-free piezoelectric ceramics (1 − x) NaNbO3-xBaTiO3 have been fabricated by a traditional ceramic sintering technique. The effects of BaTiO3 (BT) synthesized by hydrothermal method on crystal structure, density, dielectric, piezoelectric, and electromechanical properties were investigated. Results show that the phase structure transforms from the orthorhombic phase to the tetragonal phase with the increase of the content of BT, and the two phases co-exist when 0.08<×⩽0.10. However, the optimum composition for (1 − x)NaNbO3-xBaTiO3 ceramics is 0.90NaNbO3-0.10BaTiO3. The 0.90NaNbO3-0.10BaTiO3 ceramics sintered at 1250°C have higher properties: piezoelectric constant d 33 of 120 pC/N, dielectric constant ετ of 718, planar electromechanical coupling factor k p of 24%, planar frequency N d of 3 MHz·mm, and the mechanical quality factor Q m of 138, respectively. The results show that the (1−x)NaNbO3-xBaTiO3 ceramics is one of the promising lead-free materials for high-frequency applications.
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References
Matsubara M, Yamaguchi T. Processing and piezoelectric properties of lead-free (K,Na)(Nb,Ta)O3 ceramics. J Am Ceram Soc, 2005, 88 (5): 1190–1196
Zhang S J, Xia R. Characterization of lead free (Na0.5K0.5) NbO3-LiSbO3 piezoceramic. Solid State Communications, 2007, 141: 675–679
Zhang S J, Xia R. Lead-free piezoelectric ceramics vs. PZT. J. Electroceram, DOI:10.1007/s10832-007-9056-z, 2007
Ahn CW, Song H C. Effect of MnO2 on the piezoelectric properties of (1 − x)(Na0.5K0.5)NbO3-xBaTiO3 ceramics. Japanese Journal of Applied Physics, 2005, 44: 1361–1364
Zhi Y, Chen A. Piezoelectric and strain properties of Ba(Ti1 − x Zrx) O3 ceramics. Journal of Applied Physics, 2002, 92(3): 1489–1493
Lin D, Kowk KW. Structure and electrical properties of (Na0.5K0.5) NbO3-LiSbO3 lead-free piezoelectric ceramics. Journal of Applied Physics, 2007, 101: 074111-(1-6)
Chang R C, Chu S Y. The effect of sintering temperature on the properties of (Na0.5K0.5)NbO3-CaTiO3 based lead-free piezoelectric ceramics. Sensors and Actuators A, 2007, 138: 355–360
Du H L, Tang F S. Influence of sintering temperature on piezoelectric Properties of (Na0.5K0.5)NbO3-LiNbO3 lead-free piezoelectric ceramics. Materials Research Bulletin, 2007, 42: 1594–1601
Hagh N M, Jadidian B. Property-processing Relationship in Lead-Free (K,Na,Li)NbO3-solid solution system. J Electroceram, 2007, 18: 339–346
Satio Y, Takao H. Lead-Free Piezoceramics. Nature, 2004, 432(4): 84–87
Matsubara M, Yamaguchi T. Synthesis and characterization of (Na0.5K0.5)(Nb0.7Ta0.3)O3 piezoelectric ceramics sintered with sintering aid K5.4Cu1.3Ta10O29. Japanese Journal of Applied Physics, 2005, 44(9): 6618–6623
Guo Y P, Kakimoto K I. (Na0.5K0.5)NbO3-LiTaO3 lead-free piezoelectric ceramics. Materials Letters, 2005, 59: 241–244
Hollenstein E, Davis M. Piezoelectric properties of Li- and Tamodified (Na0.5K0.5)NbO3 ceramics. Applied Physics Letters, 2005, 87: 182905-(1-3)
Guo Y P, Kakimoto K. Dielectric and piezoelectric properties of lead-free (Na0.5K0.5)NbO3-SrTiO3 ceramics. Solid State Communications, 2004, 129: 279–284
Chang Y F, Yang Z P. Dielectric and piezoelectric properties of Alkaline-earth Titanate doped (Na0.5K0.5)NbO3 ceramics. Materials Letters, 2007, 61: 785–789
Jiao G C, Fan H Q. Structure and piezoelectric properties of Cudoped Potassium Sodium Tantalite Niobate ceramics. Materials Letters, 2007, 61: 4185–4187
Wang R, Xie R J. Enhanced piezoelectricity around the tetragonal/orthorhombic morphotropic phase boundary in (K,Na)NbO3-ATiO3 solid solution. J Electroceram, DOI:10.1007/s10832-007-9136-0, 2007
Zeng J T, Kwok K W. Ferroelectric and Piezoelectric Properties of Na1−x BaxNb1−x TixO3 Ceramics. J Am Ceram Soc, 2006, 89: 2828–2832
Aoyagi R, Matsuoka T. Piezoelectric properties of NaNbO3-BaTiO3 ceramics. In: Sixteenth IEEE International Symposium. Applications of Ferroelectrics, ISAF, 2007, 677–678
Park S H, Ahn C W. Microstructure and piezoelectric properties of ZnO-added (Na0.5K0.5)NbO3 ceramics. Japanese Journal of Applied Physics, 2004, 43(8B): 1072–1074
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Xie, S., Zhu, K., Qiu, J. et al. Microstructure and electrical properties of NaNbO3-BaTiO3 lead-free piezoelectric ceramics. Front. Mech. Eng. China 4, 345–349 (2009). https://doi.org/10.1007/s11465-009-0050-9
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DOI: https://doi.org/10.1007/s11465-009-0050-9