Abstract
Two types of lanthanide coordination polymers, namely, [Ln(PA)(NO3)(DMA)3] n (Ln=Gd (1), Dy (2), Eu (3), Tb (4)) (type I), and {[Ln2(PA)3(DMF)4]·2DMF} (Ln=Eu (5), Tb (6)) (type II) (PA=Pamoic acid, DMA=dimethylacetamide, DMF=N,N-dimethylformamide), have been synthesized by the reaction of Ln(NO3)3·6H2O with pamoic acid through layer diffusion method. These complexes were characterized by single crystal X-ray diffraction, infrared spectroscopy (IR), thermogravimetric analysis (TGA), fluorescence and magnetic measurements. Solvents and lanthanide atoms in the reaction play an important role in controlling different structures. Type I demonstrated 1-D linear chain structure connected by Ln atoms and PA ligands. Type II exhibited non-interpenetrating 3-D 6-connected 43612 nets based on binuclear [Ln2(CO2)6(DMF)4] cores. Magnetic properties of complexes 1–4 were investigated in details. Complex 1 shows significant magnetocaloric effect with–ΔSm=20.37 J kg–1 K–1 at 3.0 K and 7 T. Complex 2 exhibits slow relaxation of the magnetization. Complexes 3–6 exhibit both ligand- and metal-centered fluorescent properties. Complex 6 demonstrates fluorescent sensing of DMF and Cu2+ ion.
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Li B, Wen HM, Cui Y, Qian G, Chen B. Prog Polymer Sci, 2015, 48: 40–84
Zhao M, Ou S, Wu CD. Acc Chem Res, 2014, 47: 1199–1207
Liu JL, Chen YC, Guo FS, Tong ML. Coordin Chem Rev, 2014, 281: 26–49
Cui Y, Yue Y, Qian G, Chen B. Chem Rev, 2012, 112: 1126–1162
Xu LJ, Xu GT, Chen ZN. Coordin Chem Rev, 2014, 273-274: 47–62
Roy S, Chakraborty A, Maji TK. Coordin Chem Rev, 2014, 273-274: 139–164
Zhang X, Vieru V, Feng X, Liu JL, Zhang Z, Na B, Shi W, Wang BW, Powell AK, Chibotaru LF, Gao S, Cheng P, Long JR. Angew Chem Int Ed, 2015, 54: 9861–9865
Zhang JW, Kan XM, Liu BQ, Liu GC, Tian AX, Wang XL. Chem Eur J, 2015, 21: 16219–16228
Tobin G, Comby S, Zhu N, Clérac R, Gunnlaugsson T, Schmitt W. Chem Commun, 2015, 51: 13313–13316
Tian D, Li Y, Chen RY, Chang Z, Wang GY, Bu XH. J Mater Chem A, 2014, 2: 1465–1470
Li Y, Zhang S, Song D. Angew Chem Int Ed, 2013, 52: 710–713
Wu JJ, Ye YX, Qiu YY, Qiao ZP, Cao ML, Ye BH. Inorg Chem, 2013, 52: 6450–6456
Mohapatra S, Rajeswaran B, Chakraborty A, Sundaresan A, Maji TK. Chem Mater, 2013, 25: 1673–1679
Decadt R, Van Hecke K, Depla D, Leus K, Weinberger D, Van Driessche I, van der Voort P, van Deun R. Inorg Chem, 2012, 51: 11623–11634
Colodrero RMP, Papathanasiou KE, Stavgianoudaki N, Olivera-pastor P, Losilla ER, Aranda MAG, León-reina L, Sanz J, Sobrados I, Choquesillo-lazarte D, García-ruiz JM, Atienzar P, Rey F, Demadis KD, Cabeza A. Chem Mater, 2012, 24: 3780–3792
Wang S, Peng Y, Wei X, Zhang Q, Wang D, Dou J, Li D, Bai J. CrystEngComm, 2011, 13: 5313
Wang S, Yun R, Peng Y, Zhang Q, Lu J, Dou J, Bai J, Li D, Wang D. Cryst Growth Des, 2012, 12: 79–92
Cao T, Peng Y, Liu T, Wang S, Dou J, Li Y, Zhou C, Li D, Bai J. CrystEngComm, 2014, 16: 10658–10673
Biswas S, Jena HS, Goswami S, Sanda S, Konar S. Cryst Growth Des, 2014, 14: 1287–1295
Zhang L, Zhang C, Zhang B, Du C, Hou H. CrystEngComm, 2015, 17: 2837–2846
Zhang L, Lu S, Zhang C, Du C, Hou H. CrystEngComm, 2015, 17: 846–855
SAINT. Version 6 02a. Madison, WI: Bruker AXS Inc, 2002
Sheldrick GM. SADABS. Program for Brucker Area Detector Absorption Correction. Göttingen, Germany: Göttingen University, 1997
Sheldrick GM. SHELXS-97. Program for Crystal Structure Solution. Göttingen, Germany: Göttingen University, 1997
Sheldrick GM. SHELXL-97. Program for Crystal Structure Refinement. Göttingen, Germany: Göttingen University: 1997
Spek AL. J Appl Crystallogr, 2003, 36: 7–13
Li Y, Yu JW, Liu ZY, Yang EC, Zhao XJ. Inorg Chem, 2015, 54: 153–160
Liu QY, Li YL, Wang YL, Liu CM, Ding LW, Liu Y. CrystEngComm, 2014, 16: 486–491
Liu QY, Li YL, Wang YL, Liu CM, Ding LW, Liu Y. CrystEngComm, 2014, 16: 486–491
Hou YL, Xiong G, Shen B, Zhao B, Chen Z, Cui JZ. Dalton Trans, 2013, 42: 3587
Fang M, Li JJ, Shi PF, Zhao B, Cheng P. Dalton Trans, 2013, 42: 6553
Chen Z, Zhao B, Cheng P, Zhao XQ, Shi W, Song Y. Inorg Chem, 2009, 48: 3493–3495
Tian J, Li B, Zhang X, Li X, Li X, Zhang J. Dalton Trans, 2013, 42: 8504–8511
Liu SJ, Zhao JP, Song WC, Han SD, Liu ZY, Bu XH. Inorg Chem, 2013, 52: 2103–2109
Sharples JW, Zheng YZ, Tuna F, Mcinnes EJL, Collison D. Chem Commun, 2011, 47: 7650–7652
Karotsis G, Evangelisti M, Dalgarno SJ, Brechin EK. Angew Chem Int Ed, 2009, 121: 10112–10115
Sedláková L, Hanko J, Orendácová A, Orendác M, Zhou CL, Zhu WH, Wang BW, Wang ZM, Gao S. J Alloys Compd, 2009, 487: 425–429
Manoli M, Collins A, Parsons S, Candini A, Evangelisti M, Brechin EK. J Am Chem Soc, 2008, 130: 11129–11139
Zheng XY, Wang SQ, Tang W, Zhuang GL, Kong XJ, Ren YP, Long LS, Zheng LS. Chem Commun, 2015, 51: 10687–10690
Han SD, Miao XH, Liu SJ, Bu XH. Inorg Chem Front, 2014, 1: 549–552
Han SD, Miao XH, Liu SJ, Bu XH. Chem Asian J, 2014, 9: 3116–3120
Peng JB, Kong XJ, Zhang QC, Orendác M, Prokleška J, Ren YP, Long LS, Zheng Z, Zheng LS. J Am Chem Soc, 2014, 136: 17938–17941
Guo FS, Leng JD, Liu JL, Meng ZS, Tong ML. Inorg Chem, 2012, 51: 405–413
Zheng YZ, Evangelisti M, Winpenny REP. Angew Chem Int Ed, 2011, 50: 3692–3695
Du M, Li CP, Zhao XJ, Yu Q. CrystEngComm, 2007, 9: 1011–1028
Li Y, Song D. CrystEngComm, 2011, 13: 1821–1830
Cha YE, Li X, Ma D, Huo R. Eur J Inorg Chem, 2014, 2014: 2969–2975
Xu W, Zhou Y, Huang D, Xiong W, Su M, Wang K, Han S, Hong M. Cryst Growth Des, 2013, 13: 5420–5432
Zhang X, Fan L, Sun Z, Zhang W, Fan W, Sun L, Zhao X. CrystEngComm, 2013, 15: 4910–4916
Chen B, Wang L, Xiao Y, Fronczek FR, Xue M, Cui Y, Qian G. Angew Chem Int Ed, 2009, 48: 500–503
Nagarkar SS, Joarder B, Chaudhari AK, Mukherjee S, Ghosh SK. Angew Chem Int Ed, 2013, 52: 2881–2885
Cui Y, Chen B, Qian G. Coordin Chem Rev, 2014, 273-274: 76–86
Song XZ, Song SY, Zhao SN, Hao ZM, Zhu M, Meng X, Wu LL, Zhang HJ. Adv Funct Mater, 2014, 24: 4034–4041
Wang X, Zhang L, Yang J, Liu F, Dai F, Wang R, Sun D. J Mater Chem A, 2015, 3: 12777–12785
Wang Y, Xue Z, Sun Z, Tan C, Wen Y, Hu S, Zhu Q, Sheng T, Wu X. Dalton Trans, 2015, 44: 2217–2222
Jayaramulu K, Narayanan RP, George SJ, Maji TK. Inorg Chem-, 2012, 51: 10089–10091
Douvali A, Papaefstathiou GS, Gullo MP, Barbieri A, Tsipis AC, Malliakas CD, Kanatzidis MG, Papadas I, Armatas GS, Hatzidimitriou AG, Lazarides T, Manos MJ. Inorg Chem, 2015, 54: 5813–5826
Ye J, Zhao L, Bogale RF, Gao Y, Wang X, Qian X, Guo S, Zhao J, Ning G. Chem Eur J, 2015, 21: 2029–2037
Hao Z, Yang G, Song X, Zhu M, Meng X, Zhao S, Song S, Zhang H. J Mater Chem A, 2014, 2: 237–244
Dang S, Ma E, Sun ZM, Zhang H. J Mater Chem, 2012, 22: 16920–16926
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Wang, S., Ma, R., Chen, Z. et al. Solvent- and metal-directed lanthanide-organic frameworks based on pamoic acid: observation of slow magnetization relaxation, magnetocaloric effect and luminescent sensing. Sci. China Chem. 59, 948–958 (2016). https://doi.org/10.1007/s11426-015-0537-6
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DOI: https://doi.org/10.1007/s11426-015-0537-6