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NO oxidation performance and kinetics analysis of BaMO3 (M=Mn, Co) perovskite catalysts

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Abstract

Perovskite is an efficient and emerging catalyst for NO oxidation. In this study, BaMnO3 and BaCoO3 perovskite catalysts were synthesized by the sol-gel method, and their catalytic oxidation performances of NO were studied. The catalytic performances indicated that BaMnO3 and BaCoO3 perovskites had the highest NO oxidation activities with the NO conversions of 78.2% at 350 °C and 84.3% at 310 °C, respectively. The high activities of BaMnO3 and BaCoO3 perovskite catalysts were related to the abundant surface adsorption oxygen (OA = 76.21% and 78.57%, respectively) and the high concentration of Mn4+ (Mn4+/Mn = 66.95%) and Co3+ (Co3+/Co = 63.8%). Moreover, the results of FT-IR and kinetics revealed that NO and O2 adsorbed on the surface of samples and combined with the B-O band to form bidentate nitrate and bridging nitrate, which eventually was converted into NO2. The kinetics analysis revealed that the NO oxidation reaction followed the Eley-Rideal (E-R) and Langmuir-Hinshelwood (L-H) mechanisms. In addition, the activation energies were 36.453 kJ/mol for BaMnO3 and 30.081 kJ/mol for BaCoO3, implying that BaMnO3 and BaCoO3 provide low-cost and efficient catalysts, which can be comparable to Pt noble metal catalysts.

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The datasets used and/or analyzed during the current study are available from the corresponding author on reasonable request.

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Funding

Financial support for this project was provided by the National Natural Science Foundation of China (No. 21666016); the National Key R&D Program of China (2018YFC1900200); and the Key Laboratory and the Analysis and Testing Foundation of Kunming University of Science and Technology (2019M20172107029).

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Authors and Affiliations

  1. Faculty of Environmental Science and Engineering, Kunming University of Science and Technology, Kunming, 650500, Yunnan, China

    Ran Ao, Liping Ma, Zhiying Guo, Jing Yang, Liusen Mu & Yi Wei

  2. College of Resources and Environment, Chengdu University of Information Technology, Chengdu, 610225, Sichuan, China

    Jie Yang

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  1. Ran Ao
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  2. Liping Ma
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Contributions

All authors contributed to the study conception and design. Ran Ao: conceptualization; data curation; investigation; methodology; roles/writing—original draft; writing—review and editing. Liping Ma: funding acquisition; methodology; project administration; resources; supervision; writing—review and editing. Zhiying Guo: data curation; formal analysis; software. Jing Yang: data curation; formal analysis; investigation; methodology. Liusen Mu: data curation. Jie Yang: data curation, software. Yi Wei: data curation. All authors read and approved the final manuscript.

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Correspondence to Liping Ma.

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Ao, R., Ma, L., Guo, Z. et al. NO oxidation performance and kinetics analysis of BaMO3 (M=Mn, Co) perovskite catalysts. Environ Sci Pollut Res 28, 6929–6940 (2021). https://doi.org/10.1007/s11356-020-10993-9

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