Abstract
The aim of this work was to characterize the coal fly ash from gasification process (G-CFA) and to analyze its potential as hexavalent chromium Cr (VI) adsorbent. The G-CFA was characterized in terms of physical, chemical, mineralogical, and morphological analyses. Bach adsorption studies were carried out in order to evaluate the influence of pH on the adsorption capacity and removal efficiency of Cr (VI). The G-CFA characterization demonstrated that the material possessed potential to be applied as an effective low-cost adsorbent, once it presents 18.82 m2 g−1, 0.036 cm3 g−1, and 7.56 nm of surface area, pore volume, and average pore diameter, respectively. The results also showed well-defined mineralogical phases and high content of siliceous material. The adsorption experiments demonstrated that the material has potential to be used as a chromium adsorbent with high removal efficiencies.
Similar content being viewed by others
References
Adamczuk A, Kołodyńska D (2015) Equilibrium, thermodynamic and kinetic studies on removal of chromium, copper, zinc and arsenic from aqueous solutions onto fly ash coated by chitosan. Chem Eng J 274:200–212. https://doi.org/10.1016/j.cej.2015.03.088
Alehyen S, Achouri M, Taibi M (2017) Characterization, microstructure and properties of fly ash-based geopolymer. J Mater Environ Sci 8:1783–1796
Amaresh, Hoolikantimath N (2015) Removal of chromium from synthetic wastewater using adsorption technique. Int Res J Eng Technol 2:486–490
Asl SMH, Ghadi A, Baei MS, Javadian H, Maghsudi M, Kazemian H (2018) Porous catalysts fabricated from coal fly ash as cost-effective alternatives for industrial applications: a review. Fuel 217:320–342. https://doi.org/10.1016/j.fuel.2017.12.111
ASTM C618-17a (2017) Standard Specification for Coal Fly Ash and Raw or Calcined Natural Pozzolan for Use in Concrete. ASTM International, West Conshohocken, PA. https://www.astm.org
Attari M, Bukhari SS, Kazemian H, Rohani S (2017) A low-cost adsorbent from coal fly ash for mercury removal from industrial wastewater. J Environ Chem Eng 5:391–399. https://doi.org/10.1016/j.jece.2016.12.014
Benedetti V, Patuzzi F, Baratieri M (2017) Characterization of char from biomass gasification and its similarities with activated carbon in adsorption applications. Appl Energy. https://doi.org/10.1016/j.apenergy.2017.08.076
Bertolini TCR, Izidoro JC, Magdalena CP, Fungaro DA (2013) Adsorption of crystal violet dye from aqueous solution onto zeolites from coal fly and bottom ashes. Orbital: Electron J Chem 5:179–191
Brage C, Yu Q, Chen G, Sjöström K (2000) Tar evolution profiles obtained from gasification of biomass and coal. Biomass Bioenergy 18:87–91. https://doi.org/10.1016/S0961-9534(99)00069-0
Breault RW (2010) Gasification processes old and new: a basic review of the major technologies. Energies 3:216–240
Cardoso NF, Pinto RB, Lima EC, Calvete T, Amavisca CV, Royer B, Cunha MB, Fernandes THM, Pinto IS (2011) Removal of remazol black B textile dye from aqueous solution by adsorption. Desalination 269:92–103. https://doi.org/10.1016/j.desal.2010.10.047
Carvalho T, Fungaro D, Magdalena C, Cunico P (2011) Adsorption of indigo carmine from aqueous solution using coal fly ash and zeolite from fly ash. J Radioanal Nucl Chem 289:617–626
Council WE (2013) World energy resources. In: London: World Energy Council
Deshannavar UB, Katageri BG, El-Harbawi M, Parab A, Acharya K (2017) Fly ash as an adsorbent for the removal of reactive blue 25 dye from aqueous solutions: optimization, kinetic and isotherm investigations. Proc Estonian Academy Sci 66:300–308. https://doi.org/10.3176/proc.2017.3.10
Dotto GL, Lima EC, Pinto LAA (2012) Biosorption of food dyes onto Spirulina platensis nanoparticles: equilibrium isotherm and thermodynamic analysis. Bioresour Technol 103:123–130. https://doi.org/10.1016/j.biortech.2011.10.038
Dotto GL, Moura JM, Cadaval TRS, Pinto LAA (2013) Application of chitosan films for the removal of food dyes from aqueous solutions by adsorption. Chem Eng J 214:8–16. https://doi.org/10.1016/j.cej.2012.10.027
Ebadi A, Mohammadzadeh JSS, Khudiev A (2009) What is the correct form of BET isotherm for modeling liquid phase adsorption? Adsorption 15:65–73
Ferrero F (2015) Dye removal from aqueous solution using coal fly ash for continuous flow adsorption. Clean Technol Envir 17:1907–1915
Gehlot G, Verma S, Sharma S, Mehta N (2015) Adsorption isotherm studies in the removal of malachite green dye from aqueous solution by using coal fly ash. Int J Chem Stud 3:42–44
González A, Navia R, Moreno N (2009) Fly ashes from coal and petroleum coke combustion: current and innovative potential applications. Waste Manag Res 27:976–987
Graham U, Rathbone R, Robl T (1996) Adsorptive properties of fly ash carbon. ACS Division of Fuel Chemistry, Preprints. 41. https://www.researchgate.net/publication/239887648_Adsorptive_properties_of_fly_ash_carbon/download. Accessed 1 Dec 2018
Hemmings R, Berry E, Cornelius B, Scheetz B (1986) Speciation in size and density fractionated fly ash II. Characterization of a low-calcium, high-iron fly ash. MRS Proc 86. https://doi.org/10.1557/PROC-86-81
Ho Y, McKay G (1998) A comparison of chemisorption kinetic models applied to pollutant removal on various sorbents. Process Saf Environ Prot 76:332–340
Ho Y, McKay G (2002) Application of kinetic models to the sorption of copper (II) on to peat. Adsorpt Sci Technol 20:797–815
Hong H, Jiang W-T, Zhang X, Tie L, Li Z (2008) Adsorption of Cr(VI) on STAC-modified rectorite. Appl Clay Sci 42:292–299. https://doi.org/10.1016/j.clay.2008.01.015
Izidoro JC, Fungaro DA, dos Santos FS, Wang S (2012) Characteristics of Brazilian coal fly ashes and their synthesized zeolites. Fuel Process Technol 97:38–44. https://doi.org/10.1016/j.fuproc.2012.01.009
Jing Z (2013) Characterization of nanoporous ceramic granules made with coal fly ash and their utilization in phenol removal from water. J Nanomater 2013. https://doi.org/10.1155/2013/606940
Katara S, Kabra S, Sharma A, Hada R, Rani A (2013) Surface modification of fly ash by thermal activation: A DR/FTIR study. Int Res J Pure Appl Chem 3:299–307
Largitte L, Pasquier R (2016) A review of the kinetics adsorption models and their application to the adsorption of lead by an activated carbon. Chem Eng Res Des 109:495–504. https://doi.org/10.1016/j.cherd.2016.02.006
Lata S, Samadder S (2014) Removal of heavy metals using rice husk: a review. International Journal of Environmental Research and. Development 4:165–170
Lee Y-R, Soe JT, Zhang S, Ahn J-W, Park MB, Ahn W-S (2017) Synthesis of nanoporous materials via recycling coal fly ash and other solid wastes: a mini review. Chem Eng J 317:821–843. https://doi.org/10.1016/j.cej.2017.02.124
Leyva-Ramos R, Jacobo-Azuara A, Diaz-Flores PE, Guerrero-Coronado RM, Mendoza-Barron J, Berber-Mendoza MS (2008) Adsorption of chromium(VI) from an aqueous solution on a surfactant-modified zeolite. Colloids Surf A Physicochem Eng Asp 330:35–41. https://doi.org/10.1016/j.colsurfa.2008.07.025
Li J et al (2018) Influence of pressure on fluidized bed gasifier: specific coal throughput and particle behavior. Fuel 220:80–88. https://doi.org/10.1016/j.fuel.2018.02.005
Lima DR, Klein L, Dotto GL (2017) Application of ultrasound modified corn straw as adsorbent for malachite green removal from synthetic and real effluents. Environ Sci Pollut Res Int 24:21484–21495
Marques BS, Frantz TS, Sant’Anna Cadaval Junior TR, de Almeida Pinto LA, Dotto GL (2018) Adsorption of a textile dye onto piaçava fibers: kinetic, equilibrium, thermodynamics, and application in simulated effluents. Environ Sci Pollut Res. https://doi.org/10.1007/s11356-018-3587-5
Matzenbacher CA et al (2017) DNA damage induced by coal dust, fly and bottom ash from coal combustion evaluated using the micronucleus test and comet assay in vitro. J Hazard Mater 324:781–788. https://doi.org/10.1016/j.jhazmat.2016.11.062
Mishra A, Tripathi BD (2008) Utilization of fly ash in adsorption of heavy metals from wastewater. Toxicol Environ Chem 90:1091–1097. https://doi.org/10.1080/02772240801936786
Mittal A, Mittal J, Malviya A, Kaur D, Gupta VK (2010) Adsorption of hazardous dye crystal violet from wastewater by waste materials. J Colloid Interface Sci 343:463–473. https://doi.org/10.1016/j.jcis.2009.11.060
Mohan D, Pittman CU (2006) Activated carbons and low cost adsorbents for remediation of tri-and hexavalent chromium from water. J Hazard Mater 137:762–811. https://doi.org/10.1016/j.jhazmat.2006.06.060
Mohan S, Gandhimathi R (2009) Removal of heavy metal ions from municipal solid waste leachate using coal fly ash as an adsorbent. J Hazard Mater 169:351–359. https://doi.org/10.1016/j.jhazmat.2009.03.104
Mozgawa W, Król M, Dyczek J, Deja J (2014) Investigation of the coal fly ashes using IR spectroscopy. Spectrochim Acta A Mol Biomol Spectrosc 132:889–894. https://doi.org/10.1016/j.saa.2014.05.052
Nche N-AG, Bopda AB, Tchuifon DRT, Ngakou CS, Kuete I-HT, Gabche AS (2017) Removal of paracetamol from aqueous solution by adsorption onto activated carbon prepared from rice husk. J Chem Pharm Res 9:56–68
Pires M, Querol X (2004) Characterization of Candiota (South Brazil) coal and combustion by-product. Int J Coal Geol 60:57–72. https://doi.org/10.1016/j.coal.2004.04.003
Sánchez C, Arenas E, Chejne F, Londoño CA, Cisneros S, Quintana JC (2016) A new model for coal gasification on pressurized bubbling fluidized bed gasifiers. Energy Convers Manag 126:717–723. https://doi.org/10.1016/j.enconman.2016.08.066
Santos RP et al. (2014) Coal fly ash ceramics: preparation, characterization, and use in the hydrolysis of sucrose. Scientific World Journal 2014, article ID 154651, 7 pages. https://doi.org/10.1155/2014/154651
Sokolar R, Nguyen M (2018) The fly ash of class C for ceramic technology. In: IOP Conference Series: Materials Science and Engineering. IOP Publishing, p 012053. https://doi.org/10.1088/1757-899X/385/1/012053
Soltani N, Bahrami A, Pech-Canul M, González L (2015) Review on the physicochemical treatments of rice husk for production of advanced materials. Chem Eng J 264:899–935
Tauanov Z, Abylgazina L, Spitas C, Itskos G, Inglezakis V (2017) Mineralogical, microstructural and thermal characterization of coal fly ash produced from Kazakhstani power plants. IOP Conf Ser: Mater Sci Eng230 012046. https://doi.org/10.1088/1757-899X/230/1/012046
Wang S, Soudi M, Li L, Zhu ZH (2006) Coal ash conversion into effective adsorbents for removal of heavy metals and dyes from wastewater. J Hazard Mater 133:243–251. https://doi.org/10.1016/j.jhazmat.2005.10.034
Willett JC, Finkelman RB, Kalkrueth W, Gonçalves GSAB (2006) World coal quality inventory: Brazil. US Geological Survey Open-file Report 2006:1241
Wu F-C, Tseng R-L, Juang R-S (2009) Characteristics of Elovich equation used for the analysis of adsorption kinetics in dye-chitosan systems. Chem Eng J 150:366–373
Yücel DŞ (2017) Removal of heavy metals from aqueous solution using fly ash: çan thermal power plant, NW Turkey as a case study. Karaelmas Fen ve Mühendislik Dergisi 7:291–298
Zhen X et al (2016) Rapid toxicity screening of gasification ashes. Waste Manag 50:93–104. https://doi.org/10.1016/j.wasman.2016.02.016
Funding
This study was financed in part by the Coordenação de Aperfeiçoamento de Pessoal de Nível Superior - Brasil (CAPES) - Finance Code 001.
Author information
Authors and Affiliations
Corresponding author
Additional information
Responsible editor: Tito Roberto Cadaval Jr
Rights and permissions
About this article
Cite this article
Ribeiro, P.B., de Freitas, V.O., Machry, K. et al. Evaluation of the potential of coal fly ash produced by gasification as hexavalent chromium adsorbent. Environ Sci Pollut Res 26, 28603–28613 (2019). https://doi.org/10.1007/s11356-018-3852-7
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s11356-018-3852-7