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Periodic characterization of alkyl-naphthalenes in stack gas and ambient air around a medical waste incinerator

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Abstract

Due to the subtle occurrence of environmental polycyclic aromatic hydrocarbon (PAHs) pollution from incinerators, it is seldom considered a significant source of PAH pollution. However, considering the recent build-up of toxics in urban air, this may be a serious concern around the incinerator vicinity due to the potential consequences of PAHs on human health. Hence, this study determined 11 alkyl-naphthalene contributions from a hospital waste incinerator (HWI_0) into ambient air receptor points (HWI_1 to HWI_5) for a 1-year period: June 2014–May 2015. The HWI_0 and ambient gases were sampled using filter-sorbent sampling system and polyurethane foam (PUF) passive samplers, respectively, and all alkyl-naphthalenes were determined using GC-MS. Results showed that the source concentrations were in the range of 0–14.0 ng/m3 and generally higher than the receptor points. The receptor point concentration trends were mainly HWI_1 > HWI_2 ≥ HWI_3 ≥ HWI_5 ≥ HWI_4. Multivariate receptor model analysis suggested high correlations between source and the receptor points though there might be some significant contributions from other emission sources. The average monthly concentrations (∑alkyl-naphthalene) at HWI_0 and the receptors HWI_1, HWI_2, HWI_3, HWI_4 and HWI_5 were 67.4 ± 24.3, 57.9 ± 20.1, 42.8 ± 16.9, 39.7 ± 12.2, 36.5 ± 22.2 and 37.8 ± 15.4 ng/m3, respectively. Though these concentrations were lower than the estimated minimal risk level (MRL) for chronic inhalation exposure to naphthalene and its derivatives 0.003 mg/m3, continuous exposure to these pollutants might result in chronic effects. Finally, this study may be used to evaluate the environmental contribution of alkyl-naphthalenes from typical medical waste incinerator in Nigeria.

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Acknowledgements

We acknowledge the technical support of the Departments of Chemical Engineering and Environmental Health, Obafemi Awolowo University. We also acknowledge the reviewers and critics for their excellent input in making the final manuscript.

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Correspondence to Olusola Adedayo Adesina or Paul N. Diagboya.

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Responsible editor: Constantini Samara

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Adedayo Adesina, O., Ademola Sonibare, J., Diagboya, P.N. et al. Periodic characterization of alkyl-naphthalenes in stack gas and ambient air around a medical waste incinerator. Environ Sci Pollut Res 24, 21770–21777 (2017). https://doi.org/10.1007/s11356-017-9828-1

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