Abstract
The leaching characteristics of hazardous materials from Ni-Cd batteries immersed in four typical water samples, i.e., water with NaCl, river water, tap water, and deionized water, were investigated to evaluate the potential environmental harm of spent Ni-Cd batteries in the water surroundings. It is shown that four water surroundings all could leach hazardous materials from the Ni-Cd batteries. The water with NaCl concentration of 66.7 mg L−1 had the highest leaching ability, the hazardous materials were leached after only approximately 50 days (average time, with a standard deviation of 4.1), while less than 100 days were needed in the others. An electrochemical corrosion is considered to be the main leaching mechanism leading to battery breakage, while the dissolution-deposition process and the powder route result in the leakage and transference of nickel and cadmium materials from the electrodes. The anions, i.e., SO4 2− and Cl−, and dissolved oxygen in water were demonstrated to be the vital factors that influence the leaching processes. Thus, it is proposed that spent Ni-Cd batteries must be treated properly to avoid potential danger to the environment.
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Atkinson CA, Jolley DF, Simpson SL (2007) Effect of overlying water pH, dissolved oxygen, salinity and sediment disturbances on metal release and sequestration from metal contaminated marine sediments. Chemosphere 69(9):1428–1437. https://doi.org/10.1016/j.chemosphere.2007.04.068
Aziz HA, Adlan MN, Ariffin KS (2008) Heavy metals (Cd, Pb, Zn, Ni, Cu and Cr(III)) removal from water in Malaysia: post treatment by high quality limestone. Bioresour Technol 99(6):1578–1583. https://doi.org/10.1016/j.biortech.2007.04.007
Espinosa DCR, Bernardes AM, Tenório JAS (2004) An overview on the current processes for the recycling of batteries. J Power Sources 135(1-2):311–319. https://doi.org/10.1016/j.jpowsour.2004.03.083
Ferreira CAM, Ponciano JAC, Vaitsman DS, Pérez DV (2007) Evaluation of the corrosivity of the soil through its chemical composition. Sci Total Environ 388(1–3):250–255. https://doi.org/10.1016/j.scitotenv.2007.07.062
Guevara-García JA, Montiel-Corona V (2012) Used battery collection in central Mexico: metal content, legislative/management situation and statistical analysis. J. Environ Manag 95:S154–S157
Han DM, Nan JM (2005) Advances on the recycling and reusing of spent batteries. Chin. J Power Sources 29:128–131
Hazotte C, Leclerc N, Meux E, Lapicque F (2016) Direct recovery of cadmium and nickel from Ni-Cd spent batteries by electroassisted leaching and electrodeposition in a single-cell process. Hydrometallurgy 162:94–103. https://doi.org/10.1016/j.hydromet.2016.02.019
Karnchanawong S, Limpiteeprakan P (2009) Evaluation of heavy metal leaching from spent household batteries disposed in municipal solid waste. Waste Manag 29(2):550–558. https://doi.org/10.1016/j.wasman.2008.03.018
Köhler U, Antonius C, Bäuerlein P (2004) Advances in alkaline batteries. J Power Sources 127(1-2):45–52. https://doi.org/10.1016/j.jpowsour.2003.09.006
Liu XY, Gurel V, Morris D, Murray DW, Zhitkovich A, Kane AB, Hurt RH (2007) Bioavailability of nickel in single-wall carbon nanotubes. Adv Mater 19(19):2790–2796. https://doi.org/10.1002/adma.200602696
Ma JW, Nie YF, Yue DB (2002) Leaching test of spent dry battery. Shanghai. Environ Sci 21(11):676–679
Martí-Cid R, Bocio A, Llobet JM, Domingo JL (2007) Intake of chemical contaminants through fish and seafood consumption by children of Catalonia, Spain: health risks. Food Chem Toxicol 45(10):1968–1974. https://doi.org/10.1016/j.fct.2007.04.014
Martino NA, Marzano G, Mangiacotti M, Miedico O, Sardanelli AM, Gnoni A, Lacalandra GM, Chiaravalle AE, Ciani E, Bogliolo L, Minervini F, Pizzi F, Dell’Aquila ME (2017) Exposure to cadmium during in vitro maturation at environmental nanomolar levels impairs oocyte fertilization through oxidative damage: a large animal model study. Reprod Toxicol 69:132–145. https://doi.org/10.1016/j.reprotox.2017.02.005
Mason-Jones K, von Blottnitz H (2010) Flows and fates of nickel–cadmium batteries in the City of Cape Town. Miner Eng 23(3):211–218. https://doi.org/10.1016/j.mineng.2009.09.010
Nie YF, Han J (2002) Study on the leaching characteristics and hazards of heavy metals in dry batteries in landfill. Tech Equip Environ Poll Control 3:32–34
Nishi Y (2001) Lithium ion secondary batteries; past 10 years and the future. J Power Sources 100(1-2):101–106. https://doi.org/10.1016/S0378-7753(01)00887-4
Randhawa NS, Gharami K, Kumar M (2016) Leaching kinetics of spent nickel–cadmium battery in sulphuric acid. Hydrometallurgy 165:191–198. https://doi.org/10.1016/j.hydromet.2015.09.011
Sánchez-Chardi A, Nadal J (2007) Bioaccumulation of metals and effects of landfill pollution in small mammals. Part I. The greater white-toothed shrew, Crocidura russula. Chemosphere 68(4):703–711. https://doi.org/10.1016/j.chemosphere.2007.01.042
Song FM, Sridhar N (2008) Modeling pipeline crevice corrosion under a disbonded coating with or without cathodic protection under transient and steady state conditions. Corros Sci 50(1):70–83. https://doi.org/10.1016/j.corsci.2007.05.024
Zhang Z, Stout JE, Yu VL, Vidic R (2008) Effect of pipe corrosion scales on chlorine dioxide consumption in drinking water distribution systems. Water Res 42(1-2):129–136. https://doi.org/10.1016/j.watres.2007.07.054
Zhao L, Zhu NW, Wang XH (2008) Comparison of bio-dissolution of spent Ni–Cd batteries by sewage sludge using ferrous ions and elemental sulfur as substrate. Chemosphere 70(6):974–981. https://doi.org/10.1016/j.chemosphere.2007.08.011
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Guo, X., Song, Y. & Nan, J. Flow evaluation of the leaching hazardous materials from spent nickel-cadmium batteries discarded in different water surroundings. Environ Sci Pollut Res 25, 5514–5520 (2018). https://doi.org/10.1007/s11356-017-0923-0
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DOI: https://doi.org/10.1007/s11356-017-0923-0