Abstract
In this paper, particular attention was paid to the presence of aerosol solid particles, which occurred mainly as a result of exploitation and coal combustion in the thermal power plants of the Kolubara basin. Not all of the particles created by this type of anthropogenic pollution have an equal impact on human health, but it largely depends on their size and shape. The mineralogical composition and particle size distribution in the samples of aero sediments were defined. The samples were collected close to the power plant and open pit coal mine, in the winter and summer period during the year 2007. The sampling was performed by using precipitators placed in eight locations within the territory of the Lazarevac municipality. In order to characterize the sedimentary particles, several methods were applied: microscopy, SEM-EDX and X-ray powder diffraction. The concentration of aero sediments was also determined during the test period. Variety in the mineralogical composition and particle size depends on the position of the measuring sites, geology of the locations, the annual period of collecting as well as possible interactions. By applying the mentioned methods, the presence of inhalational and respiratory particles variously distributed in the winter and in the summer period was established. The most common minerals are quartz and feldspar. The presence of gypsum, clay minerals, calcite and dolomite as secondary minerals was determined, as well as the participation of organic and inorganic amorphic matter. The presence of quartz as a toxic mineral has a particular impact on human health.
Similar content being viewed by others
References
Amandus H, Hanke W, Kulman G, Reger R (1984) A re-evaluation of radiological evidence from a study of U.S. strip coal miners. Arch Environ Health 39(5):346–351
Appel BR, Tokiwa Y, Kothny EL (1983) Sampling of carbonaceous particles in the atmosphere. Atmos Environ 17(9):1787–1796
Bosbach D, Enders M (1998) Micro topography of high-calcium fly ash particle surfaces. Adv Cem Res 10(1):17–23
DIRECTIVE 2008/65 (2008) Directive on permissible levels, measuring methodology and criteria from emission monitoring sites and collecting data. Off J Repub Serbia XV(65):1–2
Đorđević Z, Tomanec R, Spasić A (2005) Present conditions and trends of the development in coal processing at the Kolubara coal mine—Serbia. Acta Montanistica Slovaca Ročnik 10:82–86
Enders M (1995) Microanalytical characterization (AEM) of glassy spheres and anhydrite from a high-calcium lignite fly ash from Germany. Cem Concr Res 25(6):1369–1377
Fubini B, Zanetti G, Altilia SM, Tiozzo R, Lison D, Saffiotti U (1999) Relationship between surface properties and cellular responses to crystalline silica: studies with heat-treated cristobalite. Chem Res Toxicol 12(8):737–745
Ghose MK, Majee SR (1998) Assessment of dust generation due to opencast coal mining—an Indian case study. Environ Monit Assess 61:255–263
Gieré R, Carleton EL, Lumpkin RG (2003) Micro- and nanochemistry of fly ash from a coal-fired power plant. Am Mineral 88:1853–1865
Henderson WJ, Blundell G, Richards RJ, Hext PM, Volcani BE, Griffiths K (1975) Ingestion of talc particles by cultured lung fibroblasts. Environ Res 9:173–178
Hower JC, Mastalerz M (2001) An approach toward a combined scheme for the petrographic classification of fly ash. Energy Fuel 15:1319–1321
Hower CJ, Rathbone FR, Robertson DJ, Peterson G, Trimble SA (1999) Petrology, mineralogy and chemistry of magnetically-separated sized fly ash. Fuel 78:197–203
Hubbard FH, McGill RJ, Dhir RK, Ellis MS (1984) Clay and pyrite transformations during ignition of pulverized coal. Mineral Mag 48:21–256
Ivanović M (2002) Mineral dust—methods and results of SiO2 and asbestos investigation. Mining Institute, Belgrade, 158 (in Serbian)
Ivanović M, Ivanović V (1998a) The influence of respirable crystalline silica on air pollution. XXVI Consultation with international participation "Air Protection '98". Belgrade, Proceedings, pp. 252–256
Ivanović M, Ivanović V (1998b) Respirable quartz in the settlements of coal basins Serbia. XXVII Consultation with international participation "Air Protection '99". Belgrade, Proceedings, pp. 176–180
Ivanović M, Ivanović V, Koprivica O (1993) Categorization of lignite deposits Tamnava-East Field by the degree of potential natural hazards from aggressive mineral dust. Min Gaz 1–4:74–80
Ivanović M, Ivanović V, Koprivica O (1995) Dust as a risk factor for working conditions in the separation of quartz sand "Kolubara"—field "D". Min Gaz 1–2:55–58
Ivanović M, Ivanović V, Stajević D (1996) Content of free silicon dioxide in the air pollution of mining settlements of the basin. Min Gaz 1–4:68–70
Ivanović M, Ivanović V, Stajević D (1997) Air pollution dust in the settlements of coal mining of the basin. XXV Consultation with international participation "Air Protection '97". Belgrade, Proceedings, pp. 249–255
Ivanović M, Kuvekalović Z, Ivanović V (2000) Quartz suspended in the living environment XXVIII Consultation with international participation "Air Protection 2000". Belgrade, Proceedings, pp. 275–279
Janković N, Janković T (1998) Coal and sedimentary rocks in coal basin Kolubara, 13th Congress of the Geologists of Serbia, Proceedings vol 4, pp. 217–224
Jones T, Blackomore P, Leach M, Bérubé K, Sexton K, Richards R (2002) Characterisation of airborne particles collected within and proximal to an opencast coalmine: South Wales, UK. Environ Monit Assess 75:293–312
Katrinak KA, Rez P, Busek PR (1992) Structural variations in individual particles from an urban aerosol. Environ Sci Technol 26:1967–1976
Kukier U, Ishak FC, Sumner EM, Miller PW (2003) Composition and element solubility of magnetic and non-magnetic fly ash fractions. Environ Pollut 123:255–266
Kutchko GB, Kim GA (2006) Fly ash characterization by SEM-EDS. Fuel 85:2537–2544
Lapenas D, Gale P, Kennedy T, Rawlings W Jr, Dietrich P (1984) Kaolin pneumoconiosis: radiologic, pathologic, and mineralogic findings. Am Rev Respir Dis 130:282–288
Love RG, Miller BG, Groat SK, Hagen S, Cowe HA, Johnstop PP, Hutchinson PA, Soutar CA (1997) Respiratory health effects of opencast coalmining: a cross sectional study of current workers. Occup Environ Med 54:416–423
Lutterotti L (2002) MAUD Material Analysis Using Diffraction
McCarthy GJ (1988) X-ray powder diffraction for studying the mineralogy of fly ash. In: GJ McCarthy, FP Glasser, DM Roy, RT Hemmings (eds.) Fly ash and coal conversion by-products: characterization, utilization and disposal. Materials Research Society Proceedings 113. pp. 75–86
Merefield J, Stone I, Jarman P, Rees G, Roberts J, Dean A (1995) Environmental Dust analysis in opencast mining areas. In: MKG Whately, A Spears (eds) European Coal Geology, Special Publication of the Geological Society of London 82, pp. 181–188
Meseguer S, Jordán MM, Sanfeliu T (2009) Use of mine spoils from Teruel coal mining district (NE, Spain). Environ Geol 56:845–853
Munro JF, Crompton GK (1999) Health effects of respirable dust from opencast coal mining. Proc Roval Coll Phys Edinburgh 29:11–15
Murphy SA, Bérubé KA, Pooley FD, Richards RJ (1998) The response of the lung epithelium to well characterized fine particles. Life Sci 62(19):1789–1799
Pless-Mulloli T, Howel D, King A, Stone I, Marefield J, Basell J, Darnell R (2000) Living near opencast coal mining sites and children’s respiratory health. Occup Environ Med 57:145–151
Richards RJ, Wusteman FS (1974) The effects of silica dust and alveolar macrophages on lung fibroblasts grown in vitro. Life Sci 14:355–364
Sarkar A, Rano R, Udaybhanu G, Basu KA (2006) A comprehensive characterisation of fly ash from a thermal power plant in Eastern India. Fuel Process Technol 87:259–277
Shanker R, Sahu AP, Dogra RKS, Zaidi SH (1975) Effect of intratracheal injection of mica dust on the lymph nodes of guinea pigs. Toxicology 5:193–199
Sokol VE, Kalugin MV, Nigmatulina NE, Volkova IN, Frenkel EA, Maksimova VN (2002) Ferrospheres from fly ashes of Chelyabinsk coals: chemical composition, morphology and formation conditions. Fuel 81:867–876
Song Q, Xiao R, Deng Z, Shen L, Xiao J, Zhang M (2008) Effect of temperature on reduction of CaSO4 oxygen carrier in chemical-looping combustion of simulated coal gas in a fluidized bed reactor. Ind Eng Chem Res 47:8148–8159
Vassilev VS, Menendez R (2005) Phase-mineral and chemical composition of coal fly ashes as a basis for their multicomponent utilization. 4. Characterization of heavy concentrates and inproved fly ash residues. Fuel 84:973–991
Vassilev VS, Menendez R, Alvarez D, Diaz-Somoano M, Martinez-Tarazona RM (2003) Phase-mineral and chemical composition of coal fly ashes as a basis for their multicomponent utilization. 1. Characterization of feed coals and fly ashes. Fuel 82:1793–1811
Vassilev VS, Menendez R, Angeles GB, Diaz-Somoano M, Martinez-Tarazona RM (2004) Phase-mineral and chemical composition of coal fly ashes as a basis for their multicomponent utilization. 3. Characterization of magnetic and char concentrates. Fuel 83:1563–1583
Vučković B, Bogdanović V (2010) Possibilities and conditions of mineral resources exploitation on designed open pit "Ore-field E", 15th Congress of the Geologists of Serbia, Proceedings, pp. 189–194
Acknowledgments
This work was supported by the Ministry of Education and Science within the framework of basic research projects no: 176010 and 176016.
Author information
Authors and Affiliations
Corresponding author
Additional information
Responsible editor: Philippe Garrigues
Rights and permissions
About this article
Cite this article
Cvetković, Ž., Logar, M. & Rosić, A. Mineralogy and characterization of deposited particles of the aero sediments collected in the vicinity of power plants and the open pit coal mine: Kolubara (Serbia). Environ Sci Pollut Res 20, 3034–3049 (2013). https://doi.org/10.1007/s11356-012-1154-z
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s11356-012-1154-z