Abstract
In this research, stainless steel meshes coated with chitosan and micron-alumina were prepared via a dip-coating method. The coated mesh exhibits underwater oleophobic property with low oil adhesion. The influence of different concentrations of chitosan and micron-alumina on underwater oil contact angle of the coated mesh was studied. The separation efficiencies of the coated mesh for different oil–water mixtures were also tested. The results showed that the underwater oil contact angle of the coated mesh was as high as 146° when the concentrations of chitosan and micron-alumina were 0.4 and 0.04 wt%, respectively. The coated mesh can separate different kinds of oil with an efficiency over 90 % in gravity-driven method. Furthermore, the mesh has high recyclability in the application of oil–water separations in both NaCl and weak alkaline solutions. The chitosan and micron-alumina coated mesh has potential applications in oil–water separations.
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Barthwal, S., & Lim, S. H. (2015). Fabrication of long-term stable superoleophobic surface based on copper oxide/cobalt oxide with micro-nanoscale hierarchical roughness. Applied Surface Science, 328, 296–305.
Chang, S. H., & Chian, C. H. (2013). Plasma surface modification effects on biodegradability and protein adsorption properties of chitosan films. Applied Surface Science, 282, 735–740.
Chen, M. D., Jiang, W., Wang, F. H., Shen, P., Ma, P. C., Gu, J. J., Mao, J. Y., & Li, F. S. (2013). Synthesis of highly hydrophobic floating magnetic polymer nanocomposites for the removal of oils from water surface. Applied Surface Science, 286, 249–256.
Dong, Y., Li, J., Shi, L., Wang, X. B., Guo, Z. G., & Liu, W. M. (2014). Underwater superoleophobic graphene oxide coated meshes for the separation of oil and water. Chemical Communications, 50, 5586–5589.
Du, C., Wang, J. D., Chen, Z. F., & Chen, D. R. (2014). Durable superhydrophobic and superoleophilic filter paper for oil–water separation prepared by a colloidal deposition method. Applied Surface Science, 313, 304–310.
Feng, L., Zhang, Z. Y., Mai, Z. H., Ma, Y. M., Liu, B. Q., Jiang, L., & Zhu, D. B. (2004). A super-hydrophobic and super-oleophilic coating mesh film for the separation of oil and water. Angewandte Chemie, International Edition, 43, 2012–2014.
Gao, R., Liu, Q., Wang, J., Liu, J. Y., Yang, W. L., Gao, Z., & Liu, L. H. (2014). Construction of superhydrophobic and superoleophilic nickel foam for separation of water and oil mixture. Applied Surface Science, 289, 417–424.
Jin, C. D., Li, J. P., Han, S. J., Wang, J., & Sun, Q. F. (2014). A durable, superhydrophobic, superoleophobic andcorrosion-resistant coating with rose-like ZnO nanoflowers on a bamboo surface. Applied Surface Science, 320, 322–327.
Kerr, R. A., Kintisch, E., Schenkman, L., & Stokstad, E. (2010). Five questions on the spill. Science, 328, 962–963.
Lu, F., Chen, Y. N., Liu, N., Cao, Y. Z., Xu, L. X., Wei, Y., & Feng, L. (2014). A fast and convenient cellulose hydrogel-coated colander for high-efficiency oil–water separation. RSC Advances, 4, 32544–32548.
McCloskey, B. D., Ju, H., & Freeman, B. D. (2010). Composite membranes based on a selective chitosan-poly( ethylene glycol ) hybrid layer: synthesis, characterization, and performance in oil–water purification. Industrial and Engineering Chemistry Research, 49, 366–373.
Motlagh, N. V., Birjandi, F. C., Sargolzaei, J., & Shahtahmassebi, N. (2013). Durable, superhydrophobic, superoleophobic and corrosion resistant coating on the stainless steel surface using a scalable method. Applied Surface Science, 283, 636–647.
Podust, T. V., Kulik, T. V., Palyanytsya, B. B., Gun’ko, V. M., Tóth, A., & Mikhalovska, L. (2014). Chitosan-nanosilica hybrid materials: preparation and properties. Applied Surface Science, 320, 563–569.
Wang, Q. J., Cui, Z., Xiao, Y., & Chen, Q. M. (2007). Stable highly hydrophobic and oleophilic meshes for oil–water separation. Applied Surface Science, 253, 9054–9060.
Wang, L. F., Yang, S. Y., Wang, J., Wang, C. F., & Chen, L. (2011). Fabrication of superhydrophobic TPU film for oil–water separation based on electrospinning route. Materials Letters, 65, 869–872.
Wu, J., Chen, J., Qasim, K., Xia, J., Lei, W., & Wang, B. P. (2012). A hierarchical mesh film with superhydrophobic and superoleophilic properties for oil and water separation. Journal of Chemical Technology and Biotechnology, 87, 427–430.
Wu, D. X., Wu, W. J., Yu, Z. Y., Zhang, C. Y., & Zhu, H. T. (2014a). Facile preparation and characterization of modified polyurethane sponge for oil absorption. Industrial and Engineering Chemistry Research, 53, 20139–20144.
Wu, D. X., Yu, Z. Y., Wu, W. J., Fang, L. L., & Zhu, H. T. (2014b). Continuous oil–water separation with surface modified sponge for cleanup of oil spills. RSC Advances, 4, 53514–53519.
Wu, L., Zhang, J. P., Li, B. C., & Wang, A. Q. (2014c). Mechanical-and oil-durable superhydrophobic polyester materials for selective oil absorption and oil/water separation. Journal of Colloid and Interface Science, 413, 112–117.
Xue, Z. X., Wang, S. T., Lin, L., Chen, L., Liu, M. J., Feng, L., & Jiang, L. (2011). A noval superhydrophilic and underwater superoleophobic hydrogel-coated mesh for oil/water separation. Advanced Materials, 23, 4270–4273.
Xue, C. H., Ji, P. T., Zhang, P., Li, Y. R., & Jia, S. T. (2013). Fabrication of superhydrophobic and superoleophilic textiles for oil–water separation. Applied Surface Science, 284, 464–471.
Yang, J., Song, H. J., Tang, H., Ji, H. Y., & Li, C. S. (2013). Plasma-driven tunable liquid adhesion of superoleophobic aluminum surfaces. Applied Surface Science, 280, 940–944.
Zeng, J. W., & Guo, Z. G. (2014). Superhydrophilic and underwater superoleophobic MFI zeolite-coated film for oil/water separation. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 444, 283–288.
Zhang, X. W., Zhang, T., Ng, J. W., & Sun, D. D. (2009). High-performance multifunctional TiO2 nanowire ultrafiltration membrane with a hierarchical layer structure for water treatment. Advanced Functional Materials, 19, 3731–3736.
Zhang, S. Y., Lu, F., Tao, L., Liu, N., Gao, C. R., Feng, L., & Wei, Y. (2013). Bio-inspired anti-oil-fouling chitosan-coated mesh for oil/water separation suitable for broad ph range and hyper-saline environments. ACS Applied Materials & Interfaces, 5, 11971–11976.
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This work was supported by the National Natural Science Foundation of China (51172117, 51472134), the Natural Science Foundation of Shandong Province (ZR2010EM035, ZR2013EMM003), and the Foundation of Qingdao Science and Technology (13-1-4-148-jch).
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Fan, J., Duan, J., Yu, Z. et al. Oleophobicity of Chitosan/Micron-alumina-Coated Stainless Steel Mesh for Oil/Water Separation. Water Air Soil Pollut 227, 163 (2016). https://doi.org/10.1007/s11270-016-2861-8
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DOI: https://doi.org/10.1007/s11270-016-2861-8