Abstract
The present study aims at assessing the hydrochemistry of the groundwater system of the Maragheh-Bonab Plain located in the East Azarbaijan Province, northwest of Iran. The groundwater is used mainly for drinking, agriculture and industry. The study also discusses the issue of the industrial untreated wastewater discharge to the Plain aquifer that is a high Ca-Cl water type with TDS value of about 150 g/L. The hydrogeochemical study is conducted by collecting and analyzing the groundwater samples from July and September of 2013. The studied system contains three major groundwater types, namely Ca–Mg–HCO3, Na–Cl, and non-dominant water, based on the analysis of the major ions. The main processes contributing to chemical compositions in the groundwater are the dissolution along the flow path, dedolomitisation, ion exchange reactions, and the mixing with wastewater. According to the computed water quality index (WQI) ranging from 25.45 to 194.35, the groundwater in the plain can be categorized into “excellent water”, “good water”, and “poor water”. There is a resemblance between the spatial distribution of the WQI and hydrochemical water types in the Piper diagram. The “excellent” quality water broadly coincides with the Ca-Mg-HCO3 water type. The “poor” water matches with the Na–Cl water type, and the “good” quality water coincides with blended water. The results indicate that this aquifer suffers from intense human activities which are forcing the aquifer into a critical condition.
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References
Acheampong SY, Hess JW (1998) Hydrogeologic and hydrochemical framework of the shallow groundwater system in the southern Voltaian Sedimentary Basin, Ghana. Hydrogeology Journal 6:527–537
Alavi M, Shahrabi M (1978) Geologic map of Maragheh 1: 100000. Geological Survey of Iran, Tehran
Al-Bassam AM (1998) Determination of hydrochemical processes and classification of hydrochemical facies for the Sakakah aquifer, northeastern Saudi Arabia. J African Earth Sci 27(1):27–38
APHA (American Public Health Association) (1998) Standard method for the examination of water and wastewater. 17th edition. Washington, DC
Appelo CAJ, Postma D (2005) Geochemistry, groundwater and pollution, 2nd edn. A.A. Balkema Publishers, Netherlands
Asghari Moghaddam A, Fijani E (2009) Hydrogeologic framework of the Maku area basalts, northwestern Iran. Hydrogeology Journal 17:949–959
Berberian M, King GCP (1981) Towards paleogeography and tectonic evolution of Iran. Earth Science 18(2):210–262
Campbell BG, Amini MH, Bernor RL, Dickinson W, Drake R, Morris R, van Couvering JA, van Couvering JAH (1980) Maragheh: a classical late Miocene vertebrate locality in northwestern Iran. Nature 287:837–841
Chebotarev I (1955) Metamorphism of natural water in the crust of weathering. Geochimica et Cosmochimica Acta 8:22–212
Cloutier V, Lefebvre R, Therrien R, Savard MM (2008) Multivariate statistical analysis of geochemical data as indicative of the hydrogeochemical evolution of groundwater in a sedimentary rock aquifer system. J Hydrol 353(3–4):294–313
Dragon K (2006) Application of factor analysis to study contamination of a semi-confined aquifer (Wielkopolska buried valley aquifer, Poland). Journal of Hydrology 331(1–2):272–279
Dunnette DA (1979) A geographically variable water quality index used in Oregon. Journal of the Water Pollution Control Federation 51(1):53–61
Fijani E, Nadiri A, Asghari Moghaddam A, Tsai FT-C, Dixon B (2013) Optimization of DRASTIC method by supervised committee machine artificial intelligence to assess groundwater vulnerability for Maragheh–Bonab plain aquifer, Iran. J Hydrol 503:89–100
Freeze R, Cherry J (1979) Groundwater. Prentice-Hall, Englewood Cliffs, New Jersey, USA
Hem (1986) Study and interpretation of the chemical characteristics of natural water. U.S. Geological survey, Water Supply Paper 2254
Hossain G, Howladar MF, Nessa L, Ahmed SS, Quamruzzaman C (2010) Hydrochemistry and classification of groundwater resources of Ishwardi municipal area, Pabna District, Bangladesh. Geotechnical and Geological Engineering 28(5):671–679
Hounslow AW (1995) Water quality data: analysis and interpretation. Lewis Publisher, USA
Huang SB, Han ZT, Zhao L, Kong XK (2015) Hydrochemistry indicating groundwater contamination and the potential fate of chlorohydrocarbons in combined polluted groundwater: a case study at a contamination site in North China. Bulletin of Environmental Contamination and Toxicology 94(5):589–597
Jankowski J, Acworth RI, Shekarforoush S (1998) Sources of salinity in the Kyeamba Valley: implications for the agricultural productivity due to the impact of Na-Cl rich groundwaters. In: weaver TR, Lawrence CR(eds) Proc Int groundwater Conf groundwater. Sustainable Solutions, University of Melbourne, Australia, pp. 287–292
Jiang Y, Wu Y, Groves C, Yuan D, Kambesis P (2009) Natural and anthropogenic factors affecting the groundwater quality in the Nandong karst underground river system in Yunan, China. J Contaminant Hydrol 109:49–61
Kortatsi BK (2007) Hydrochemical framework of groundwater in the Ankobra Basin, Ghana. Aquatic Geochemistry 13:41–74
Kumar M, Ramanathan AL, Rao MS, Kumar B (2006) Identification and evaluation of hydrogeochemical processes in the groundwater environment of Delhi, India. J Environ Geol 50:1025–1039
Matthess G, Harvey JC (1982) The properties of groundwater. John Wiley & Sons Inc, U.S.A.
Mazor E, Drever JI, Fineley J, Huntoon PW (1993) Hydrochemical implication of groundwater mixing: an example from the southern Laramie basin, Wyoming. Water Resources Res 29(1):193–205
Mishra PC, Patel RK (2001) Study of the pollution load in the drinking water of Rairangpur, a small tribal dominated town of North Orissa. Indian J Environ Ecoplanning 5(2):293–298
Morgenstern U, Daughney CJ, Leonard G, Gordon D, Donath F, Reeves R (2015) Using groundwater age and hydrochemistry to understand sources and dynamics of nutrient contamination through the catchment into Lake Rotorua, New Zealand. Hydrol Earth Syst Sci 19:803–822
Naik S, Purohit KM (2001) Studies on water quality of river Brahmaniin Sundargarh district, Orissa. Indian Journal of Environment and Ecoplanning 5(2):397–402
Othmer K (1978) Encyclopedia of chemical technology, vol Volume 1, Third edn. John Wiley & Sons publications, U.S.A.
Piper AM (1944) A graphical procedure in the geochemical interpretation of water analyses. American Geophysics 25:914–923
Plummer LN, Busby JF, Lee RW, Hanshaw BB (1990) Geochemical modeling of the Madison aquifer in parts of Montana, Wyoming, and South Dakota. Water Resources Research 26:1981–2014
Rajankar PN, Tambekar DH, Wate SR (2011) Groundwater quality and water quality index at Bhandara District. Environmental Monitoring and Assessment 179:619–625
Ravikumar P, Venkatesharaju K, Somashekar RK (2010) Major ion chemistry and hydrochemical studies of groundwater of Bangalore south Taluk, India. Environmental Monitoring and Assessment 163:643–653
Sahu P, Sikdar PK (2008) Hydrochemical framework of the aquifer in and around East Calcutta wetlands, West Bengal. Indian Environmental Geology 55(4):823–835
Schwartz FW, Zhang H (2003) Fundamentals of ground water. John Wiley and Sons, U.S.A.
Singh DF (1992) Studies on the water quality index of some major rivers of Pune, Maharashtra. Proceedings of the Academy of Environmental Biology 1(1):61–66
Stocklin J (1968) Structural history and tectonics of Iran, a review. American Association of Petroleum Geologists Bulletin 52(7):1229–1258
Subba Rao N (1997) Studies on water quality index in hard rock terrain of Guntur district, Andhra Pradesh. India National Seminar on Hydrology of Precambrian Terrains and Hard Rock Areas:129–134
Tiwari TN, Mishra MA (1985) A preliminary assignment of water quality index of major Indian rivers. Indian J Environ Protect 5:276–279
Umar A, Umar R, Ahmad MS (2001) Hydrogeological and hydrochemical framework of regional aquifer system in Kali-ganga sub-basin, India. Environmental Geology 40(4–5):602–611
Umar R, Ahmed I, Alam F, Khan MM (2009) Hydrochemical characteristics and seasonal variations in groundwater quality of an alluvial aquifer in parts of central ganga plain, western Uttar Pradesh, India. Environmental Geology 58:1295–1300
Vasanthavigar M, Srinivasamoorthy K, Vijayaragavan K, Ganthi RR, Chidambaram S, Anandhan P, Manivannan R, Vasudevan S (2010) Application of water quality index for groundwater quality assessment: Thirumanimuttar sub-basin. India Environ Monitor Assess 171:595–609
Water and Soil consulting corporation (1975). Geoelectrical Survey of Maragheh (in Persian).
Water Resource Corporation of East Azarbaijan Province (1964) Report of groundwater resources studies in Maragheh area (in Persian).
WHO (World Health Organization) (2009). Guideline for drinking water quality.
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The authors would like to thank the East Azerbaijan Regional Water Authority for providing an access to their data.
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Fijani, E., Moghaddam, A.A., Tsai, F.TC. et al. Analysis and Assessment of Hydrochemical Characteristics of Maragheh-Bonab Plain Aquifer, Northwest of Iran. Water Resour Manage 31, 765–780 (2017). https://doi.org/10.1007/s11269-016-1390-y
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DOI: https://doi.org/10.1007/s11269-016-1390-y