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Control of the NO–NH3 SCR Behavior of Cu-ZSM-5 by Variation of the Electronic State of Copper

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Abstract

The effect of NH4OH/Cu2+ in a copper-acetate solution on the properties of ion-exchanged Cu-ZSM-5 catalysts in the selective catalytic reduction of NO by NH3 (NO–NH3 SCR) has been studied. The temperature programmed desorption of ammonia (NH3-TPR) on Cu-ZSM-5 and the ammonia adsorption–desorption dynamics at 75–300 °C were studied to identify and quantify the nature of acid sites and ammonia desorption heat of Cu-ZSM-5. The Cu-ZSM-5 catalysts containing Cu-structures with extra-lattice oxygen were active in the low-temperature SCR, whereas those with isolated Cu2+ ions were active in the high-temperature SCR. It was shown that Cu-structures with extra-lattice oxygen were generated during the ion exchange of H-ZSM-5 with a water-ammonia solution of copper-acetate where the NH4OH/Cu2+ ratio was in the range of 6–15. Isolated Cu2+ ions were produced in the ion-exchange mode with the ammonia-free solution.

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Acknowledgements

The work was conducted within the framework of the budget project (АААА-А17-117041710086-6) of Boreskov Institute of Catalysis.

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Authors and Affiliations

  1. Boreskov Institute of Catalysis, Novosibirsk, 630090, Russia

    S. A. Yashnik & Z. R. Ismagilov

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  1. S. A. Yashnik
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  2. Z. R. Ismagilov
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Correspondence to S. A. Yashnik.

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Yashnik, S.A., Ismagilov, Z.R. Control of the NO–NH3 SCR Behavior of Cu-ZSM-5 by Variation of the Electronic State of Copper. Top Catal 62, 179–191 (2019). https://doi.org/10.1007/s11244-018-1101-4

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