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A series of heterobimetallic Ni(II)–Ln(III) (Ln = La, Ce, Pr and Nd) coordination polymers derived from 3-EtOsalamo and dicarboxylates: syntheses, crystal structures and fluorescence properties

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Abstract

Four coordination polymers 2∞ [Ni(DMF)(L)Ln(bdc)1.5] (Ln = La (1) and Nd (4)) and 2∞ [Ni2(DMF)2(L)2Ln2(bdc)3]·CH3OH (Ln = Ce (2) and Pr (3)) were derived from a symmetrical salamo-based ligand (H2L) with Ni(OAc)2·4H2O, Ln(NO3)3·6H2O (Ln = La, Ce, Pr and Nd), and H2bdc (terephthalic acid). Coordination polymers 1–4 were synthesized and characterized by elemental analyses, X-ray single crystal diffraction, infrared spectroscopy and ultraviolet–visible absorption spectroscopy. Coordination polymers 1–4 have similar structures exhibiting two-dimensional coordination polymers with brick wall in which [Ni(DMF)(L)Ln] units were linked by exodentate (bdc)2− linker. In each unit, Ni(II) atoms adopted a slightly distorted octahedral geometry, the Ln(III) atoms were nine-coordinated, and the coordination polyhedron was a distorted tricapped trigonal prism. The crystal structure and supramolecular features were discussed in detail. At the same time, the fluorescent properties of coordination polymers 1–4 were also investigated.

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Acknowledgements

This work was supported by the National Natural Science Foundation of China (21761018) and the Program for Excellent Team of Scientific Research in Lanzhou Jiaotong University (201706), which are gratefully acknowledged.

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Authors and Affiliations

  1. School of Chemical and Biological Engineering, Lanzhou Jiaotong University, Lanzhou, 730070, People’s Republic of China

    Yu Zhang, Ya-Juan Li, Shuang-Zhu Guo, Tao Fu & Li Zhao

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  1. Yu Zhang
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Correspondence to Li Zhao.

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Zhang, Y., Li, YJ., Guo, SZ. et al. A series of heterobimetallic Ni(II)–Ln(III) (Ln = La, Ce, Pr and Nd) coordination polymers derived from 3-EtOsalamo and dicarboxylates: syntheses, crystal structures and fluorescence properties. Transit Met Chem 45, 485–492 (2020). https://doi.org/10.1007/s11243-020-00400-0

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