Abstract
Three coordination polymers based on the new ligand oxamide N,N-bis(4-phthalic acid), namely [Zn(L)0.5-(2,2′-bpy)] n (1), [Ni2(2,2′-bpy)4(µ 2-Ox)]L·3H2O (2) and [Cd(L)(1,10-phen)] (3) [L = oxamide N,N-bis(4-phthalic acid)], (2,2′-bpy = 2,2′-bipyridine), (1,10-phen = 1,10-phenanthroline), have been solvothermally synthesized and structurally characterized by single-crystal X-ray diffraction: compound 1 is one-dimensional ladder-like coordination polymer, compound 2 exhibits a three-dimensional structure resulting in extensive hydrogen bonds built with the help of lattice water molecules, compound 3 also exhibits a three-dimensional supramolecular structure. All compounds were also characterized by elemental analysis, IR spectra and thermogravimetric analysis; furthermore, the magnetic measurements for 2 reveal antiferromagnetic coupling between the nickel(II) ions.
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Acknowledgments
We are very grateful for the support of this study by the National Natural Science Foundation of China (Nos. 21461023 and 21361023), Fundamental Research Funds for the Gansu Universities.
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Osman, I.O., Deng, WT., Fan, Y. et al. Zinc(II), nickel(II) and cadmium(II) coordination polymers based on the ligand oxamide N,N-bis(4-phthalic acid): synthesis, structural characterization and magnetic properties. Transition Met Chem 41, 133–141 (2016). https://doi.org/10.1007/s11243-015-0005-4
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DOI: https://doi.org/10.1007/s11243-015-0005-4