Skip to main content
Log in

Effect of the Method of Preparation of ZnO/CdS and TiO2/CdS Film Nanoheterostructures on Their Photoelectrochemical Properties

  • Published:
Theoretical and Experimental Chemistry Aims and scope

A study was carried out on the photoelectric properties of ITO/TiO2/CdS and ITO/ZnO/CdS nanostructurized films obtained by the SILAR method and the photocatalytic reduction of sulfur by ethanol in the presence of Cd(II) salts. The nanostructures obtained by the latter method display much higher photocurrent density (by a factor of 2 in the case of systems derived from ZnO and a factor of 5 in systems derived from TiO2) upon irradiation with white light (λ > 400 nm) in aqueous solutions of sodium sulfide than the heterostructures obtained by the traditional SILAR method.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3

Similar content being viewed by others

References

  1. S. Rühle, M. Shalom, and A. Zaban, ChemPhysChem, 11, No. 11, 2290–2304 (2010).

    Article  Google Scholar 

  2. G. Hodes, J. Phys. Chem. C, 112, No. 46, 17778–17787 (2008).

    Article  CAS  Google Scholar 

  3. P. V. Kamat, J. Phys. Chem. C, 112, No. 48, 18737–18753 (2008).

    CAS  Google Scholar 

  4. P. V. Kamat, K. Tvrdy, D. R. Baker, and J. G. Radich, Chem. Rev., 110, No. 11, 6664–6688 (2010).

    Article  CAS  Google Scholar 

  5. Z. Yang, C.-Y. Chen, P. Roy, and H.-T. Chang, Chem. Commun., 47, No. 34, 9561–9571 (2011).

    Article  CAS  Google Scholar 

  6. H. Tada, M. Fujishima, and H. Kobayashi, Chem. Soc. Rev., 40, No. 7, 4232–4243 (2011).

    Article  CAS  Google Scholar 

  7. M. Fujii, K. Nagasuna, M. Fujishima, et al., J. Phys. Chem. C, 113, No. 38, 16711–16716 (2009).

    Article  CAS  Google Scholar 

  8. K. Nagasuna, T. Akita, M. Fujishima, and H. Tada, Langmuir, 27, No. 11, 7294–7300 (2011).

    Article  CAS  Google Scholar 

  9. B. Ma, L. Wang, H. Dong, et al., Phys. Chem. Chem. Phys., 13, No. 7, 2656–2658 (2011).

    Article  CAS  Google Scholar 

  10. A. L. Stroyuk, V. V. Shvalagin, A. E. Raevskaya, et al., Teor. Éksp. Khim., 44, No. 4, 199–220 (2008). [Theor. Exp. Chem., 44, No. 4, 205–231 (2008) (English translation).]

    Google Scholar 

  11. M. A. Zhukovskiy, O. L. Stroyuk, V. V. Shvalagin, et al., Photochem. Photobiol. A, 203, Nos. 2/3, 137–144 (2009).

    Article  CAS  Google Scholar 

  12. A. L. Stroyuk, C. Ya. Kuchmii, M. A. Zhukovskii, et al., Teor. Éksp. Khim., 45, No. 5, 289–294 (2009). [Theor. Exp. Chem., 45, No. 5, 302–307 (2009) (English translation).]

    Google Scholar 

  13. V. V. Shvalagin, A. L. Stroyuk, and S. Ya. Kuchmii, Teor. Éksp. Khim., 43, No. 4, 215–219 (2007). [Theor. Exp. Chem., 43, No. 4, 229–234 (2007) (English translation).]

    Google Scholar 

  14. O. L. Stroyuk, O. Ye. Rayevska, V. V. Shvalagin, et al., Photochem. Photobiol. Sci., DOI: 10.1039/c2pp25196e (2012).

    Google Scholar 

  15. A. V. Kozitskii, A. L. Stroyuk, S. Ya. Kuchmii, et al., Teor. Éksp. Khim., 48, No. 5, 308–314 (2012). [Theor. Exp. Chem., 48, No. 5, 331–337 (2012) (English translation).]

    Google Scholar 

  16. S. V. Gaponenko, Optical Properties of Semiconductor Nanocrystals, University Press, Cambridge (1998).

    Book  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to A. L. Stroyuk.

Additional information

Translated from Teoreticheskaya i Éksperimental’naya Khimiya, Vol. 49, No. 3, pp. 153–158, May-June, 2013.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Kozytskiy, A.V., Stroyuk, A.L., Kuchmy, S.Y. et al. Effect of the Method of Preparation of ZnO/CdS and TiO2/CdS Film Nanoheterostructures on Their Photoelectrochemical Properties. Theor Exp Chem 49, 165–171 (2013). https://doi.org/10.1007/s11237-013-9310-1

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11237-013-9310-1

Key words

Navigation