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Calculation of the specific heat close to the multicritical and second order phase regions in ND4Cl

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Abstract

We calculated the specific heat C V of ND4Cl under the prediction of an Ising model presented here. Our calculated C V agrees with the experimental C P data for the multicritical (P = 0.1 MPa) and second order (P = 150 MPa) phase regions in this crystalline system. This agreement is particularly good above T C \( ( \cong \)250 K) for the multicritical regime and below T C \( (\cong \)261 K) for the second order phase transition in ND4Cl. This shows that the observed behaviour of ND4Cl can be well described by an Ising model close to the phase transitions considered in this crystalline system.

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References

  1. Garland CW, Bruins DE, Greytak TJ (1975) Phys Rev B 12:2759

    Article  CAS  Google Scholar 

  2. Bruins DE, Garland CW (1975) J Chem Phys 63:4139

    Article  CAS  Google Scholar 

  3. Garland CW, Baloga JD (1977) Phys Rev B16:331

    Google Scholar 

  4. Yelon WB, Cox DE (1972) Solid State Comm 11:1011

    Article  CAS  Google Scholar 

  5. Yelon WB, Cox DE, Kortman PJ, Daniels WB (1974) Phys Rev B9:4843

    Google Scholar 

  6. Garland CW, Weiner BB (1971) Phys Rev B3:1634

    Google Scholar 

  7. Benguigui LA (1976) Solid State Comm 20:173

    Article  CAS  Google Scholar 

  8. Zahradnik C, Garland CW (1979) J Chem Phys 70:1011

    Article  CAS  Google Scholar 

  9. Smits A, Müller GJ, Kröger FA (1937) Z Phys Chem B38:177

    CAS  Google Scholar 

  10. Nagamiya T (1942) Proc Phys Math Soc Japan 24:137

    CAS  Google Scholar 

  11. Seymour RS (1971) Acta Cryst A27:348

    Google Scholar 

  12. Hüller A (1972) Z Phys 254:456

    Article  Google Scholar 

  13. Yelon WB (1973) Proceedings of the NATO ASI Anharmonic Lattices, Structural Transitions and Melting, p 255

  14. Stevenson R (1976) J Chem Phys 34:346

    Article  Google Scholar 

  15. Press W, Eckert J, Cox DE, Rotter C, Kamitakahara W (1976) Phys Rev B14:1983

    Google Scholar 

  16. Leung RC, Zahradnik C, Garland CW (1979) Phys Rev B19:2612

    Google Scholar 

  17. Anderson P, Ross RG (1987) J Phys C: Solid State Phys 20:4737

    Article  Google Scholar 

  18. Yamada Y, Mori M, Noda Y (1972) J Phys Soc Japan 32:1565

    Article  CAS  Google Scholar 

  19. Hüller A (1974) Z Phys 270:343

    Article  Google Scholar 

  20. Vaks VG, Schneider VE (1976) Phys Stat Sol (a) 35:61

    Article  CAS  Google Scholar 

  21. Vlasova AA, Tornau EE, Schneider VE (1978) Fiz Tverd Tela (Leningrad) 20:858

    CAS  Google Scholar 

  22. Yurtseven H, Salihoğlu S, Tüblek A (1995) Phase Trans 54:151

    Article  CAS  Google Scholar 

  23. Seeck OH, Hupfeld D, Krull H, Tolan M (1998) Phys Rev B58:623

    Google Scholar 

  24. Couzi M, Denoyer F, Lambert M (1974) J Phys (France) 35:753

    CAS  Google Scholar 

  25. McKenzie DR, Seymour RS (1975) J Phys C: Solid State Phys 8:1071

    Article  CAS  Google Scholar 

  26. Yurtseven H, Sherman WF (1994) Phase Trans 47:69

    Article  CAS  Google Scholar 

  27. Yurtseven H, Kayışoğlu D, Sherman WF (1998) Phase Trans 67:399

    Article  CAS  Google Scholar 

  28. Yurtseven H, Mertoğlu A (2001) J Chin Phys 39:349

    CAS  Google Scholar 

  29. Mouritsen OG (1984) Computer studies of phase transitions and critical phenomena, Springer-Verlag, Berlin, Heidelberg

  30. Garland CW, Renard R (1966) J Chem Phys 44:1130

    Article  CAS  Google Scholar 

  31. Renard R, Garland CW (1966) J Chem Phys 44:1125

    Article  CAS  Google Scholar 

  32. Garland CW, Renard R (1966) J Chem Phys 44:1120

    Article  CAS  Google Scholar 

  33. Slichter CP, Seidel H, Schwartz P, Fredericks GE (1971) Phys Rev B 4:907

    Article  Google Scholar 

  34. Fredericks GE (1971) Phys Rev B 4:911

    Article  Google Scholar 

  35. Schwartz P (1971) Phys Rev B 4:920

    Article  Google Scholar 

  36. Yurtseven H (1994) Phase Trans 47:59

    Article  CAS  Google Scholar 

  37. Geisel T, Keller J (1975) J Chem Phys 62:3777

    Article  CAS  Google Scholar 

  38. Yurtseven H, Sherman WF (1995) Phase Trans 54:165

    Article  CAS  Google Scholar 

  39. Andrews SR, Harley RT, Jahn IR, Sherman WF (1982) J Phys C: Solid State Phys 15:4679

    Article  CAS  Google Scholar 

  40. Wagner EL, Hornig DF (1950) J Chem Phys 18:296

    Article  CAS  Google Scholar 

  41. Boiko AA (1970) Sov Phys Crystallography 14:539

    Google Scholar 

  42. Fredrickson LR, Decius JC (1974) J Chem Phys 60:4630

    Article  Google Scholar 

  43. Trappeniers NJ, van der Molen Th J (1966) Physica 32:1161

    Article  CAS  Google Scholar 

  44. Wirths M, Schneider GM (1981) J Chem Thermodynamics 13:701

    Article  CAS  Google Scholar 

  45. Pistorius CWFT (1969) J Chem Phys 50:1436

    Article  CAS  Google Scholar 

  46. Yurtseven H, Yanık A (2005) J App Phys 98:094104-1

    Google Scholar 

  47. Weiner BB, Garland CW (1972) J Chem Phys 56:155

    Article  CAS  Google Scholar 

Download references

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Correspondence to Hamit Yurtseven.

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Yurtseven, H., Yanık, A. Calculation of the specific heat close to the multicritical and second order phase regions in ND4Cl. Struct Chem 18, 937–941 (2007). https://doi.org/10.1007/s11224-007-9217-3

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