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Influence of the steric properties of pyridine ligands on the structure of complexes containing the {LnCd2(bzo)7} fragment

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Abstract

The reaction of Cd(NO3)2 · 4H2O and Eu(NO3)3 · 6H2O or Tb(NO3)3 · 6H2O with potassium 3,5-di-tert-butylbenzoate (Kbzo) and N-donor ligands (1,10-phenanthroline (phen), 2,4-lutidine (2,4-lut), 3,4-lutidine (3,4-lut), phenanthridine (phtd), 2,3-cyclododecenopyridine (cdpy), acridine (acr)) afforded heterometallic LnCd2 complexes: [EuCd2(bzo)7(EtOH)2(phen)] (2), [LnCd2(bzo)7(2,4-lut)4] (Ln = Eu (3), Tb (4)), [EuCd2(bzo)7(H2O)2(2,4-lut)2] · MeCN (5), [EuCd2(NO3)(bzo)6(EtOH)2(2,4-lut)2] (6), [EuCd2(bzo)7(H2O)(EtOH)(3,4-lut)2] · 5EtOH (7), 3[EuCd2(bzo)7(H2O)2(phtd)2] · 4phtd (8), [EuCd2(bzo)7(EtOH)3(cdpy)] (9), 2[EuCd2-(bzo)2(EtOH)4] · acr (10). The structures of complexes 2, 3, and 5–10 were determined by single-crystal X-ray diffraction. The isostructurality of complexes 3 and 4 was confirmed by powder X-ray diffraction. The structure of the trinuclear {Ln2Cd} metal core is stable and independent of the type of peripheral ligands coordinated to cadmium atoms. Photoluminescent properties of compounds 3 and 4 were studied.

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Authors and Affiliations

  1. N. S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 31 Leninsky prosp., 119991, Moscow, Russian Federation

    M. A. Shmelev, Yu. K. Voronina, N. V. Gogoleva, A. A. Sidorov, M. A. Kiskin, G. G. Aleksandrov & I. L. Eremenko

  2. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 119991, Moscow, Russian Federation

    F. M. Dolgushin, Yu. V. Nelyubina, E. A. Varaksina & I. V. Taydakov

  3. P. N. Lebedev Physical Institute, Russian Academy of Sciences, 53 Leninsky prosp., 119333, Moscow, Russian Federation

    E. A. Varaksina & I. V. Taydakov

  4. Moscow Institute of Physics and Technology, 9 Institutskiy per., 141700, Dolgoprudny, Moscow region, Russian Federation

    I. V. Taydakov

Authors
  1. M. A. Shmelev
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  2. Yu. K. Voronina
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  3. N. V. Gogoleva
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  4. A. A. Sidorov
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  5. M. A. Kiskin
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  6. F. M. Dolgushin
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  7. Yu. V. Nelyubina
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  8. G. G. Aleksandrov
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  9. E. A. Varaksina
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  10. I. V. Taydakov
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  11. I. L. Eremenko
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Correspondence to M. A. Shmelev.

Additional information

Dedicated to Academician of the Russian Academy of Sciences A. M. Muzafarov on the occasion of his 70th birthday.

Deceased.

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 8, pp. 1544–1560, August, 2020.

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Shmelev, M.A., Voronina, Y.K., Gogoleva, N.V. et al. Influence of the steric properties of pyridine ligands on the structure of complexes containing the {LnCd2(bzo)7} fragment. Russ Chem Bull 69, 1544–1560 (2020). https://doi.org/10.1007/s11172-020-2934-0

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  • DOI: https://doi.org/10.1007/s11172-020-2934-0

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