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New pyridylphenylene cyclopentadienon as a building block for dendrimer synthesis

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Abstract

The synthesis of new tetrasubstituted pyridyl-containing cyclopentadienone, namely, 3,4-bis(4-(phenylethynyl)phenyl)-2,5-di(pyridin-2-yl)cyclopenta-2,4-dien-1-one is reported for the first time as a monomer for dendrimer synthesis. The synthesis by Diels—Alder approach allowed to prepare 2nd generation dendrimer with phenylethynyl peripherial fragments. A presence of triple bonds in the structure of dendrimers determines the possibility of their subsequent modification, in particular, by coordinating with metal compounds to obtain catalytically active nanocomposites.

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Authors and Affiliations

  1. A. N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, 28 ul. Vavilova, 119991, Moscow, Russian Federation

    A. S. Torozova, I. Yu. Krasnova & Z. B. Shifrina

  2. D. I. Mendeleev University of Chemical Technology of Russia, 9 Miusskaya pl., 125047, Moscow, Russian Federation

    A. A. Korolkova

Authors
  1. A. S. Torozova
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  2. A. A. Korolkova
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  3. I. Yu. Krasnova
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  4. Z. B. Shifrina
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Corresponding author

Correspondence to Z. B. Shifrina.

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Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 1, pp. 0091–0096, January, 2020.

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Torozova, A.S., Korolkova, A.A., Krasnova, I.Y. et al. New pyridylphenylene cyclopentadienon as a building block for dendrimer synthesis. Russ Chem Bull 69, 91–96 (2020). https://doi.org/10.1007/s11172-020-2727-5

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  • DOI: https://doi.org/10.1007/s11172-020-2727-5

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