Abstract
Isothermal calorimetry, static and dynamic light scattering, and NMR spectroscopy studies provided evidence for slow formation of large associates of solvates in aqueous solutions of nitric acid, which makes it possible to attribute the anomalous kinetic features in the oxidation of acetone to the supramolecular mechanism of the reaction.
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Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 4, pp. 0984—0992, April, 2016.
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Lagodzinskaya, G.V., Laptinskaya, T.V., Kazakov, A.I. et al. Slow large-scale supramolecular structuring as a cause of kinetic anomalies in the liquid-phase oxidation with nitric acid. Russ Chem Bull 65, 984–992 (2016). https://doi.org/10.1007/s11172-016-1401-4
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DOI: https://doi.org/10.1007/s11172-016-1401-4