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2D coordination polymers of AgI—MII (MII = Ni, Cu) with anions of substituted malonic acids

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Abstract

Heterometallic malonate complexes [Ag2Ni(H2O)2(R2mal)2]n (R2mal2– is the dimethylmalonate dianion (Me2mal2–) (1) or the cyclobutane-1,1-dicarboxylate dianion (Cbdc2–) (2)) and [Ag2Cu(H2O)(Me2mal)2]n (3) were synthesized. The bis-chelate fragment {M(R2mal)2} (M = Ni, Cu) composed of two dianions of an acid and a 3d metal atom is the structure-forming unit of these complexes. The mononuclear fragments are linked by silver(I) atoms, which are involved in argentophilic interactions, to form 2D coordination polymers.

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Author information

Authors and Affiliations

  1. N. S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 31 Leninsky prosp., 119991, Moscow, Russian Federation

    E. N. Zorina-Tikhonova, N. V. Gogoleva, G. G. Aleksandrov, M. A. Kiskin, A. A. Sidorov & I. L. Eremenko

  2. Samara Center for Theoretical Materials Science, Samara State University., 1 ul. Akademika Pavlova, 443011, Samara, Russian Federation

    E. V. Aleksandrov

  3. S. P. Korolev Samara State Aerospace University (National Research University), 34 Moskovskoye shosse, 443086, Samara, Russian Federation

    E. V. Aleksandrov

Authors
  1. E. N. Zorina-Tikhonova
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  2. N. V. Gogoleva
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  3. E. V. Aleksandrov
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  4. G. G. Aleksandrov
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  5. M. A. Kiskin
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  6. A. A. Sidorov
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  7. I. L. Eremenko
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Corresponding author

Correspondence to E. N. Zorina-Tikhonova.

Additional information

Dedicated to Academician of the Russian Academy of Sciences V. M. Novotortsev on the occasion of his 70th birthday.

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 3, pp. 0759—0766, March, 2016.

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Zorina-Tikhonova, E.N., Gogoleva, N.V., Aleksandrov, E.V. et al. 2D coordination polymers of AgI—MII (MII = Ni, Cu) with anions of substituted malonic acids. Russ Chem Bull 65, 759–766 (2016). https://doi.org/10.1007/s11172-016-1370-7

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  • DOI: https://doi.org/10.1007/s11172-016-1370-7

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