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In situ XPS study of the size effect in the interaction of NO with the surface of the model Ag/Al2O3/FeCrAl catalysts

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Abstract

The interaction of NO with the surface of model Ag/Al2O3/FeCrAl catalysts containing Ag nanoparticles of different size (1 and 3 nm) was studied. The use of the Auger parameter αAg (E b(Ag3d5/2) + E kin(Ag MVV)) made it possible to reliably identify the change in the chemical state of silver cluster upon their interaction with О2 and NO. The oxygen treatment leads to the oxidation of small Ag nanoparticles (1 nm) and formation of AgO x clusters resulted in the intensive formation of nitrite—nitrate structures on the step of the interaction with NO. These structures are localized on both the silver clusters and Al2O3 surface. An increase in the size of Ag0 nanoparticles to 3 nm results in an increase in the stability of these structures and impedes the Ag0 → AgO x transition, due to which the formation of surface groups NO2 –/NO3 – is suppressed. The data obtained make it possible to explain the dependence of the activity of the Ag/Al2O3 catalysts in the selective reduction of NO on the Ag nanoparticle size.

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Authors and Affiliations

  1. G. K. Boreskov Institute of Catalysis, Siberian Branch of the Russian Academy of Sciences, 5 prosp. Akad. Lavrent´eva, 630090, Novosibirsk, Russian Federation

    A. V. Bukhtiyarov, I. P. Prosvirin & V. I. Bukhtiyarov

  2. Novosibirsk State University, 2 ul. Pirogova, 630090, Novosibirsk, Russian Federation

    A. V. Bukhtiyarov, I. P. Prosvirin & V. I. Bukhtiyarov

  3. N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 119991, Moscow, Russian Federation

    A. Yu. Stakheev & A. I. Mytareva

Authors
  1. A. V. Bukhtiyarov
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  2. A. Yu. Stakheev
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  3. A. I. Mytareva
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  4. I. P. Prosvirin
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  5. V. I. Bukhtiyarov
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Correspondence to A. V. Bukhtiyarov.

Additional information

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 12, pp. 2780—2785, December, 2015.

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Bukhtiyarov, A.V., Stakheev, A.Y., Mytareva, A.I. et al. In situ XPS study of the size effect in the interaction of NO with the surface of the model Ag/Al2O3/FeCrAl catalysts. Russ Chem Bull 64, 2780–2785 (2015). https://doi.org/10.1007/s11172-015-1225-7

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  • DOI: https://doi.org/10.1007/s11172-015-1225-7

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