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Synthesis and structure of uranyl complexes with malonic acid dianions

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The uranyl complexes with malonic acid dianions [UO2(C3H2O4)(CO(NH2)2)]·H2O (1), [UO2(C3H2O4)(CONH2NMe2)]·H2O (2), and [UO2(C3H2O4)(MeCONMe2)] (3) were synthesized and characterized by X-ray crystallography. The structural units [UO2(C3H2O4)L] in the crystals of 13 refer to the AK21M1 crystal chemical group (A = UO2 2+, K21 = C3H2O4 2−, M1 = L) of uranyl complexes; the crystals of 1 have a framework structure and 2 and 3 have a chain structure. Some structural features of the [UO2(C3H2O4)L] complex groups are discussed.

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Correspondence to L. B. Serezhkina.

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Dedicated to the memory of Corresponding Member of the Russian Academy of Sciences Mikhail Yuvenal’evich Antipin (1951–2013).

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 8, pp. 1835–1842, August, 2013.

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Serezhkin, V.N., Grigor’ev, M.S., Vologzhanina, A.V. et al. Synthesis and structure of uranyl complexes with malonic acid dianions. Russ Chem Bull 62, 1835–1842 (2013). https://doi.org/10.1007/s11172-013-0264-1

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  • DOI: https://doi.org/10.1007/s11172-013-0264-1

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