Skip to main content
SpringerLink
Log in

Platinum-catalyzed addition of iodomethane to acetylene

  • Full Articles
  • Published:
Russian Chemical Bulletin Aims and scope

Abstract

The reaction of iodomethane and acetylene in the presence of PtII and NaI in acetone gives (E)-1-iodopropene. A possible mechanism involves the intermediate formation of a PtIV methyl vinyl derivative by the iodoplatination of acetylene with a reversibly formed a PtIV methyl complex and assumes the catalytic character of the process.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. I. P. Beletskaya, A. V. Cherpakov, Comprehensive Coordination Chemistry II, Elsevier Pergamon, 2004, Vol. 9, p. 305.

    Article  CAS  Google Scholar 

  2. V. P. Ananikov, I. P. Beletskaya, Organometallics, 2012, 31, 1595.

    Article  CAS  Google Scholar 

  3. Metal-Catalyzed Cross-Coupling Reactions, Eds F. Diederich, P. J. Stang, Wiley-VCH, Wienheim, 1998, 540 pp.

    Google Scholar 

  4. S. A. Mitchenko, O. V. Khazipov, T. V. Krasnyakova, Teor. Eksp. Khim., 2012, 48, 230 [Theor. Exp. Chem. (Engl. Transl.), 2012, 48, 246].

    Google Scholar 

  5. S. A. Mitchenko, O. V. Khazipov, M. Yu. Zubritskii, T. V. Krasnyakova, N. S. Silina, Teor. Eksp. Khim., 2012, 48, 315 [Theor. Exp. Chem. (Engl. Transl.), 2012, 48, 338].

    Google Scholar 

  6. Sintez kompleksnykh soedinenii metallov platinovoi gruppy: Spravochnik [Synthesis of Complexes of Platinum Group Metals: Manual], Ed. I. N. Chernyaev, Nauka, Moscow, 1964 (in Russian).

    Google Scholar 

  7. J. R. L. Priqueler, I. S. Butler, F. D. Rochon, Appl. Spectrosc. Rev., 2006, 41, 185.

    Article  CAS  Google Scholar 

  8. S. A. Mitchenko, V. P. Ananikov, I. P. Beletskaya, Y. A. Ustynyuk, Mendeleev Commun., 1997, 7, 130.

    Article  Google Scholar 

  9. R. K. Harris, B. R. Howes, J. Mol. Spectrosc., 1968, 28, 191.

    Article  CAS  Google Scholar 

  10. K. Hasegawa, R. Asami, K. Takahashi, Bull. Chem. Soc. Jpn, 1978, 51, 916.

    Article  CAS  Google Scholar 

  11. A. N. Vedernikov, Chem. Commun., 2009, 32, 4781.

    Article  Google Scholar 

  12. S. A. Mitchenko, V. V. Zamashchikov, O. N. Pryadko, Kinet. Katal., 1993, 34, 484 [Kinet. Catal. (Engl. Transl.), 1993, 34, No. 3].

    CAS  Google Scholar 

  13. V. P. Ananikov, D. G. Musaev, K. Morokuma, Organometallics, 2005, 24, 715.

    Article  CAS  Google Scholar 

  14. A. Ariafard, Z. Ejehi, H. Sadrara, T. Mehrabi, S. Etaati, A. Moradzadeh, M. Moshtaghi, H. Nosrati, N. J. Brookes, B. F. Yates, Organometallics, 2011, 30, 422.

    Article  CAS  Google Scholar 

  15. V. P. Ananikov, S. A. Mitchenko, I. P. Beletskaya, J. Organomet. Chem., 2000, 604, 290.

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. L. M. Litvinenko Institute of Physicoorganic Chemistry and Coal Chemistry, National Academy of Sciences of Ukraine, 20 ul. R. Lyuksemburg, 83114, Donetsk, Ukraine

    S. A. Mitchenko, O. V. Khazipov & T. V. Krasnyakova

  2. Luhansk Taras Shevchenko National University, 2 ul. Oboronna, 91011, Luhansk, Ukraine

    T. V. Krasnyakova

Authors
  1. S. A. Mitchenko
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. O. V. Khazipov
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. T. V. Krasnyakova
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to S. A. Mitchenko.

Additional information

Dedicated to the Academician of the Russian Academy of Sciences I. P. Beletskaya on the occasion of her anniversary.

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 4, pp. 0984—0988, April, 2013.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Mitchenko, S.A., Khazipov, O.V. & Krasnyakova, T.V. Platinum-catalyzed addition of iodomethane to acetylene. Russ Chem Bull 62, 984–988 (2013). https://doi.org/10.1007/s11172-013-0128-8

Download citation

  • Received:

  • Revised:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11172-013-0128-8

Key words

Search

Navigation