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The influence of perchloric acid on 2,3-dimethylpyrazine and 1,2-bis(4-pyridyl)ethane: crystal structure and Hirshfeld surfaces analysis

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Abstract

2,3-Dimethylpyrazine and 1,2-bis(4-pyridyl)ethane are both N-containing aromatic heterocyclics with two N atoms approximately in the para position. We here report two compounds derived from these heterocyclics (compounds 1 and 2). Compounds 1 and 2 both form a 1:1 2,3-dimethylpyrazine:perchloric acid (PA) and 1,2-bis(4-pyridyl)ethane:PA cocrystal, respectively. Their crystal structures were characterized by single-crystal X-ray diffraction, which revealed that the C–H⋯O and N–H⋯O hydrogen bonding interactions were found to stabilize the crystal structure in compounds 1 and 2. However, PA plays a necessary role for the one-dimensional structure in 1 and the three-dimensional structure in 2. Hirshfeld surfaces and fingerprint plots were applied to get the same conclusion.

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Acknowledgments

We are highly grateful to the financial support from the National Natural Science Foundation of China (No. 21241009, No. 21371031), and the 2014 College Graduate Innovation Projects in Jiangsu Province (No. SJLX_0089).

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Authors and Affiliations

  1. School of Chemistry and Chemical Engineering, Southeast University, Nanjing, 211189, People’s Republic of China

    Yang Ling, Wei Wang, Li-Jing Yang, Qing-Ling Liu, Yang-Hui Luo, Li-Hai Zhai & Bai-Wang Sun

  2. College of Chengxian, Southeast University, Nanjing, 210088, People’s Republic of China

    Wei Wang

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  1. Yang Ling
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  2. Wei Wang
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Correspondence to Bai-Wang Sun.

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Ling, Y., Wang, W., Yang, LJ. et al. The influence of perchloric acid on 2,3-dimethylpyrazine and 1,2-bis(4-pyridyl)ethane: crystal structure and Hirshfeld surfaces analysis. Res Chem Intermed 42, 673–685 (2016). https://doi.org/10.1007/s11164-015-2049-7

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