Skip to main content
Log in

A facile synthesis of hierarchical flower-like TiO2 with enhanced photocatalytic activity

  • Published:
Research on Chemical Intermediates Aims and scope Submit manuscript

Abstract

The hierarchical flower-like TiO2 has been achieved by using a simple solvothermal process without any surfactants or colloidal crystals as a template. The structures of the products were characterized by powder X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), and nitrogen adsorption–desorption analysis. The relationship between hierarchical structure and photocatalytic performance has been presented based on detailed characterizations. It was found that the hierarchical flower-like structure was a benefit for light absorption and significantly enhanced the photocatalytic activity.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6

Similar content being viewed by others

References

  1. M.M. Maye, I.I.S. Lim, J. Luo, Z. Rab, D. Rabinovich, T.-B. Liu, C.-J. Zhong, J. Am. Chem. Soc. 127, 1519 (2005)

    Article  CAS  Google Scholar 

  2. V. Tzitzios, D. Niarchos, M. Gjoka, N. Boukos, D. Petridis, J. Am. Chem. Soc. 127, 13756 (2005)

    Article  CAS  Google Scholar 

  3. G. Hu, D. Ma, L. Liu, M. Cheng, X.-H. Bao, Angew. Chem. Int. Ed. Engl. 43, 3452 (2004)

    Article  CAS  Google Scholar 

  4. M. Mo, J.-C. Yu, L.-Z. Zhang, S.K.A. Li, Adv. Mater. 17, 756 (2005)

    Article  CAS  Google Scholar 

  5. A.L. Linsebigler, G.-Q. Lu, J. T. Yates Jr., Chem. Rev. 95, 735 (1995)

    Article  CAS  Google Scholar 

  6. A. Fujishima, T.-N. Rao, D.A. Tryk, J. Photochem. Photobiol. C 1, 1 (2000)

    Article  CAS  Google Scholar 

  7. H.-X. Li, Z.-F. Bian, J. Zhu, D.-Q. Zhang, G.-S. Li, Y.-N. Huo, H. Li, Y.-F. Lu, J. Am. Chem. Soc. 129, 8406 (2007)

    Article  CAS  Google Scholar 

  8. C.-Z. Wu, Y. Xie, L.-Y. Lei, S.-Q. Hu, C.-Z. OuYang, Adv. Mater. 18, 1727 (2006)

    Article  CAS  Google Scholar 

  9. X.-L. Hu, J.-C. Yu, J.-M. Gong, J. Phys. Chem. C 111, 11180 (2007)

    Article  CAS  Google Scholar 

  10. D. Zhang, L. Qi, J. Ma, H. Cheng, J. Mater. Chem. 12, 3677 (2002)

    Article  CAS  Google Scholar 

  11. K.D. Kim, S.H. Kim, H.T. Kim, Colloids Surf. A 254, 99 (2005)

    Article  CAS  Google Scholar 

  12. Q. Zhang, L. Gao, Langmuir 19, 967 (2003)

    Article  CAS  Google Scholar 

  13. Y.-X. Zhang, G.-H. Li, Y.-X. Jin, Y. Zhang, J. Zhang, L.-D. Zhang, Chem. Phys. Lett. 365, 300 (2002)

    Article  CAS  Google Scholar 

  14. J.-J. Wu, C.-C. Yu, J. Phys. Chem. B 108, 3377 (2004)

    Article  CAS  Google Scholar 

  15. S. Liu, K. Huang, Sol. Energy Mater. Sol. Cells 85, 125 (2004)

    CAS  Google Scholar 

  16. S.-M. Liu, L.-M. Gan, L.-H. Liu, W.-D. Zhang, H.-C. Zeng, Chem. Mater. 14, 1391 (2002)

    Article  CAS  Google Scholar 

  17. D. Gong, C.A. Grimes, O.K. Varghese, W. Hu, R. Singh, S.-Z. Chen, E.C. Dickey, J. Mater. Res. 16, 3331 (2001)

    Article  CAS  Google Scholar 

  18. T. Kasuga, M. Hiramatsu, A. Hoson, T. Sekino, K. Niihara, Langmuir 14, 3160 (1998)

    Article  CAS  Google Scholar 

  19. Y. Lin, G.-S. Wu, X.-Y. Yuan, T. Xie, L.-D. Zhang, J. Phys. Condens. Matter 15, 2917 (2003)

    Article  CAS  Google Scholar 

  20. A.R. Armstrong, G. Armstrong, J. Canales, R. García, P.G. Bruce, Adv. Mater. 7, 862 (2005)

    Article  Google Scholar 

  21. Z.-Y. Yuan, B.-L. Su, Colloids Surf. A 241, 173 (2004)

    Article  CAS  Google Scholar 

  22. D. Walsh, S. Mann, Nature 377, 320 (1995)

    Article  CAS  Google Scholar 

  23. C.-W. Guo, Y. Cao, S.-H. Xie, W.-L. Dai, K.-N. Fan, Chem. Commun. 700 (2003)

  24. H.-G. Yang, H.-C. Zeng, J. Phys. Chem. B 108, 3492 (2004)

    Article  CAS  Google Scholar 

  25. C.-W. Sun, J. Sun, G.-L. Xiao, H.-R. Zhang, X.-P. Qiu, H. Li, L.-Q. Chen, J. Phys. Chem. B 110, 13445 (2006)

    Article  CAS  Google Scholar 

  26. J.-G. Yu, H.-G. Yu, B. Cheng, X.-J. Zhao, J.-C. Yu, W.K. Ho, J. Phys. Chem. B 107, 13871 (2003)

    Article  CAS  Google Scholar 

  27. J.-G. Yu, Y.-R. Su, B. Cheng, Adv. Funct. Mater. 17, 1984 (2007)

    Article  CAS  Google Scholar 

  28. J.-A. Wang, R. Limas-Ballesteros, T. Lopez, A. Moreno, R. Gomez, O. Novaro, X. Bokhimi, J. Phys. Chem. B 105, 9692 (2001)

    Article  CAS  Google Scholar 

Download references

Acknowledgment

This work was supported by the Government (2007CG59), Shanghai Normal University (SK200723), and the State Key Laboratory Breeding Base of Photocatalysis of Fuzhou University (K-081019).

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to He-Xing Li.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Zhu, J., Wang, SH., Bian, ZF. et al. A facile synthesis of hierarchical flower-like TiO2 with enhanced photocatalytic activity. Res Chem Intermed 35, 769–777 (2009). https://doi.org/10.1007/s11164-009-0096-7

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11164-009-0096-7

Keywords

Navigation