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Roles of Mn in the High-Temperature Air Oxidation of 9Cr Ferritic–Martensitic Steel After Severe Plastic Deformation

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Abstract

Oxidation resistance of 9Cr ferritic–martensitic steel before and after cold-swaging process in air at 923 K was compared, and the oxide scales were characterized in detail by secondary ion mass spectrometry (SIMS). Both the cold-swaged sample and post-annealed samples showed considerably greater oxidation resistance than the initial as-tempered sample. Mn played a key role in scale formation of the cold-swaged sample and post-annealed sample; although the Mn content was only 0.5 wt% in the matrix, formation of Mn oxide (MnCr2O4 and Mn2O3) was favored. Roles of Mn in the oxidation behaviors of the cold-swaged sample and post-annealed sample were discussed.

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Authors and Affiliations

  1. Key Laboratory of Nuclear Materials and Safety Assessment, Institute of Metal Research, Chinese Academy of Sciences, 72 Wenhua Road, Shenyang, 110016, China

    Shenghu Chen & Lijian Rong

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  1. Shenghu Chen
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  2. Lijian Rong
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Correspondence to Shenghu Chen or Lijian Rong.

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Chen, S., Rong, L. Roles of Mn in the High-Temperature Air Oxidation of 9Cr Ferritic–Martensitic Steel After Severe Plastic Deformation. Oxid Met 89, 415–428 (2018). https://doi.org/10.1007/s11085-017-9796-3

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  • DOI: https://doi.org/10.1007/s11085-017-9796-3

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