Abstract
In this paper, we theoretically investigate intersubband absorption in La-doped BaSnO3/BaO perovskite-oxide double and triple symmetrical quantum wells. The goal is to assess the emerging possibilities offered by perovskite heterostructures for realization of oxide-based quantum well optoelectronic devices. Properties such as small electron effective mass, very high room-temperature mobility of BaSnO3, large conduction band offset between the two materials, are all promising for technological applications. Some of the possible applications include active n-channel materials in p-n junctions, field-effect transistors, ferroelectric field-effect transistors, sensitive UV photoconductors, and electron transport layers in perovskite solar cells. We are interested in tuning of the absorption spectra via quantum well width modulation, changing of doping density and variation of external electric field along the growth direction which is important for application in electro-optical light modulators. The electronic structure is calculated self-consistently by solving the Schrödinger–Poisson system of equations where the exchange correlation effects are also taken into the account.
Similar content being viewed by others
Data availability
Not applicable.
References
Ando, T., Taniyama, H., Ohtani, N., Nakayama, M., Hosoda, M.: Self-consistent calculation of subband occupation and electron–hole plasma effects: variational approach to quantum well states with Hartree and exchange-correlation interactions. J. Appl. Phys. 94, 4489–4501 (2003)
Barium Oxide, Electronic properties, (https://www.ucl.ac.uk/~ucapahh/research/crystal/bao.htm). Retrieved May 5, 2022.
Chin, V.W.L., Tansley, T.L., Osotchan, T.: Electron mobilities in gallium, indium, and aluminum nitrides. J. Appl. Phys. 75(11), 7365–7372 (1994)
Demkov, A.A., Posadas, A.B.: Integration of Functional Oxides with Semiconductors. Springer, New York (2014)
Guo, W.: Transition metal oxide thin films integration on SrTiO3, Dissertation (2021).
Jacoboni, C., Canali, C., Ottaviani, G., Quaranta, A.A.: A review of some charge transport properties of silicon. Solid State Electron. 20(2), 77–89 (1977)
Kang, J., Lee, J.H., Lee, H.K., Kim, K.T., Kim, J.H., Maeng, M.J., Hong, J.A., Park, Y., Kim, K.H.: Effect of threading dislocations on the electronic structure of La-doped BaSnO3 thin films. Mater. (basel). 15(7), 2417 (2022)
Khan, A.I., Chatterjee, K., Wang, B., Drapcho, S., You, L., Serrao, C., Bakaul, S.R., Ramesh, R., Salahuddin, S.: Negative capacitance in a ferroelectric capacitor. Nat. Mater. 14, 182–186 (2014)
Kim, H.J., et al.: High mobility in a stable transparent perovskite oxide. Appl. Phys. Express 5, 061102 (2012a)
Kim, H.J., et al.: Physical properties of transparent perovskite oxide (Ba, La)SnO3 with high electrical mobility at room temperature. Phys. Rev. B 86, 165205 (2012b)
Kumah, D.P., Ngai, J.H., Kornblum, L.: Epitaxial oxides on semiconductors: from fundamentals to new devices. Adv. Funct. Mater. 30, 1901597 (2020)
Laurent Nevou.: Q_SchrodingerPoisson1D_CB, (https://github.com/LaurentNevou/Q_SchrodingerPoisson1D_CB), GitHub. Retrieved March 18 (2022a)
Lee, J.H., Lee, W.-J., Kim, T.H., Lee, T., Hong, S., Kim, K.H.: Transparent p-CuI/n-BaSnO3-δ heterojunctions with a high rectification ratio. J. Phys. Condens. Matter. 29, 384004 (2017)
Lee, Y., Yoon, D., Yu, S., Sim, H., Park, Y., Nam, Y.-S., Kim, K.-J., Choi, S.-Y., Kang, Y., Son, J.: Reversible manipulation of photoconductivity caused by surface oxygen vacancies in perovskite stannates with ultraviolet light. Adv. Mater. 34, 2107650 (2021)
Li, W., Hamze, A.K., Demkov, A.A.: Tunable giant nonlinear optical susceptibility in BaSnO3 quantum wells. Phys. Rev. B 104, 235419 (2021)
Luttinger, J.M., Kohn, W.: Motion of electrons and holes in perturbed periodic fields. Phys. Rev. 97, 869 (1955)
Ma, T.P., Han, J.-P.: Why is nonvolatile ferroelectric memory field-effect transistor still elusive? IEEE Electron. Device Lett. 23, 386–388 (2002)
McKee, R.A., Walker, F.J., Chisholm, M.F.: Crystalline oxides on silicon: the first five monolayers. Phys. Rev. Lett. 81, 3014 (1998)
McKee, R.A., Walker, F.J., Chisholm, M.F.: Physical structure and inversion charge at a semiconductor interface with a crystalline oxide. Science 293, 468–471 (2001)
Medvedeva, J.E.: Averaging of the electron effective mass in multicomponent transparent conducting oxides. EPL 78, 57004 (2007)
Miller, S.L., McWhorter, P.J.: Physics of the ferroelectric nonvolatile memory field effect transistor. J. Appl. Phys. 72, 5999–6010 (1992)
Paik, H., Chen, Z., Lochocki, E., et al.: Adsorption-controlled growth of La-doped BaSnO3 by molecular-beam epitaxy. APL Mater. 5, 116107 (2017)
Park, C., Kim, U., Ju, C.J., Park, J.S., Kim, Y.M., Char, K.: High mobility field effect transistor based on BaSnO3 with Al2O3 gate oxide. Appl. Phys. Lett. 105, 203503 (2014)
Shin, S.S., Yeom, E.J., Yang, W.S., Hur, S., Kim, M.G., Im, J., Seo, J., Noh, J.H., Seok, S.I.: Colloidally prepared La-doped BaSnO3 electrodes for efficient, photostable perovskite solar cells. Science 356, 167–171 (2017)
The Materials Project, BaSnO3 mp-3163 (https://materialsproject.org/materials/mp-3163). Retrieved May 5, 2022.
Funding
This work was supported by Ministry of Education, Science and Technological Development (Republic of Serbia).
Author information
Authors and Affiliations
Contributions
All authors contributed to the study conception and design. Material preparation, data collection and analysis were performed by all authors. The first draft of the manuscript was written by Novak Stanojević and all the authors contributed in finalizing the previous versions of the manuscript. All authors have read and approved the submitted version of the manuscript.
Corresponding author
Ethics declarations
Conflict of interest
The authors have no relevant financial or non-financial interests to disclose.
Ethical approval
Not applicable.
Additional information
Publisher's Note
Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.
Rights and permissions
Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.
About this article
Cite this article
Stanojević, N., Vuković, N. & Radovanović, J. Calculation of intersubband absorption in n-doped BaSnO3 quantum wells. Opt Quant Electron 55, 383 (2023). https://doi.org/10.1007/s11082-023-04656-5
Received:
Accepted:
Published:
DOI: https://doi.org/10.1007/s11082-023-04656-5