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Chiral effects in low-cost plasmonic arrays of elliptic nanoholes

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Abstract

In this work we present an approach to induce chiral effects in well-known plasmonic nanohole arrays with triangular unit cell. Arrays with circular nanoholes in metals can exhibit interesting light-matter interaction mechanisms such as surface plasmon polaritons and extraordinary optical transmission. Moving from circular to elliptical shape and tilting the ellipse away from the lattice symmetry lines, a symmetry breaking induces a different absorption of the circularly polarized light of opposite handedness, i.e. circular dichroism. We numerically investigate circular dichroism at normal incidence in elliptic nanoholes in Au in the spectral range 400–1000 nm. We focus on its dependence on the elliptic nanohole tilt, and further proceed with the ellipse radii optimization. The optimized circular dichroism reaches 84%, and we report on the near field absorption distribution at the wavelengths of this maximum value.

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References

  • Alizadeh, M.H., Reinhard, B.M.: Plasmonically enhanced chiral optical fields and forces in achiral split ring resonators. ACS Photonics 2, 361–368 (2015)

    Article  Google Scholar 

  • Barnes, W.L., Dereux, A., Ebbesen, T.W.: Surface plasmon subwavelength optics. Nature 424, 824–830 (2003)

    Article  ADS  Google Scholar 

  • Belardini, A., Larciprete, M.C., Centini, M., Fazio, E., Sibilia, C., Chiappe, D., Martella, C., Toma, A., Giordano, M., Buatier de Mongeot, F.: Circular dichroism in the optical second-harmonic emission of curved gold metal nanowires. Phys. Rev. Lett. 107, 257401 (2011)

    Article  ADS  Google Scholar 

  • Belardini, A., Centini, M., Leahu, G., Fazio, E., Sibilia, C., Haus, J.W., Sarangan, A.: Second harmonic generation on self-assembled tilted gold nanowires. Faraday Discuss. 178, 357–362 (2015)

    Article  ADS  Google Scholar 

  • Belardini, A., Centini, M., Leahu, G., Hooper, D.C., Li Voti, R., Fazio, E., Haus, J.W., Sarangan, A., Valev, V.K., Sibilia, C.: Chiral light intrinsically couples to extrinsic/pseudo-chiral metasurfaces made of tilted gold nanowires. Sci. Rep. 6, 31796 (2016)

    Article  ADS  Google Scholar 

  • Bertolotti, M., Belardini, A., Benedetti, A., Sibilia, C.: Second harmonic circular dichroism by self-assembled metasurfaces. J. Opt. Soc. Am. B 32, 1287–1293 (2015)

    Article  ADS  Google Scholar 

  • Blanchard-Dionne, A., Meunier, M.: Sensing with periodic nanohole arrays. Adv. Opt. Photonics 9, 891–940 (2017)

    Article  ADS  Google Scholar 

  • Cesca, T., Michieli, N., Kalinic, B., Sánchez-Espinoza, A., Rattin, M., Russo, V., Mattarello, V., Scian, C., Mazzoldi, P., Mattei, G.: Nonlinear absorption tuning by composition control in bimetallic plasmonic nanoprism arrays. Nanoscale 7, 12411–12418 (2015)

    Article  ADS  Google Scholar 

  • Coolins, J.T., Kuppe, C., Hooper, D.C., Sibilia, C., Centini, M., Valev, V.K.: Chirality and chiroptical effects in metal nanostructures: fundamentals and current trends. Adv. Opt. Mater. 5, 1700182 (2017)

    Article  Google Scholar 

  • Couture, M., Liang, Y., Poirier Richard, H.-P., Faid, R., Peng, W., Masson, J.-F.: Tuning the 3D plasmon field of nanohole arrays. Nanoscale 5, 12399–12408 (2013)

    Article  ADS  Google Scholar 

  • Ebbesen, T.W., Lezec, H.J., Ghaemi, H.F., Thio, T., Wolff, P.A.: Extraordinary optical transmission through sub-wavelength hole arrays. Nature 391, 667–669 (1998)

    Article  ADS  Google Scholar 

  • García de Abajo, F.J.: Colloquium: light scattering by particle and hole arrays. Rev. Mod. Phys. 79, 1267–1290 (2007)

    Article  ADS  Google Scholar 

  • Giudicatti, S., Marabelli, F., Valsesia, A., Pellacani, P., Colpo, P., Rossi, F.: Interaction among plasmonic resonances in a gold film embedding a two-dimensional array of polymeric nanopillars. J. Opt. Soc. Am. B 29, 1641–1647 (2012)

    Article  ADS  Google Scholar 

  • Hakkarainen, T., Petronijevic, E., Rizzo Piton, M., Sibilia, C.: Demonstration of extrinsic chirality of photoluminescence with semiconductor-metal hybrid nanowires. Sci. Rep. 9, 5040 (2019)

    Article  ADS  Google Scholar 

  • Hendry, E., Carpy, T., Johnston, J., Popland, M., Mikhaylovskiy, R.V., Lapthorn, A.J., Kelly, S.M., Barron, L.D., Gadegaard, N., Kadodwala, M.: Ultrasensitive detection and characterization of biomolecules using superchiral fields. Nat. Nanotechnol. 5, 783–787 (2010)

    Article  ADS  Google Scholar 

  • Hendry, E., Mikhaylovskiy, R.V., Barron, L.D., Kadodwala, M., Davis, T.J.: Chiral electromagnetic fields generated by arrays of nanoslits. Nano Lett. 12, 3640–3644 (2012)

    Article  ADS  Google Scholar 

  • Hutt, A.J., Tan, S.C.: Drug chirality and its clinical significance. Drugs 52, 1–12 (1996)

    Article  Google Scholar 

  • Leahu, G., Petronijevic, E., Belardini, A., Centini, M., Sibilia, C., Hakkarainen, T., Koivusalo, E., Rizzo Piton, M., Suomalainen, S., Guina, M.: Evidence of optical circular dichroism in GaAs-based nanowires partially covered with gold. Adv. Opt. Mater. 5, 1601063 (2017)

    Article  Google Scholar 

  • Li, Z., Liu, C., Rong, X., Luo, Y., Cheng, H., Zheng, L., Lin, F., Shen, B., Gong, Y., Zhang, S., Fang, Z.: Tailoring MoS2 valley-polarized photoluminescence with super chiral near-field. Adv. Mater. 30, 18019081 (2018)

    Google Scholar 

  • Liu, H., Lalanne, Ph: Comprehensive microscopic model of the extraordinary optical transmission. Nature 452, 728–731 (2008)

    Article  ADS  Google Scholar 

  • Lumerical Solutions, Inc. http://www.lumerical.com/tcad-products/fdtd/

  • Maier, S.A.: Plasmonics: Fundamentals and Applications. Springer, Berlin (2007)

    Book  Google Scholar 

  • Maoz, B.M., Ben Moshe, A., Vestler, D., Bar-Elli, O., Markovich, G.: Chiroptical effects in planar achiral plasmonic oriented nanohole arrays. Nano Lett. 12, 2357–2361 (2012)

    Article  ADS  Google Scholar 

  • Michieli, N., Kalinic, B., Scian, C., Cesca, T., Mattei, G.: Emission rate modification and quantum efficiency enhancement of Er3 + emitters by near-field coupling with nanohole arrays. ACS Photonics 5, 2189–2199 (2018)

    Article  Google Scholar 

  • Nguyen, L.A., He, H., Pham-Huy, C.: Chiral drugs: an overview. Adv. Nat. Sci. Nanosci. Nanotechnol. 2, 85–100 (2006)

    Google Scholar 

  • Petronijevic, E., Centini, M., Belardini, A., Leahu, G., Hakkarainen, T., Sibilia, C.: Chiral near-field manipulation in Au–GaAs hybrid hexagonal nanowires. Opt. Express 25, 14148–14157 (2017a)

    Article  ADS  Google Scholar 

  • Petronijevic, E., Leahu, G., Mussi, V., Sibilia, C., Bovino, F.A.: Photoacoustic technique for the characterization of plasmonic properties of 2D periodic arrays of gold nanoholes. AIP Adv. 7, 025210 (2017b)

    Article  ADS  Google Scholar 

  • Petronijevic, E., Leahu, G., Belardini, A., Centini, M., Li Voti, R., Hakkarainen, T., Koivusalo, E., Rizzo Piton, M., Suomalainen, S., Guina, M., Sibilia, C.: Photo-acoustic spectroscopy reveals extrinsic optical chirality in GaAs-based nanowires partially covered with gold. Int. J. Thermophys. 39, 46 (2018a)

    Article  ADS  Google Scholar 

  • Petronijevic, E., Leahu, G., Belardini, A., Centini, M., Li Voti, R., Hakkarainen, T., Koivusalo, E., Rizzo Piton, M., Suomalainen, S., Guina, M., Sibilia, C.: Resonant absorption in GaAs-based nanowires by means of photo-acoustic spectroscopy. Int. J. Thermophys. 39, 45 (2018b)

    Article  ADS  Google Scholar 

  • Petronijevic, E., Sibilia, C.: Enhanced near-field chirality in periodic arrays of Si nanowires for chiral sensing. Molecules 24, 853 (2019)

    Article  Google Scholar 

  • Petronijevic, E., Sandoval, E.M., Ramezani, M., Ordóňez-Romero, C.L., Noguez, C., Bovino, F.A., Sibilia, C., Pirruccio, G.: Extended chiro-optical near-field response of achiral plasmonic lattices. J. Phys. Chem. C 123(38), 23620–23627 (2019a)

    Article  Google Scholar 

  • Petronijevic, E., Leahu, G., Li Voti, R., Belardini, A., Scian, C., Michieli, N., Cesca, T., Mattei, G., Sibilia, C.: Photo-acoustic detection of chirality in metal-polystyrene metasurfaces. Appl. Phys. Lett. 114, 053101 (2019b)

    Article  ADS  Google Scholar 

  • Ruan, Z., Qiu, M.: Enhanced transmission through periodic arrays of subwavelength holes: the role of localized waveguide resonances. Phys. Rev. Lett. 96, 233901 (2006)

    Article  ADS  Google Scholar 

  • Russo, V., Michieli, N., Cesca, T., Scian, C., Silvestri, D., Morpurgo, M., Mattei, G.: Gold–silver alloy semi-nanoshell arrays for label-free plasmonic biosensors. Nanoscale 9, 10117–10125 (2017)

    Article  Google Scholar 

  • Salomon, L., Grillot, F., Zayats, A.V., de Fornel, F.: Near-field distribution of optical transmission of periodic subwavelength holes in a metal film. Phys. Rev. Lett. 86, 1110–1113 (2001)

    Article  ADS  Google Scholar 

  • Sanchez-Esquivel, H., Raygoza-Sanchez, K.Y., Rangel-Rojo, R., Gemo, E., Michieli, N., Kalinic, B., Reyes-Esqueda, J.A., Cesca, T., Mattei, G.: Spectral dependence of nonlinear absorption in ordered silver metallic nanoprism arrays. Sci. Rep. 7, 5307 (2017)

    Article  ADS  Google Scholar 

  • Schäferling, M., Dregely, D., Hentschel, M., Giessen, H.: Tailoring enhanced optical chirality: design principles for chiral plasmonic nanostructures. Phys. Rev. X 2, 031010 (2012a)

    Google Scholar 

  • Schäferling, M., Yin, X., Giessen, H.: Formation of chiral fields in a symmetric environment. Opt. Express 20, 26326–26336 (2012b)

    Article  ADS  Google Scholar 

  • Tang, Y., Cohen, A.E.: Enhanced enantioselectivity in excitation of chiral molecules by superchiral light. Science 332(6027), 333–336 (2011)

    Article  ADS  Google Scholar 

  • Vázquez-Guardado, A., Chanda, D.: Superchiral light generation on degenerate achiral surfaces. Phys. Rev. Lett. 120, 137601 (2018)

    Article  ADS  Google Scholar 

  • Wang, Z., Cheng, F., Winsor, T., Liu, T.: Optical chiral metamaterials: a review of the fundamentals, fabrication methods and applications. Nanotechnology 27, 412001 (2016)

    Article  Google Scholar 

  • Xu, J., Guan, P., Kvasnička, P., Gong, H., Homola, J., Yu, Q.: Light transmission and surface-enhanced Raman scattering of quasi-3D plasmonic nanostructure arrays with deep and shallow Fabry-Pérot nanocavities. J. Phys. Chem. C 115, 10996–11002 (2011)

    Article  Google Scholar 

  • Zhao, Y., Askarpour, A.N., Sun, L., Shi, J., Li, X., Alù, A.: Chirality detection of enantiomers using twisted optical metamaterials. Nat. Commun. 8, 14180 (2017)

    Article  ADS  Google Scholar 

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Acknowledgements

We kindly acknowledge Optical Society of America for the financial support of Nikola Zaric. We are grateful to Franco Marabelli for useful suggestions.

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Correspondence to E. Petronijevic.

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This article is part of the Topical Collection on Advanced Photonics Meets Machine Learning.

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Petronijevic, E., Ali, H., Zaric, N. et al. Chiral effects in low-cost plasmonic arrays of elliptic nanoholes. Opt Quant Electron 52, 176 (2020). https://doi.org/10.1007/s11082-020-02279-8

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