Abstract
Quasi solid state dye-sensitized solar cells (DSSCs) have been fabricated with electrolytes containing \(\text{ I }^{-}/\text{ I }_{3}^{-}\) redox couple using 80 % hydrolyzed polyvinyl alcohol (PVA) doped with potassium iodide (KI) and a mixture of potassium iodide and tetrapropyl ammonium iodide (\(\text{ Pr }_{4}\text{ NI }\)) salts. The quasi solid state gel polymer electrolytes were prepared using 1:1 ethylene carbonate (EC):propylene carbonate (PC) mixture. The solar cells have the structure of ITO/\(\text{ TiO }_{2}\)/N3-Dye/electrolyte/Pt/ITO. The conductivity of the electrolytes has been calculated from the bulk resistance value determined using the electrochemical impedance spectroscopy. The performance of the DSSCs has been studied by varying the concentration of the doping salts in the electrolyte and incident light intensity. The DSSC fabricated with the KI salt electrolyte containing 9.9 wt% PVA, 39.6 wt% EC, 39.6 wt% PC, 10.9 wt% KI\((+\text{ I }_{2})\) exhibited the best power conversion efficiency of 1.97 %. However, the DSSC with a double-salt electrolyte containing 9.9 wt% PVA: 39.6 wt% EC: 39.6 wt% PC: (6.5 wt% KI: 4.4 wt% \(\text{ Pr }_{4}\text{ NI }\)) (\(+\text{ I }_{2}\)) exhibited a higher efficiency of 3.27% under \(100 \text{ mW/cm }^{2}\) light intensity. The efficiency of this cell increased to 4.59 % under dimmer light of intensity of \(54 \text{ mW/cm }^{2}\).
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Agarwala, S., Thummalakunta, L.N.S.A., Cook, C.A., Peh, C.K.N., Wong, A.S.W., Ke, L., Ho, G.W.: Co-existence of LiI and KI in filler-free, quasi-solid-state electrolyte for efficient and stable dye-sensitized solar cell. J. Power Sourc. 196, 1651–1656 (2011a)
Agarwala, S., Peh, C.K.N., Ho, G.W.: Highly stable quasi-solid state dye sensitized solar cell: improved performance using diphenylamine in filler free KI and LiI electrolyte. Appl. Mater. Interface 3, 2383–2391 (2011b)
Bandara, T.M.W.J., Mellander, B.-E.: Evaluation of mobility, diffusion coefficient and density of charge carriers in ionic liquids and novel electrolytes based on a new model for dielectric response. In: Kokorin, Alexander (ed.) Ionic Liquids: Theory, Properties, New Approaches, pp. 383–406. InTech Janeza Trdine, Crotia (2011)
Bandara, T.M.W.J., Dissanayake, M.A.K.L., Jayasundara, W.J.M.J.S.R., Albinsson, I., Mellander, B.-E.: Efficiency enhancement in dye sensitized solar cells using gel polymer electrolytes based on a tetrahexylammonium iodide and \(\text{ MgI }_{2}\) binary iodide system. Phys. Chem. Chem. Phys. 14, 8620–8627 (2012)
Chiba, Y., Islam, A., Watanabe, Y., Komiya, R., Koide, N., Han, L.: Dye-sensitized solar cells with conversion efficiency of 11.1%. Jpn. J. Appl. Phys. 45, L638–L640 (2006)
Cui, Y., Zhang, J., Zhang, X., Feng, J., Hong, Y., Zhu, Y.: High performance quasi-solid-state dye-sensitized solar cells based on acetamide-modified polymer electrolytes. Org. Electron. 13, 2561–2567 (2012)
Dissanayake, M.A.K.L., Thotawatthage, C.A., Senadeera, Bandara, T.M.W.J., Jayasundera, W.J.M.J.S.R., Mellander, B.-E.J.: Efficiency enhancement by mixed cation effect in dye-sensitized solar cells with PAN based gel polymer electrolyte. Photochem. Photobiol. A Chem. 246, 29–35 (2012)
Grätzel, M.: Dye-sensitized solar cells. J. Photochem. Photobiol. C Photochem. Rev. 4, 145–153 (2003)
Ileperuma, O.A., Kumara, G.R.A., Yang, H.-S., Murakami, K.: Quasi-solid electrolyte based on polyacrylonitrile for dye-sensitized solar cells. J. Photochem. Photobiol. A Chem. 217, 308–312 (2011)
Jeonga, W.-S., Lee, J.-W., Jung, S., Yun, J.H., Parka, N.-G.: Evaluation of external quantum efficiency of a 12.35% tandem solar cell comprising dye-sensitized and CIGS solar cells. Solar Energy Mater. Solar Cell. 95, 3419–3423 (2011)
Jia, Y.-T., Gong, J., Gu, X.-H., Kim, H.-Y., Dong, J., Shen, X.-Y.: Fabrication and characterization of poly (vinyl alcohol)/chitosan blend nanofibers produced by electrospinning method. Carbohydr. Polym. 67, 403–409 (2007)
Kelly, C.A., Farzad, F., Thompson, D.W., Stipkala, J.M., Meyer, G.J.: Cation controlled interfacial charge separation in sensitized nanocrystalline \(\text{ TiO }_{2}\) photoanodes. Langmuir 15, 7047–7054 (1999)
Kusama, H., Arakawa, H.: Influence of alkylaminopyridine additives in electrolytes on dye-sensitized solar cell performance. Sol. Energy Mater. Sol. Cells. 81, 87–99 (2004a)
Kusama, H., Arakawa, H.: Influence of aminotriazole additives in electrolytic solution on dye-sensitized solar cell performance. J. Photochem. Photobiol. A Chem. 164, 103–110 (2004b)
Lan, Z., Wu, J., Wang, D., Hao, S., Lin, J., Huang, Y.: Quasi-solid state dye-sensitized solar cells based on gel polymer electrolyte with poly(acrylonitrile-co-styrene)/NaI+I2 sol. Solar Energy 80, 1483–1488 (2006)
Lan, Z., Wu, J., Lin, J., Huang, M., Li, P., Li, Q.: Influence of ionic additives NaI/I2 on the properties of polymer gel electrolyte and performance of quasi-solid-state dye-sensitized solar cells. Electrochim. Acta 53, 2296–2301 (2008)
Lee, K.-M., Wu, S.-J., Chen, C.-Y., Wu, C.-G., Ikegami, M., Miyoshi, K., Miyasaka, T., Ho, K.-C.: Efficient and stable plastic dye-sensitized solar cells based on a high light-harvesting ruthenium sensitizer. J. Mater. Chem. 19, 5009–5015 (2009)
Nazeeruddin, M.K., Kay, A., Rodicio, I., Humphry-Baker, R., Muller, E., Liska, P., Vlachopoulos, N., Grätzel, M.: Conversion of light to electricity by \(\text{ cis-X }_{2}\)Bis(2,2’-bipyridyl-4,4’-dicarboxylate)ruthenium(II) charge-transfer sensitizers (X = C1-, Br-, I-, CN-, and SCN-) on nanocrystalline \(\text{ TiO }_{2}\) electrodes. J. Am. Chem. Soc. 115, 6382–6390 (1993)
Nazeeruddin, M.K., Pechy, P., Grätzel, M.: Engineering of efficient panchromatic sensitizers for nanocrystalline \(\text{ TiO }_{2}\)-based solar cells. J. Am. Chem. Soc. 123, 1613–1624 (2001)
O’ Regan, B., Grätzel, M.: A low-cost, high-efficiency solar cell based on dye-sensitized colloidal \(\text{ TiO }_{2}\) films. Nature 353, 737–740 (1991)
Oskam, G., Bergeron, B.V., Meyer, G.J., Searson, P.C.: Pseudohalogens for dye-sensitized \(\text{ TiO }_{2}\) photoelectrochemical cells. J. Phys. Chem. B 105, 6867–6873 (2001)
Osman, Z., Ibrahim, Z.A., Arof, A.K.: Conductivity enhancement due to ion dissociation in plasticized chitosan based polymer electrolytes. Carbohydr. Polym. 44, 167–173 (2001)
Pelet, S., Moser, J.E., Gratzel, M.: Cooperative effect of adsorbed cations and iodide on the interception of back electron transfer in the dye sensitization of nanocrystalline \(\text{ TiO }_{2}\). J. Phys. Chem. B 104, 1791–1795 (2000)
Santa-Nokki, H., Busi, S., Kallioinen, J., Lahtinen, M., Korppi-Tommola, J.: Quaternary ammonium polyiodides as ionic liquid/soft solid electrolytes in dye-sensitized solar cells. J. Photochem. Photobiol. A Chem. 186, 29–33 (2007)
Sapp, S.A., Elliott, C.M., Contado, C., Caramori, S., Bignozzi, C.A.: Substituted polypyridine complexes of cobalt(II/III) as efficient electron-transfer mediators in dye-sensitized solar cells. J. Am. Chem. Soc. 37, 11215–11222 (2002)
Wang, P., Zakeeruddin, M.Z., Moser, J.E., Nazeeruddin, M.K., Sekiguchi, T., Gratzel, M.: A stable quasi-solid-state dye-sensitized solar cell with an amphiphilic ruthenium sensitizer and polymer gel electrolyte. Nat. Mater. 2, 402–407 (2003)
Wu, J., Lan, Z., Wang, D., Hao, S., Lin, J., Wei, Y., Yin, S., Sato, T.: Quasi-solid state dye-sensitized solar cells-based gel polymer electrolytes with poly(acrylamide)–poly(ethylene glycol) composite. J. Photochem. Photobiol. A Chem. 181, 333–337 (2006)
Wu, J., Lan, Z., Wang, D., Hao, S., Lin, J., Huang, Y., Yin, S., Sato, T.: Gel polymer electrolyte based on poly(acrylonitrile-co-styrene) and a novel organic iodide salt for quasi-solid state dye-sensitized solar cell. Electrochim. Acta 51, 4243–4249 (2006)
Xiang, W., Fang, Y., Lin, Y., Fang, S.: Polymer-metal complex as gel electrolyte for quasi-solid-state dye-sensitized solar cells. Electrochim. Acta 56, 1605–1610 (2011)
Yang, C.-C., Wu, G.M.: Study of microporous PVA/PVC composite polymer membrane and it application to \(\text{ MnO }_{2}\) capacitors. Mater. Chem. Phys. 114, 948–955 (2009)
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The Authors thank University of Malaya for the AFR Program grant No. RP003D-13AFR.
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Arof, A.K., Naeem, M., Hameed, F. et al. Quasi solid state dye-sensitized solar cells based on polyvinyl alcohol (PVA) electrolytes containing \(\mathbf{I}^{\mathbf{-}}/\mathbf{I}_{\mathbf{3}}^{\mathbf{-}}\) redox couple. Opt Quant Electron 46, 143–154 (2014). https://doi.org/10.1007/s11082-013-9723-z
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DOI: https://doi.org/10.1007/s11082-013-9723-z