Abstract
Metal oxide nanoparticles are small but easily form agglomerates in suspension, depending on the strength of particle–particle and particle–media interactions. To understand the agglomeration behavior of nanoparticles in media and relate to it to product performance testing, measurement methods are desired to characterize highly scattering metal oxide nanoparticle suspensions without dilution. In this article, we describe the advantages of using photocorrelation spectroscopy (PCS) in a backscattering detection configuration to carry out a realistic agglomerate size measurement in multiple scattering media found in most metal oxide nanoparticle suspensions. The dynamic behavior of nano-titanium dioxide (TiO2) particles in buffer solutions of different chemical composition and pH values was investigated as a sample system using PCS. The resulting autocorrelation functions (AFs) at different time intervals, particle concentrations, and pH values were measured at several detection angles. The AF exhibits a multi-mode relaxation time feature and the calculated hydrodynamic diameters strongly depended on media composition and detection angle. This result indicates that the size and dispersion of nano-TiO2 agglomerates are significantly affected by solution media. A measurement protocol for determining size and dispersion of metal oxide particles in media is proposed and related to a performance test found in industry.
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Allen NS, Edge M, Corrales T, Childs A, Liauw CM, Catalina F, Peinado C, Minihan A, Aldcroft D (1998) Ageing and stabilisation of filled polymers: an overview. Polym Degrad Stab 61:183–199
Ammala A, Hill AJ, Meakin P, Pas SJ, Turney TW (2002) Degradation studies of polyolefins incorporating transparent nanoparticulate zinc oxide UV stabilizers. J Nanopart Res 4:167–174
Badaire S, Poulin P, Maugey M, Zakri C (2004) In situ measurements of nanotube dimensions in suspensions by depolarized dynamic light scattering. Langmuir 20:10367–10370
Baer DR, Gaspar DJ, Nachimuthu P, Techane SD, Castner DG (2010) Application of surface chemical analysis tools for characterization of nanoparticles. Anal Bioanal Chem 396:983–1002
Brant J, Lecoanet H, Wiesner MR (2005) Aggregation and deposition characteristics of fullerene nanoparticles in aqueous systems. J Nanopart Res 7:545–553
Brundle CR, Evans CA Jr, Wilson S (1992) Encyclopedia of materials characterization. Butterworth-Heinemann, Boston
Chu B, Liu T (2000) Characterization of nanoparticles by scattering technique. J Nanopart Res 2:29–41
Colomer MT, Guzman J, Moreno R (2008) Determination of peptization time of particulate sols using optical techniques: Titania as a case study. Chem Mater 20:4161–4165
Das P, Mallick A, Sarkar D, Chattopadhyay N (2008) Probe-induced self-aggregation of gamma-cyclodextrin: Formation of extended nanotubular suprastructure. J Phys Chem C 112(26):9600–9603
Frisken B (2001) Revisiting the method of cumulants for the analysis of dynamic light-scattering data. Appl Opt 40:4087–4091
Georgalis Y, Starikov EB, Hollenbach B, Lurz R, Scherzinger E, Saenger W, Lehrach H, Wanker EE (1998) Huntingtin aggregation monitored by dynamic light scattering. Proc Natl Acad Sci 95:6118–6121
Gradzielski M (2008) Recent developments in the characterisation of microemulsions. Curr Opin Colloid Interface Sci 13:263–269
Holmqvist P, Nägele G (2010) Long-time dynamics of concentrated charge-stabilized colloids. Phys Rev Lett 104:0583011–0583014
Kaszuba M, Connah MT (2006) Protein and nanoparticle characterisation using light scattering techniques. Part Part Syst Charact 23:193–196
Kaszuba M, Connah MT, McNeil-Watson FK, Nobbmann U (2007) Resolving concentrated particle size mixtures using dynamic light scattering. Part Part Syst Charact 24:159–162
Kaszuba M, McKnight D, Connah MT, McNeil-Watson FK, Nobbmann U (2008) Measuring sub nanometre sizes using dynamic light scattering. J Nanopart Res 10:823–829
Ozon F, Petekidis G, Vlassopoulos D (2006) Signatures of nonergodicity transition in a soft colloidal system. Ing Eng Chem Res 45:6946–6952
Rodriguez-Maldonado L, Fernandez-Nieves A, Fernandez-Barbero A (2005) Dynamic light scattering from high molecular weight poly-l-lysine molecules. Colloids Surf A 207–271:335–339
Ross S, Morrison ID (1988) Size and surface area. In: Colloidal systems and interfaces. Wiley, New York, pp 31–54
Susoff M, Winter D, Eisenbach CD, Oppermann W (2008) J Phys Chem B 112:4519–4525
Tanguchi J, Murata H, Okamura Y (2010) Analysis of aggregation and dispersion states of small particles in concentrated suspensions by using diffused photon density wave spectroscopy. Colloids Surf B 76:137–144
Turton TJ, White JR (2001) Effect of stabilizer and pigment on photo-degradation depth profiles in polypropylene. Polym Degrad Stab 74:559–568
Watson S, Forester A, Tseng IH, Sung L (2008) Assessment of spectrophotometric assay methods on nanostructured pigments. In: Fernando RH, Sung LP (eds) ACS symposium series book on nanotechnology applications in coatings. Oxford University Press, Oxford
Witten KG, Bretschneider JC, Eckert T, Richtering W, Simon U (2008) Assembly of DNA-functionalized gold nanoparticles studied by UV/Vis-spectroscopy and dynamic light scattering. Phys Chem Chem Phys 10:1870–1875
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Tseng, IH., Watson, S.S. & Sung, LP. Characterizing the dynamic behavior of nano-TiO2 agglomerates in suspensions by photocorrelation spectroscopy. J Nanopart Res 13, 2195–2204 (2011). https://doi.org/10.1007/s11051-010-9977-3
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DOI: https://doi.org/10.1007/s11051-010-9977-3