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Electrodeposition of different types of tungsten cathode deposits from ionic melts

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Materials Science Aims and scope

A review of experimental investigations of electrochemical deposition of tungsten from ionic melts is presented. The electrolytes used are systematized depending on the structure of deposits.

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References

  1. S. P. Antonov, L. E. Ivanovskiii, and S. S. Petenev, “Deposition of coatings of refractory metals by electrolysis of molten salts,” Zashch. Met., 9, 567–571 (1973).

    CAS  Google Scholar 

  2. A. N. Baraboshkin, Electrocrystallization of Metals from Molten Salts [in Russian], Nauka, Moscow (1976).

    Google Scholar 

  3. V. V. Malyshev, High-Temperature Electrochemistry and Electrodeposition of Metals of Groups IV–VIA and Their Compounds in Ionic Melts [in Ukrainian], VMURoL “Ukraina,” Kyiv (2004).

  4. J. A. van Liempt, “Electrodeposition of tungsten from fused salts,” Electrochem. Angew, Phys. Chem., 31, 249–256 (1925).

    Google Scholar 

  5. L. N. Zavorokhin, Electrodeposition of Tungsten from Tungstate Melts [in Russian], Author’s Thesis of the Candidate-Degree Thesis (Chemical Sciences) [in Russian], Sverdlovsk (1977).

  6. S. V. Plaksin and A. N. Baraboshkin, “Electrodeposition of single-crystal tungsten deposits from tungstate melts,” in: Electrode Processes in Halogenide and Oxide Electrolytes [in Russian], Ural Scientific Center, Sverdlovsk (1981), pp. 22–26.

  7. A. N. Baraboshkin, K. P. Tarasova, and V. A. Nazarov, “Study of the composition and structure of cathodic deposits in electrolysis of Na2WO4−WO3 molten mixtures,” Tr. Inst. Élektrokhim. UNTs Akad. Nauk SSSR, Issue 19, 44–47 (1973).

    Google Scholar 

  8. K. P. Tarasova, and V. A. Nazarov, and N. O. Esina, “Composition and structure of cathodic deposits in electrolysis of tungstate salts,” Tr. Inst. Élektrokhim. UNTs Akad. Nauk SSSR, Issue 21, 61–65 (1974).

    Google Scholar 

  9. V. R. Raksha, K. A. Kaliev, and R. K. Shurdumov, “Study of cathodic products of electrolysis of tungstate–metaphosphate melts,” in: High-Temperature Physical Chemistry and Electrochemistry [in Russian], Issue 27, Ural Scientific Center, Sverdlovsk (1981), pp. 112–116.

  10. F. I. Kukoz, V. I. Goncharov, and M. Yu. Asfatsadur’yan, “Electrodeposition of lithium–tungsten bronzes from a chloride–tungstate melt,” in: Proc. of the 3rd Ural Conf. “High-Temperature Physical Chemistry and Electrochemistry [in Russian], Sverdlovsk (1981), pp. 95–96.

  11. A. N. Baraboshkin, K. A. Kaliev, and S. M. Zakhar’yash, “Study of cathodic products of electrolysis of tungstate melts,” Khim. Tekhnol. Molibd. Vol’fr., Issue 4, 130–132 (1973).

  12. C. V. Collins and W. Ostertag, “Single crystal preparation of cubic rare-earth tungsten bronzes,” J. Amer. Chem. Soc., 83, 3171–3176 (1966).

    Article  Google Scholar 

  13. A. N. Baraboshkin, A. B. Filosovova, and N. A. Saltykova, “Electrodeposition of dendrite tungsten deposits from tungstate melts,” Tr. Inst. Élektrokhim. Ural. Filial. Akad. Nauk SSSR, Issue 13, 49–52 (1969).

    Google Scholar 

  14. J. Miller, “Obtaining mode of tungsten big crystalline dendrite deposit,” J. Electrochem. Soc., 116, No. 9, 815–818 (1969).

    Google Scholar 

  15. V. V. Mikhailov, Nonferrous Metallurgy of the USA [in Russian], Mintsvetmet SSSR, Moscow (1972).

    Google Scholar 

  16. V. S. Balikhin and A. V. Reznichenko, “Refining of tungsten in chloride–fluoride melts,” Tsvetn. Met., No. 10, 59–62 (1979).

    Google Scholar 

  17. I. Morita, G. Marukawa, and M. Hito, “Fluoroborate electrolyte for tungsten electrodeposition,” J. Electrochem. Soc., 122, No. 8, 703–707 (1975).

    Google Scholar 

  18. T. Kh. Imamov, R. N. Bazarov, and A. A. Kal’kov, “Electrochemical method of obtaining molybdenum and tungsten from molten media,” Élektrokhimiya, 10, 1223–1228 (1974).

    Google Scholar 

  19. S. H. White and U. M. Twardoch, “The chemistry and electrochemistry associated with the electroplating of group VIA transition metals,” J. Appl. Electrochem., 17, 225 (1987).

    Article  CAS  Google Scholar 

  20. V. V. Malyshev, A. I. Gab, N. N. Uskova, and V. V. Soloviev, “Chemistry and electrochemistry of tungsten-containing ionic melt,” Molten Salts. Bull., No. 2, 1–10 (2004).

    Google Scholar 

  21. V. Malyshev, A. Gab A., and M. Gaune-Escard, “Molybdenum electrometallurgical processes in ionic melts,” Mater. Manufact. Proc., 23, No. 8, 748–751 (2008).

  22. Chuk-Ching Ma, “Electrodeposition of tungsten from pyrosulfate melts,” Ind. Eng. Chem., 44, 342–347 (1952).

    Article  Google Scholar 

  23. G. W. Mellors and S. Senderoff, “The electrodeposition of coherent deposits of refractory metals,” J. Electrochem. Soc., 113, No. 1, 60–66 (1966).

    Article  CAS  Google Scholar 

  24. D. H. Baker, “Electrowinning molybdenum and tungsten,” J. Met., 16, 873–879 (1964).

    CAS  Google Scholar 

  25. K. H. Stern, T. Stenly, and S. T. Gadomsky, “Electrodeposition of tungsten powders from mineral-salt electrolyte,” J. Electrochem. Soc., 130, No. 2, 300–305 (1983).

    Article  CAS  Google Scholar 

  26. A. B. Suchkov, G. V. Rumyantseva, A. R. Demachev, and M. V. Zhukova, “Electrolytic preparation of tungsten powder,” Poroshk. Metall., 12, 1–3 (1971), English translation: Powder. Metall. Metal Ceram., 10, No. 12, 941–942(1971).

  27. Ya. P. Chernobaev, L. N. Antishin, and M. P. Loshkarev, “Preparation of disperse metallic powders by electroreduction of poorly soluble compounds in molten media,” Dokl. Akad. Nauk. USSR, 5, 618–623 (1963).

    Google Scholar 

  28. K. A. Kaliev, A. G. Askent’ev, and A. N. Baraboshkin, “Study of the initial stage of electrodeposition of crystals of sodium–tungsten bronzes from tungstate melts,” Tr. Inst. Élektrokhim. Ural. Nauchn. Tsentra Akad. Nauk SSSR, Issue 28, 47–52 (1979).

    Google Scholar 

  29. V. Malyshev, A. Gab, and M. Gaune-Escard, “Initial stages of nucleation of molybdenum and tungsten carbide phases in tungstatemolybdate-carbonate melts,” J. Appl. Electrochem., 38, 315–320 (2008).

    Article  CAS  Google Scholar 

  30. L. E. Ivanovskii, “Deposition of coatings of refractory metals by electrolysis of molten salts,” in: Physical Chemistry and Electrochemistry of Molten and Solid Electrolytes [in Russian], Ural Scientific Center of the Academy of Sciences of the SSSR, Sverdlovsk (1973), pp. 79–82.

  31. K. H. Stern and M. L. Deanhardt, “Tungsten coatings from molten fluorides,” J. Thin Solid Films., 10, No. 1, 9–12 (1983).

    Article  Google Scholar 

  32. G. W. Mellors and S. Senderoff, “The electroforming of refractory metals,” Plating, 51, 972–976 (1964).

    CAS  Google Scholar 

  33. S. Senderoff and G. W. Mellors, “Electrodeposition of coherent deposits of the refractory metals,” Science, 153, 1475–1479 (1973).

    Article  Google Scholar 

  34. A. N. Baraboshkin, N. A. Saltykova, and V. G. Semenov, “Electrodeposition of tungsten and its alloys from fluoride melts,” Tr. Inst. Élektrokhim. Ural. Nauchn. Tsentra Akad. Nauk SSSR, Issue 24, 28–32 (1976).

  35. G. L. Davis and C. H. R. Gentry, “Coatings electrodeposition from metaborate melts,” Metallurgia, 33, 3–9 (1956).

    Google Scholar 

  36. F. X. McCawley, C. D. Kenahan, and R. U. S. Schlain, “Polytungstate–metaborate melts for tungsten electrodeposition,” Bur. Min. Rept. Invest., No. 6454, 3–64 (1964).

  37. D. M. Chizhikov, V. G. Trusova, and M. I. Pyatakova, “Chloride–carbonate electrolyte for tungsten plating,” Tsvetn. Met., No. 3, 49–53 (1965).

    Google Scholar 

  38. D. M. Chizhikov, V. G. Trusova, and M. I. Pyatakova, “Chloride–perrhenate electrolyte for deposition of tungsten,” Tsvetn. Met., No. 4, 46–51 (1973).

    Google Scholar 

  39. Yu. K. Delimarskii, N. I. Parkhomenko, and V. F. Grishchenko, “Preparation of tungsten coatings by electrolysis of oxychloride melts,” Zashch. Met., 12, 726–729 (1976).

    CAS  Google Scholar 

  40. V. I. Shapoval, V. F. Grishchenko, and N. I. Parkhomenko, “Chloride–tungstate electrolyte for electrodeposition of tungsten,” Ukr. Khim. Zh., No. 6, 26–31 (1974).

    Google Scholar 

  41. N. Kh. Tumanova and L. P. Barchuk, Platings from Ionic Melts [in Russian], Tekhnika, Kiev (1983).

  42. A. N. Baraboshkin, A. M. Molchanov, E. S. Martem’yanova, and O. N. Vinogradov-Zhabrov, “Structure of continuous tungsten layers electrodeposited from a chloride melt,” Tr. Inst. Élektrokhim. Ural. Nauchn. Tsentra Akad. Nauk SSSR, Issue 23, 46–51 (1976).

    Google Scholar 

  43. A. N. Baraboshkin and A. M. Molchanov, “Electrolyte for deposition of tungsten from chloride melts,” Tr. Inst. Élektrokhim. Ural. Nauchn. Tsentra Akad. Nauk SSSR, Issue 24, 33–37 (1977).

  44. S. F. Belos, S. F. Igumnov, and V. A. Kozlova, “Deposition of tungsten coatings on electronegative metals,” Rasplavy, No. 2, 20–25 (1981).

  45. V. S. Balikhin and V. S. Pavlovskii, “On deposition of tungsten coatings by electrolysis of salt melts,” Tsvetn. Met., 3, 70–73 (1975).

    Google Scholar 

  46. A. N. Baraboshkin, V. K. Perevozkin, and E. S. Ponomareva, “Structure of tungsten coatings obtained by electrolysis of chloride–tungstate melts,” Tr. Inst. Élektrokhim. Ural. Filiala Akad. Nauk SSSR, Issue 11, 45–49 (1968).

    Google Scholar 

  47. A. N. Baraboshkin, E. S. Martem’yanova, and A. F. Shunailov, “ Structure of continuous tungsten deposits obtained by electrolysis of a Na2WO4–WO3 melt,” Tr. Inst. Élektrokhim. Ural. Filiala Akad. Nauk SSSR, Issue 21, 66–69 (1974).

    Google Scholar 

  48. A. N. Baraboshkin, A. M. Molchanov, and E. S. Martem’yanova, “Electrodeposition of tungsten from chloride–tungstate melts,” Tr. Inst. Élektrokhim. Ural. Filiala Akad. Nauk SSSR, Issue 23, 46–51 (1975).

    Google Scholar 

  49. V. V. Malyshev, A. I. Gab, N. N. Uskova, and V. V. Soloviev, “Structure and electrochemistry of tungsten-containing ionic melts,” in: Proc. of the Int. Symp. of Ionic Liquids in Honour of Marcelle Gaune-Escard (June 26–28, 2003, France, Carry le Rouet), Carryle Rouet, France (2003), pp. 517–532.

  50. S. V. Plaksin and A. N. Baraboshkin, “Electrodeposition of tungsten from tungstate melts of different composition,” in: Electrode Processes in Halogenide and Oxide Electrolytes [in Russian], Sverdlovsk (1981), pp. 22–26.

  51. V. V. Malyshev and V. I. Pozhuev, “Electrodeposition and properties of molybdenum (tungsten)–nickel (cobalt) platings,” Poverkhn. Rentgen Sinkhrotron. Neitron. Issledov., No. 2, 94–101 (2007).

  52. V. V. Malyshev, D.-M. Ya. Bruskova, A. I. Gab, and L. V. Ursulyak, “Electrochemical behavior of halogenide dimeric tungsten complexes in a KCl−NaCl−K3W2Cl9 melt,” Metalurgiya, Issue 18, 92–101 (2008).

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Correspondence to V. V. Malyshev.

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Translated from Fizyko-Khimichna Mekhanika Materialiv, Vol.47, No.3, pp.68–76, May–June, 2011.

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Malyshev, V.V. Electrodeposition of different types of tungsten cathode deposits from ionic melts. Mater Sci 47, 345–354 (2011). https://doi.org/10.1007/s11003-011-9402-9

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