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Red phosphors in MgAl2Si2O8 doping with Mn4+, Gd3+ and Lu3+ and host-sensitized luminescence properties

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Abstract

Mn4+ doped and Gd3+, Lu3+ co-doped MgAl2Si2O8-based phosphors were first of all synthesized by solid state reaction at about 1300.0 °C. They were characterized by thermogravimetry, differential thermal analysis, X-ray powder diffraction, photoluminescence, and scanning electron microscopy. The luminescence mechanism of the phosphors which showed broad red emission bands in the range of 610–715 nm and had a different maximum intensity when activated by UV illumination was discussed. Such a red emission can be attributed to the intrinsic 2E → 4A2 transitions of Mn4+.

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Acknowledgements

This study was supported by Erciyes University EUBAP under project number FBD-09-804.

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Authors and Affiliations

  1. Department of Chemistry, Faculty of Science, Erciyes University, Kayseri, 38039, Turkey

    Nilgun Ozpozan Kalaycioglu

  2. Department of Materials Science and Engineering, Faculty of Engineering, Karamanoğlu Mehmetbey University, Karaman, 70200, Turkey

    Esra Çırçır

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  1. Nilgun Ozpozan Kalaycioglu
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  2. Esra Çırçır
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Correspondence to Esra Çırçır.

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Kalaycioglu, N.O., Çırçır, E. Red phosphors in MgAl2Si2O8 doping with Mn4+, Gd3+ and Lu3+ and host-sensitized luminescence properties. J Therm Anal Calorim 111, 273–277 (2013). https://doi.org/10.1007/s10973-012-2248-z

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  • DOI: https://doi.org/10.1007/s10973-012-2248-z

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