Abstract
Thermal properties (DTA-TG and thermal expansion) of spray-coated fly ash-based geopolymer have been studied. The geopolymer composition selected for thermal spray coating had Si:Al = 3.3 and Na:Al = 1.45. To improve the fire resistant characteristics, fine- and coarse-milled vermiculite powder was added at 10 mass percent. Water:geopolymer ratios varied from 0.35 to 0.41 depending on vermiculite content and method of coating. Water added into a starting mixture to increase the flow ability also decreased the geopolymerisation reaction.
Similar content being viewed by others
References
Davidovits J. Global warming impact on the cement and aggregates industries. World Res Rev. 1994;6:263–78.
Cheng TW, Chiu JP. Fire-resistant geopolymer produced by granulated blast furnace slag. Miner Eng. 2003;16:205–10.
Krivenko PV, Pushkareva YEK, Sukhanevich MV, Guziy SG. Fireproof coatings on the basis of alkaline aluminium silicate systems, development in strategic materials. Ceram Eng Sci Proc. 2008; 29(10):129–142.
Temuujin J, Minjigmaa A, Rickard W, Lee M, Williams I, van Riessen A. Preparation of metakaolin based geopolymer coatings on metal substrates as thermal barriers. Appl Clay Sci. 2009;46:265–70.
Temuujin J, Minjigmaa A, Rickard W, Lee M, Williams I, van Riessen A. Fly ash based geopolymer thin coatings on metal substrates and its thermal evaluation. J Hazard Mat. 2010;180:748–52.
Kong DLY, Sanjayan JG, Sagoe-Crentsil K. Comparative performance of geopolymers made with metakaolin and fly ash after exposure to elevated temperatures. Cem Concr Res. 2007;37:1583–9.
Rickard WDA, van Riessen A, Walls P. Thermal character of geopolymers synthesized from class F fly ash containing high concentrations of iron and a-quartz. Int J Appl Ceram Technol. 2010;7:81–8.
Marrion C, Richard PE, Custler LP, Johann M, Meacham P. Fire protection of structural steel in high-rise buildings. In: Goode MG, editor. Civil engineering research foundation, NIST GCR 04-872. Gaithersburg: National Institute of Standards and Technology; 2004. p. 88.
Suvorov SA, Skurikhin VV. Vermiculite—a promising material for high temperature heat insulators. Refrac Ind Ceram. 2003;44:186–93.
Temuujin J, van Riessen A. Effect of fly ash preliminary calcination on the properties of geopolymer. J Hazard Mat. 2009;164:634–9.
Provis JL, Yong CZ, Duxson P, van Deventer JSJ. Correlating mechanical and thermal properties of sodium silicate-fly ash geopolymers. Colloid Surf A. 2009;336:57–63.
Pérez-Maqueda LA, Balek V, Poyato J, Šubrt J, Bauntsewa IM, Beckman IN, Malek Z. Study of natural and ion exchanged vermiculite by emanation thermal analysis, TG, DTA and XRD. J Therm Anal Calorim. 2003;71:715–26.
Balek V, Pérez-Rodríguez JL, Pérez-Maqueda LA, Šubrt J, Poyato J. Thermal behaviour of ground vermiculite. J Therm Anal Calorim. 2007;88:819–23.
Acknowledgements
The authors wish to thank the Perlite and Vermiculite Factory Pty. (Perth, WA) for donating the vermiculite samples.
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Temuujin, J., Minjigmaa, A., Rickard, W. et al. Thermal properties of spray-coated geopolymer-type compositions. J Therm Anal Calorim 107, 287–292 (2012). https://doi.org/10.1007/s10973-011-1766-4
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10973-011-1766-4