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Study on the thermal behavior of the complexes of the type [PdX2(tdmPz)] (X = Cl−, Br−, I−, SCN−)

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Abstract

Four new mononuclear Pd(II) complexes of the type [PdX2(tdmPz)] {X = Cl− (1); Br− (2); I− (3); SCN− (4); tdmPz = 1-thiocarbamoyl-3,5-dimethylpyrazole} have been synthesized and characterized by elemental analysis, IR spectroscopy, 1H and 13C{1H}-NMR experiments. The thermal behavior of the complexes 1–4 has been investigated by means of thermogravimetry (TG) and differential thermal analysis (DTA). From the initial decomposition temperatures, the thermal stability of the complexes can be ordered in the sequence: 3 < 4 ≡ 2 < 1. The final products of the thermal decompositions were characterized as metallic palladium by X-ray powder diffraction.

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Acknowledgements

The authors wish to acknowledge CNPq, FAPESP, and CAPES for the financial support.

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Authors and Affiliations

  1. Departamento de Química Geral e Inorgânica, UNESP—Univ Estadual Paulista, C.P. 355, Araraquara, SP, 14801-970, Brazil

    Fillipe V. Rocha, Carolina V. Barra, Silmar J. S. Franchi, Adelino V. G. Netto, Antonio E. Mauro & Regina C. G. Frem

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  1. Fillipe V. Rocha
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  2. Carolina V. Barra
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  3. Silmar J. S. Franchi
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  4. Adelino V. G. Netto
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  5. Antonio E. Mauro
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  6. Regina C. G. Frem
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Correspondence to Adelino V. G. Netto or Antonio E. Mauro.

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Rocha, F.V., Barra, C.V., Franchi, S.J.S. et al. Study on the thermal behavior of the complexes of the type [PdX2(tdmPz)] (X = Cl−, Br−, I−, SCN−). J Therm Anal Calorim 106, 385–389 (2011). https://doi.org/10.1007/s10973-010-1239-1

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