Skip to main content
SpringerLink
Log in

Trimellitate complexes of divalent transition metals with hydrazinium cation

Thermal and spectroscopic studies

  • Published:
Journal of Thermal Analysis and Calorimetry Aims and scope Submit manuscript

Abstract

New dihydrazinium divalent transition metal trimellitate hydrates of empirical formula (N2H5)2M(Html)2·nH2O, where n = 1 for M = Co or Ni, and n = 2 for M = Mn, Zn, or Cd (H3tml = trimellitic acid), and monohydrazinium cadmium trimellitate, [(N2H5)Cd(Html)1.5·2H2O] have been prepared and characterized by physico-chemical methods. Electronic spectroscopic, and magnetic moment data suggest that Co and Ni complexes adopt an octahedral geometry. The IR spectra confirm the presence of monodentate carboxylate anion (Δν = νasy(COO−) − νsym(COO−) > 190 cm−1) and coordinated N2H5 + ion (νN–N 1015 − 990 cm−1) in all the complexes. All the complexes undergo endothermic decomposition eliminating CO2 in the temperature region 200–250 °C, followed by exothermic decomposition (in the range of 500–570 °C) of organic moiety to give the respective metal carbonate as the end products except nickel and cobalt complexes, which leave respective metal oxides. X-ray powder diffraction patterns reveal that Ni and Co complexes are isomorphous as are those of, Zn(II) and Cd(II) of the type, (N2H5)2M(Html)2·2H2O.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3

Similar content being viewed by others

References

  1. Choppin GR, Rizkalla EN, El-ansi TA, Dadgar A. Complexation thermodynamics of lanthanide ions by benzenepolycarboxylate ligands. J Coord Chem. 1994;31:297–304.

    Article  CAS  Google Scholar 

  2. Wang Z-M, Van de Burgt LJ, Choppin GR. Spectroscopic study of lanthanide(III) complexes with carboxylic acids. Inorg Chim Acta. 1999;193:167–77.

    Article  Google Scholar 

  3. Brzyska W, Kurpiel-Gorgol R, Dabkowska M. Thermal decomposition of scandium(III) benzenetricarboxylates in air and nitrogen atmospheres. J Therm Anal Calorim. 1983;28:333–9.

    Article  CAS  Google Scholar 

  4. Brzyska W, Wolodkiewicz W. Thermal decomposition of copper(II) benzenetricarboxylates in air atmosphere. J Therm Anal Calorim. 1986;31:961–5.

    Article  CAS  Google Scholar 

  5. Gajapathy D, Govindarajan S, Patil KC, Manohar H. Synthesis, characterisation and thermal properties of hydrazinium metal oxalate hydrates. Crystal and molecular structure of hydrazinium copper oxalate monohydrate. Polyhedron. 1983;2:865–73.

    Article  CAS  Google Scholar 

  6. Govindarajan S, Patil KC, Poojary MD, Manohar H. Synthesis, characterization and X-ray structure of hexahydrazinium diuranyl pentaoxalate dihydrate, (N2H5)6(UO2)2(C2O4)5·2H2O. Inorg Chim Acta. 1986;120:103–7.

    Article  CAS  Google Scholar 

  7. Sivasankar BN, Govindarajan S. Acetate and malonate complexes of cobalt(II), nickel(II) and zinc(II) with hydrazinium cation. Preparation, spectral and thermal studies. J Therm Anal Calorim. 1997;48:1401–13.

    Article  CAS  Google Scholar 

  8. Kuppusamy K, Govindarajan S. Hydrazinium cation as a ligand: preparation and spectral, thermal and XRD studies on hydrazinium metal phthalates. Eur J Solid State Inorg Chem. 1995;32:997–1012.

    CAS  Google Scholar 

  9. Premkumar T, Govindarajan S. Thermoanalytical and spectroscopic studies on hydrazinium lighter lanthanide complexes of 2-pyrazinecarboxylic acid. J Therm Anal Calorim. 2009. doi:10.1007/s10973-009-0117-1 (online first).

  10. Premkumar T, Govindarajan S. Transition metal complexes of pyrazinecarboxylic acids with neutral hydrazine as a ligand. J Therm Anal Calorim. 2005;79:115–21.

    Article  CAS  Google Scholar 

  11. Premkumar T, Govindarajan S. The chemistry of hydrazine derivatives—thermal behavior and characterisation of hydrazinium salts and metal hydrazine complexes of 4, 5-imidazoledicarboxylic acid. Thermochim Acta. 2002;386:35–42.

    Article  CAS  Google Scholar 

  12. Premkumar T, Govindarajan S. Divalent transition metal complexes of 3,5-pyrazoledicarboxylate. J Therm Anal Calorim. 2006;84:395–9.

    Article  CAS  Google Scholar 

  13. Gonsalves LR, Verenkar VMS, Mojumdar SC. Preparation and characterization of Co0.5Zn0.5Fe2(C4H2O4)3·6N2H4. J Therm Anal Calorim. 2009;96:53–7.

    Article  CAS  Google Scholar 

  14. Vikram L, Sivasankar BN. Hydrazinium metal(II) and metal(III) ethylenediamine tetraacetate hydrates. J Therm Anal Calorim. 2008;91:963–70.

    Article  CAS  Google Scholar 

  15. Raju B, Sivasankar BN. Spectral, thermal and X-ray studies on some new Bis–hydrazine lanthanide(III) glyoxylates. J Therm Anal Calorim. 2008;94:289–96.

    Article  CAS  Google Scholar 

  16. Vikram L, Raju B, Ragul R, Sivasankar BN. Thermal degradation studies on some lanthanide–EDTA complexes containing hydrazinium cation. J Therm Anal Calorim. 2008;93:987–91.

    Article  CAS  Google Scholar 

  17. Vogel AI. A text book of quantitative inorganic analysis. 4th ed. London: Longman; 1986.

    Google Scholar 

  18. Cotton FA, Wilkinson G. The elements of the first transition series. In: Advanced inorganic chemistry. 3rd ed. New Delhi: Wiley Eastern; 1972. p. 881.

  19. Figgis BN, Lewis J. The magnetic properties of transition metal complexes. In: Progress in inorganic chemistry. 6th ed. New York: F.A. Cotton, Interscience; 1964. p. 1430.

  20. Brown DB, Donner JA, Hall JW, Wilson SR, Wilson RB, Hondgson DJ, et al. Interaction of hydrazine with copper(II) chloride in acidic solutions. Formation, spectral and magnetic properties, and structures of copper(II), copper(I), and mixed-valence species. Inorg Chem. 1979;18:2635–41.

    Article  CAS  Google Scholar 

  21. Braibanti A, Dallavalle F, Pellinghelli MA, Laporati E. The nitrogen-nitrogen stretching band in hydrazine derivatives and complexes. Inorg Chem. 1968;7:1430–3.

    Article  CAS  Google Scholar 

  22. Nakamoto K. Infrared and Raman spectra of inorganic and coordination compounds. 3rd ed. New York: Wiley Interscience; 1978.

    Google Scholar 

  23. Gonzalez-Sanchez F. Infra-red spectra of the benzene carboxylic acids. Spectrochim Acta. 1958;12:17–33.

    Article  CAS  Google Scholar 

Download references

Author information

Author notes

  1. T. Premkumar

    Present address: Department of Materials Science and Engineering, Gwangju Institute of Science and Technology, 1 Oryong-dong, Buk-gu, Gwangju, 500-712, South Korea

Authors and Affiliations

  1. Department of Chemistry, Bharathiar University, Coimbatore, 641046, India

    S. Vairam, T. Premkumar & S. Govindarajan

Authors
  1. S. Vairam
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. T. Premkumar
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. S. Govindarajan
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to S. Govindarajan.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Vairam, S., Premkumar, T. & Govindarajan, S. Trimellitate complexes of divalent transition metals with hydrazinium cation. J Therm Anal Calorim 100, 955–960 (2010). https://doi.org/10.1007/s10973-009-0459-8

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10973-009-0459-8

Keywords

Search

Navigation